Polyampholyte Polymers‐Based Sensors: A Review on Stimuli and Applications

Abstract Polyampholytes are a specific type of zwitterionic materials composed of monomers with both positive and negative charges. These materials can be synthesized through various methods, such as free radical, anionic, or cationic polymerization, or by modifying existing polymers through postpol...

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Bibliographic Details
Main Authors: Ali Zardehi‐Tabriz, Yoones Ghayebzadeh, Amirhossein Enayati Gerdroodbar, Marzieh Golshan, Hossein Roghani‐Mamaqani, Mehdi Salami‐Kalajahi
Format: Article
Language:English
Published: Wiley-VCH 2023-12-01
Series:Macromolecular Materials and Engineering
Subjects:
Online Access:https://doi.org/10.1002/mame.202300179
Description
Summary:Abstract Polyampholytes are a specific type of zwitterionic materials composed of monomers with both positive and negative charges. These materials can be synthesized through various methods, such as free radical, anionic, or cationic polymerization, or by modifying existing polymers through postpolymerization processes. Polyampholytes possess unique properties that make them attractive for a wide range of applications, particularly in sensor technology. They can undergo conformational changes in response to external stimuli like pH variations, temperature fluctuations, or changes in salt concentration. These properties have led to their application in biosensors, salt and ion sensors, pH sensors, fluorescence‐based sensors, strain sensors, and thermosensitive sensors. It is worth noting that in some cases polyampholytes can respond to multiple stimuli simultaneously. Overall, polyampholytes are drawing great attention for their excellent mechanical properties including self‐healing, high toughness, and fatigue resistance. Thus, this review is focused on advances that are made to develop polyampholyte polymer‐based sensors in different applications.
ISSN:1438-7492
1439-2054