1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione
Urazolyl radicals are a class of persistent nitrogen-centered radicals. In a previous work, we successfully formed self-assembled monolayers of substituted urazolyl radicals on gold surfaces. To extend the scope of these investigations, we sought to form a self-assembled monolayer using a urazolyl r...
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-02-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2023/1/M1578 |
| _version_ | 1828715758106968064 |
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| author | Gary W. Breton |
| author_facet | Gary W. Breton |
| author_sort | Gary W. Breton |
| collection | DOAJ |
| description | Urazolyl radicals are a class of persistent nitrogen-centered radicals. In a previous work, we successfully formed self-assembled monolayers of substituted urazolyl radicals on gold surfaces. To extend the scope of these investigations, we sought to form a self-assembled monolayer using a urazolyl radical species that we knew existed predominantly in the dimerized <i>N</i>-<i>N</i> form instead of existing predominantly as free <i>N</i>-centered radical species, as had previously been investigated. We successfully synthesized the precursor urazole compound needed to generate the desired urazolyl radical, and completely characterized its structure. Most importantly, it was determined that the alkyne functional group that is needed to adhere to the gold surface remained intact. Unfortunately, however, we only obtained ambiguous results from attempts at forming self-assembled monolayers of this species on gold. |
| first_indexed | 2024-03-11T06:08:10Z |
| format | Article |
| id | doaj.art-402b99e11276477e8c262f8c1a1e36a1 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-03-11T06:08:10Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-402b99e11276477e8c262f8c1a1e36a12023-11-17T12:49:41ZengMDPI AGMolbank1422-85992023-02-0120231M157810.3390/M15781-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dioneGary W. Breton0Department of Chemistry and Biochemistry, Berry College, Mount Berry, GA 30149, USAUrazolyl radicals are a class of persistent nitrogen-centered radicals. In a previous work, we successfully formed self-assembled monolayers of substituted urazolyl radicals on gold surfaces. To extend the scope of these investigations, we sought to form a self-assembled monolayer using a urazolyl radical species that we knew existed predominantly in the dimerized <i>N</i>-<i>N</i> form instead of existing predominantly as free <i>N</i>-centered radical species, as had previously been investigated. We successfully synthesized the precursor urazole compound needed to generate the desired urazolyl radical, and completely characterized its structure. Most importantly, it was determined that the alkyne functional group that is needed to adhere to the gold surface remained intact. Unfortunately, however, we only obtained ambiguous results from attempts at forming self-assembled monolayers of this species on gold.https://www.mdpi.com/1422-8599/2023/1/M1578urazoleradicalurazolyl radicalSAM |
| spellingShingle | Gary W. Breton 1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione Molbank urazole radical urazolyl radical SAM |
| title | 1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione |
| title_full | 1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione |
| title_fullStr | 1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione |
| title_full_unstemmed | 1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione |
| title_short | 1-[2,6-Dimethyl-4-(pent-4-yn-1-yloxy)phenyl]-4-phenyl-1,2,4-triazolidine-3,5-dione |
| title_sort | 1 2 6 dimethyl 4 pent 4 yn 1 yloxy phenyl 4 phenyl 1 2 4 triazolidine 3 5 dione |
| topic | urazole radical urazolyl radical SAM |
| url | https://www.mdpi.com/1422-8599/2023/1/M1578 |
| work_keys_str_mv | AT garywbreton 126dimethyl4pent4yn1yloxyphenyl4phenyl124triazolidine35dione |