Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil
Four sequential extraction procedures (Sposito, Tessier, Silveira and Bureau Communautaire de Reference (BCR)) were used to evaluate the distribution of some metals (Fe, Cu, Cd and Zn) in a contaminated soil around a mining area. The results showed that Fe and Zn were mainly recovered in the recalci...
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Format: | Article |
Language: | English |
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Czech Academy of Agricultural Sciences
2013-06-01
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Series: | Soil and Water Research |
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Online Access: | https://swr.agriculturejournals.cz/artkey/swr-201302-0004_assessment-of-trace-and-heavy-metal-distribution-by-four-sequential-extraction-procedures-in-a-contaminated-soi.php |
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author | Qingsong HE Yue REN Ibrahim MOHAMED Maha ALI Waseem HASSAN Fangui ZENG |
author_facet | Qingsong HE Yue REN Ibrahim MOHAMED Maha ALI Waseem HASSAN Fangui ZENG |
author_sort | Qingsong HE |
collection | DOAJ |
description | Four sequential extraction procedures (Sposito, Tessier, Silveira and Bureau Communautaire de Reference (BCR)) were used to evaluate the distribution of some metals (Fe, Cu, Cd and Zn) in a contaminated soil around a mining area. The results showed that Fe and Zn were mainly recovered in the recalcitrant soil fractions, while Cd was primarily localized in the exchangeable fraction. Soil Cu was highly associated with organic matter fraction. The amorphous Fe fraction in Silveira could be recognized as part of the Fe-Mn oxide fraction in Tessier and BCR procedures, while the crystalline Fe oxide fraction was classified into the residual fraction in Sposito, BCR and Tessier schemes. Although the same reagent was used to extract target fraction, less carbonate-bound Cu, Cu and Zn were extracted in Tessier procedure as compared to Silveira method, while Tessier scheme yielded a higher proportion of Fe, Cu and Zn in the Fe-Mn oxide fraction than BCR method. Due to the lack of uniformity of experimental conditions and the differences in extraction reagents, the extraction efficiency of metal species varied with the sequential extraction schemes. Therefore, care should be taken when comparing the results obtained by different sequential extraction procedures. |
first_indexed | 2024-04-10T08:03:53Z |
format | Article |
id | doaj.art-4029ef1c65f7476386d02b249cfbd52f |
institution | Directory Open Access Journal |
issn | 1801-5395 1805-9384 |
language | English |
last_indexed | 2024-04-10T08:03:53Z |
publishDate | 2013-06-01 |
publisher | Czech Academy of Agricultural Sciences |
record_format | Article |
series | Soil and Water Research |
spelling | doaj.art-4029ef1c65f7476386d02b249cfbd52f2023-02-23T03:48:22ZengCzech Academy of Agricultural SciencesSoil and Water Research1801-53951805-93842013-06-0182717610.17221/20/2012-SWRswr-201302-0004Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soilQingsong HE0Yue REN1Ibrahim MOHAMED2Maha ALI3Waseem HASSAN4Fangui ZENG5College of Mining Technology, Taiyuan University of Technology, Taiyuan, Shanxi, ChinaHubei Geological Research Laboratory, Wuhan, ChinaSoil Science Department, Faculty of Agriculture, Benha University, Benha, EgyptSoil Science Department, Faculty of Agriculture, Benha University, Benha, EgyptCollege of Resources and Environment, Huazhong Agricultural University, Wuhan, ChinaKey Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Department of Earth Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi, China$2Four sequential extraction procedures (Sposito, Tessier, Silveira and Bureau Communautaire de Reference (BCR)) were used to evaluate the distribution of some metals (Fe, Cu, Cd and Zn) in a contaminated soil around a mining area. The results showed that Fe and Zn were mainly recovered in the recalcitrant soil fractions, while Cd was primarily localized in the exchangeable fraction. Soil Cu was highly associated with organic matter fraction. The amorphous Fe fraction in Silveira could be recognized as part of the Fe-Mn oxide fraction in Tessier and BCR procedures, while the crystalline Fe oxide fraction was classified into the residual fraction in Sposito, BCR and Tessier schemes. Although the same reagent was used to extract target fraction, less carbonate-bound Cu, Cu and Zn were extracted in Tessier procedure as compared to Silveira method, while Tessier scheme yielded a higher proportion of Fe, Cu and Zn in the Fe-Mn oxide fraction than BCR method. Due to the lack of uniformity of experimental conditions and the differences in extraction reagents, the extraction efficiency of metal species varied with the sequential extraction schemes. Therefore, care should be taken when comparing the results obtained by different sequential extraction procedures.https://swr.agriculturejournals.cz/artkey/swr-201302-0004_assessment-of-trace-and-heavy-metal-distribution-by-four-sequential-extraction-procedures-in-a-contaminated-soi.phpfractionationmetalsmining activitiespollution |
spellingShingle | Qingsong HE Yue REN Ibrahim MOHAMED Maha ALI Waseem HASSAN Fangui ZENG Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil Soil and Water Research fractionation metals mining activities pollution |
title | Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil |
title_full | Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil |
title_fullStr | Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil |
title_full_unstemmed | Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil |
title_short | Assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil |
title_sort | assessment of trace and heavy metal distribution by four sequential extraction procedures in a contaminated soil |
topic | fractionation metals mining activities pollution |
url | https://swr.agriculturejournals.cz/artkey/swr-201302-0004_assessment-of-trace-and-heavy-metal-distribution-by-four-sequential-extraction-procedures-in-a-contaminated-soi.php |
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