Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water

This paper examines the influence of polyacrylic superabsorbent polymers (SAP) on the properties concerning chloride diffusion in cementitious materials. The conducted study investigated the influence of SAP on chloride diffusion in concretes of the initial w/c = 0.4 (for which the changes in compre...

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Main Authors: Maciej Kalinowski, Piotr Woyciechowski
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/15/4064
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author Maciej Kalinowski
Piotr Woyciechowski
author_facet Maciej Kalinowski
Piotr Woyciechowski
author_sort Maciej Kalinowski
collection DOAJ
description This paper examines the influence of polyacrylic superabsorbent polymers (SAP) on the properties concerning chloride diffusion in cementitious materials. The conducted study investigated the influence of SAP on chloride diffusion in concretes of the initial w/c = 0.4 (for which the changes in compressive strength due to the SAP presence were negligible). The impact on the diffusivity of concrete of several variables was analyzed: the material characteristics of SAP, additional water added to the concrete to make up for the amount of water stored in the SAP structure, and the method of SAP dosing to the mix (either in a non-saturated form or in a hydrogel form). We found that, in the case of modifying concrete with polyacrylic SAP of a median particle size in dry conditions of 330 µm and without additional water, the coefficient of chloride ion diffusion was reduced to 65% of the reference value. The negative influence (increase) of increasing w/c<sub>tot</sub> by the amount of water initially entrained by SAP on the chloride diffusivity of concrete was identified. The conducted study indicates the premise of the mechanism of the water release from SAP in cementitious composites.
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spelling doaj.art-405ed7c7a6e54ae79a2ccda05b2975df2023-11-22T05:51:11ZengMDPI AGMaterials1996-19442021-07-011415406410.3390/ma14154064Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained WaterMaciej Kalinowski0Piotr Woyciechowski1Faculty of Civil Engineering, Warsaw University of Technology, 00-637 Warsaw, PolandFaculty of Civil Engineering, Warsaw University of Technology, 00-637 Warsaw, PolandThis paper examines the influence of polyacrylic superabsorbent polymers (SAP) on the properties concerning chloride diffusion in cementitious materials. The conducted study investigated the influence of SAP on chloride diffusion in concretes of the initial w/c = 0.4 (for which the changes in compressive strength due to the SAP presence were negligible). The impact on the diffusivity of concrete of several variables was analyzed: the material characteristics of SAP, additional water added to the concrete to make up for the amount of water stored in the SAP structure, and the method of SAP dosing to the mix (either in a non-saturated form or in a hydrogel form). We found that, in the case of modifying concrete with polyacrylic SAP of a median particle size in dry conditions of 330 µm and without additional water, the coefficient of chloride ion diffusion was reduced to 65% of the reference value. The negative influence (increase) of increasing w/c<sub>tot</sub> by the amount of water initially entrained by SAP on the chloride diffusivity of concrete was identified. The conducted study indicates the premise of the mechanism of the water release from SAP in cementitious composites.https://www.mdpi.com/1996-1944/14/15/4064superabsorbent polymersconcretechloride diffusionhydrogelcementSAP
spellingShingle Maciej Kalinowski
Piotr Woyciechowski
Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water
Materials
superabsorbent polymers
concrete
chloride diffusion
hydrogel
cement
SAP
title Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water
title_full Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water
title_fullStr Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water
title_full_unstemmed Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water
title_short Chloride Diffusion in Concrete Modified with Polyacrylic Superabsorbent Polymer (SAP) Hydrogel—The Influence of the Water-to-Cement Ratio and SAP-Entrained Water
title_sort chloride diffusion in concrete modified with polyacrylic superabsorbent polymer sap hydrogel the influence of the water to cement ratio and sap entrained water
topic superabsorbent polymers
concrete
chloride diffusion
hydrogel
cement
SAP
url https://www.mdpi.com/1996-1944/14/15/4064
work_keys_str_mv AT maciejkalinowski chloridediffusioninconcretemodifiedwithpolyacrylicsuperabsorbentpolymersaphydrogeltheinfluenceofthewatertocementratioandsapentrainedwater
AT piotrwoyciechowski chloridediffusioninconcretemodifiedwithpolyacrylicsuperabsorbentpolymersaphydrogeltheinfluenceofthewatertocementratioandsapentrainedwater