Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures

<p>Abstract</p> <p>The nucleation and evolution of InN nanowires in a self-catalyzed growth process have been investigated to probe the microscopic growth mechanism of the self-catalysis and a model is proposed for high pressure growth window at ~760 Torr. In the initial stage of t...

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Main Authors: Xu Guowei, Li Zhuangzhi, Baca Javier, Wu Judy
Format: Article
Language:English
Published: SpringerOpen 2009-01-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-009-9434-3
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author Xu Guowei
Li Zhuangzhi
Baca Javier
Wu Judy
author_facet Xu Guowei
Li Zhuangzhi
Baca Javier
Wu Judy
author_sort Xu Guowei
collection DOAJ
description <p>Abstract</p> <p>The nucleation and evolution of InN nanowires in a self-catalyzed growth process have been investigated to probe the microscopic growth mechanism of the self-catalysis and a model is proposed for high pressure growth window at ~760 Torr. In the initial stage of the growth, amorphous InN<sub> <it>x</it> </sub> microparticles of cone shape in liquid phase form with assistance of an InN<sub> <it>x</it> </sub> wetting layer on the substrate. InN crystallites form inside the cone and serve as the seeds for one-dimensional growth along the favorable [0001] orientation, resulting in single-crystalline InN nanowire bundles protruding out from the cones. An amorphous InN<sub> <it>x</it> </sub> sheath around the faucet tip serves as the interface between growing InN nanowires and the incoming vapors of indium and nitrogen and supports continuous growth of InN nanowires in a similar way to the oxide sheath in the oxide-assisted growth of other semiconductor nanowires. Other InN 1D nanostructures, such as belts and tubes, can be obtained by varying the InN crystallites nucleation and initiation process.</p>
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spelling doaj.art-4014d15012604d8a8b95c1287127f37b2023-08-02T06:30:40ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2009-01-0151713Probing Nucleation Mechanism of Self-Catalyzed InN NanostructuresXu GuoweiLi ZhuangzhiBaca JavierWu Judy<p>Abstract</p> <p>The nucleation and evolution of InN nanowires in a self-catalyzed growth process have been investigated to probe the microscopic growth mechanism of the self-catalysis and a model is proposed for high pressure growth window at ~760 Torr. In the initial stage of the growth, amorphous InN<sub> <it>x</it> </sub> microparticles of cone shape in liquid phase form with assistance of an InN<sub> <it>x</it> </sub> wetting layer on the substrate. InN crystallites form inside the cone and serve as the seeds for one-dimensional growth along the favorable [0001] orientation, resulting in single-crystalline InN nanowire bundles protruding out from the cones. An amorphous InN<sub> <it>x</it> </sub> sheath around the faucet tip serves as the interface between growing InN nanowires and the incoming vapors of indium and nitrogen and supports continuous growth of InN nanowires in a similar way to the oxide sheath in the oxide-assisted growth of other semiconductor nanowires. Other InN 1D nanostructures, such as belts and tubes, can be obtained by varying the InN crystallites nucleation and initiation process.</p>http://dx.doi.org/10.1007/s11671-009-9434-3Indium nitrideSelf-catalyzedNanowiresInN<sub> <it>x</it> </sub> conesSheath
spellingShingle Xu Guowei
Li Zhuangzhi
Baca Javier
Wu Judy
Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures
Nanoscale Research Letters
Indium nitride
Self-catalyzed
Nanowires
InN<sub> <it>x</it> </sub> cones
Sheath
title Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures
title_full Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures
title_fullStr Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures
title_full_unstemmed Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures
title_short Probing Nucleation Mechanism of Self-Catalyzed InN Nanostructures
title_sort probing nucleation mechanism of self catalyzed inn nanostructures
topic Indium nitride
Self-catalyzed
Nanowires
InN<sub> <it>x</it> </sub> cones
Sheath
url http://dx.doi.org/10.1007/s11671-009-9434-3
work_keys_str_mv AT xuguowei probingnucleationmechanismofselfcatalyzedinnnanostructures
AT lizhuangzhi probingnucleationmechanismofselfcatalyzedinnnanostructures
AT bacajavier probingnucleationmechanismofselfcatalyzedinnnanostructures
AT wujudy probingnucleationmechanismofselfcatalyzedinnnanostructures