Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids
Abstract The injection of sulfate-containing seawater into an oil reservoir, for maintaining the reservoir pressure, can promote the growth of sulfate reducing bacteria and archaea near the injection wells, leading to the formation of sulfides such as hydrogen sulfide. However, intermediate sulfur s...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SpringerOpen
2018-08-01
|
| Series: | Journal of Petroleum Exploration and Production Technology |
| Subjects: | |
| Online Access: | http://link.springer.com/article/10.1007/s13202-018-0528-2 |
| _version_ | 1828381928957411328 |
|---|---|
| author | Mahsan Basafa Kelly Hawboldt |
| author_facet | Mahsan Basafa Kelly Hawboldt |
| author_sort | Mahsan Basafa |
| collection | DOAJ |
| description | Abstract The injection of sulfate-containing seawater into an oil reservoir, for maintaining the reservoir pressure, can promote the growth of sulfate reducing bacteria and archaea near the injection wells, leading to the formation of sulfides such as hydrogen sulfide. However, intermediate sulfur species with different valence states, such as polythionates and polysulfides have been detected in several produced water samples, likely a result of phase partitioning, and chemical and microbial reactions. These sulfur species could affect the microbial communities (e.g., microbially influenced corrosion) and will impact the efficiency of souring mitigation methods. In addition, the presence of these sulfur species can result in operational, environmental, and treatment problems. Therefore, development and implementation of souring control strategies during production cycle of oil and gas reservoirs require identifying the origins, reactivity, and the partitioning behaviour of these compounds. This paper presents an overview of the known mechanisms responsible for reservoir souring and then focuses on the chemical reactions and sulfur species associated with production and consumption of hydrogen sulfide. In this work we highlight complexity of the sulfur chemistry and that the assumption that all the sulfate is reduced to hydrogen sulfide can lead to inappropriate souring management methods. The paper also reviews the detection and analysis methods used for sulfur compounds. The review demonstrates that there is a gap in the current souring models and methods due to the exclusion of key sulfur compounds and challenges in identifying and quantifying these compounds with respect to speed of analysis and sample stability. |
| first_indexed | 2024-12-10T04:23:48Z |
| format | Article |
| id | doaj.art-3ff2f5a388ed4e279e4956f45b40feed |
| institution | Directory Open Access Journal |
| issn | 2190-0558 2190-0566 |
| language | English |
| last_indexed | 2024-12-10T04:23:48Z |
| publishDate | 2018-08-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Journal of Petroleum Exploration and Production Technology |
| spelling | doaj.art-3ff2f5a388ed4e279e4956f45b40feed2022-12-22T02:02:20ZengSpringerOpenJournal of Petroleum Exploration and Production Technology2190-05582190-05662018-08-01921105111810.1007/s13202-018-0528-2Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluidsMahsan Basafa0Kelly Hawboldt1Faculty of Engineering and Applied Science, Memorial University of NewfoundlandFaculty of Engineering and Applied Science, Memorial University of NewfoundlandAbstract The injection of sulfate-containing seawater into an oil reservoir, for maintaining the reservoir pressure, can promote the growth of sulfate reducing bacteria and archaea near the injection wells, leading to the formation of sulfides such as hydrogen sulfide. However, intermediate sulfur species with different valence states, such as polythionates and polysulfides have been detected in several produced water samples, likely a result of phase partitioning, and chemical and microbial reactions. These sulfur species could affect the microbial communities (e.g., microbially influenced corrosion) and will impact the efficiency of souring mitigation methods. In addition, the presence of these sulfur species can result in operational, environmental, and treatment problems. Therefore, development and implementation of souring control strategies during production cycle of oil and gas reservoirs require identifying the origins, reactivity, and the partitioning behaviour of these compounds. This paper presents an overview of the known mechanisms responsible for reservoir souring and then focuses on the chemical reactions and sulfur species associated with production and consumption of hydrogen sulfide. In this work we highlight complexity of the sulfur chemistry and that the assumption that all the sulfate is reduced to hydrogen sulfide can lead to inappropriate souring management methods. The paper also reviews the detection and analysis methods used for sulfur compounds. The review demonstrates that there is a gap in the current souring models and methods due to the exclusion of key sulfur compounds and challenges in identifying and quantifying these compounds with respect to speed of analysis and sample stability.http://link.springer.com/article/10.1007/s13202-018-0528-2Chemical reactionsHydrogen sulfideSour reservoirsSulfur chemistryAnalytical methods |
| spellingShingle | Mahsan Basafa Kelly Hawboldt Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids Journal of Petroleum Exploration and Production Technology Chemical reactions Hydrogen sulfide Sour reservoirs Sulfur chemistry Analytical methods |
| title | Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids |
| title_full | Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids |
| title_fullStr | Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids |
| title_full_unstemmed | Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids |
| title_short | Reservoir souring: sulfur chemistry in offshore oil and gas reservoir fluids |
| title_sort | reservoir souring sulfur chemistry in offshore oil and gas reservoir fluids |
| topic | Chemical reactions Hydrogen sulfide Sour reservoirs Sulfur chemistry Analytical methods |
| url | http://link.springer.com/article/10.1007/s13202-018-0528-2 |
| work_keys_str_mv | AT mahsanbasafa reservoirsouringsulfurchemistryinoffshoreoilandgasreservoirfluids AT kellyhawboldt reservoirsouringsulfurchemistryinoffshoreoilandgasreservoirfluids |