Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing

Graphitisation of structural characteristics and improvement in electrical conductivity was reported onto waste carbon powder through femtosecond laser annealing. Raman spectroscopy on the carbon powder pre- and post-annealing showed a shift from amorphous-like carbon to graphitic-like carbon, which...

Full description

Bibliographic Details
Main Authors: Lucas Lum, Chong-Wei Tan, Chun Fei Siah, Kun Liang, Beng Kang Tay
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Micromachines
Subjects:
Online Access:https://www.mdpi.com/2072-666X/13/1/120
_version_ 1797491812290527232
author Lucas Lum
Chong-Wei Tan
Chun Fei Siah
Kun Liang
Beng Kang Tay
author_facet Lucas Lum
Chong-Wei Tan
Chun Fei Siah
Kun Liang
Beng Kang Tay
author_sort Lucas Lum
collection DOAJ
description Graphitisation of structural characteristics and improvement in electrical conductivity was reported onto waste carbon powder through femtosecond laser annealing. Raman spectroscopy on the carbon powder pre- and post-annealing showed a shift from amorphous-like carbon to graphitic-like carbon, which can be explained by the three-stage model. Electrical I-V probing of the samples revealed an increase in conductivity by up to 90%. An increase in incident laser power was found to be correlated to an increase in conductivity. An average incident laser power of 0.104 W or less showed little to no change in electrical characteristics, while an average incident laser power of greater than 1.626 W had a destructive effect on the carbon powder, shown through the reduction in powder. The most significant improvement in electrical conductivity has been observed at laser powers ranging from 0.526 to 1.286 W. To conclude, the graphitisation of waste carbon powder is possible using post-process femtosecond laser annealing to alter its electrical conductivity for future applications.
first_indexed 2024-03-10T00:54:39Z
format Article
id doaj.art-408d5f0ea541414bb380786b4b6a5ff3
institution Directory Open Access Journal
issn 2072-666X
language English
last_indexed 2024-03-10T00:54:39Z
publishDate 2022-01-01
publisher MDPI AG
record_format Article
series Micromachines
spelling doaj.art-408d5f0ea541414bb380786b4b6a5ff32023-11-23T14:45:17ZengMDPI AGMicromachines2072-666X2022-01-0113112010.3390/mi13010120Graphitisation of Waste Carbon Powder with Femtosecond Laser AnnealingLucas Lum0Chong-Wei Tan1Chun Fei Siah2Kun Liang3Beng Kang Tay4Centre for Micro- and Nano-Electronics (CMNE), School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Ave, Singapore 639798, SingaporeCentre for Micro- and Nano-Electronics (CMNE), School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Ave, Singapore 639798, SingaporeCentre for Micro- and Nano-Electronics (CMNE), School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Ave, Singapore 639798, SingaporeCentre for Micro- and Nano-Electronics (CMNE), School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Ave, Singapore 639798, SingaporeCentre for Micro- and Nano-Electronics (CMNE), School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Ave, Singapore 639798, SingaporeGraphitisation of structural characteristics and improvement in electrical conductivity was reported onto waste carbon powder through femtosecond laser annealing. Raman spectroscopy on the carbon powder pre- and post-annealing showed a shift from amorphous-like carbon to graphitic-like carbon, which can be explained by the three-stage model. Electrical I-V probing of the samples revealed an increase in conductivity by up to 90%. An increase in incident laser power was found to be correlated to an increase in conductivity. An average incident laser power of 0.104 W or less showed little to no change in electrical characteristics, while an average incident laser power of greater than 1.626 W had a destructive effect on the carbon powder, shown through the reduction in powder. The most significant improvement in electrical conductivity has been observed at laser powers ranging from 0.526 to 1.286 W. To conclude, the graphitisation of waste carbon powder is possible using post-process femtosecond laser annealing to alter its electrical conductivity for future applications.https://www.mdpi.com/2072-666X/13/1/120carbon blackfemtosecond laser annealingablationnano-crystallisation
spellingShingle Lucas Lum
Chong-Wei Tan
Chun Fei Siah
Kun Liang
Beng Kang Tay
Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing
Micromachines
carbon black
femtosecond laser annealing
ablation
nano-crystallisation
title Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing
title_full Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing
title_fullStr Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing
title_full_unstemmed Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing
title_short Graphitisation of Waste Carbon Powder with Femtosecond Laser Annealing
title_sort graphitisation of waste carbon powder with femtosecond laser annealing
topic carbon black
femtosecond laser annealing
ablation
nano-crystallisation
url https://www.mdpi.com/2072-666X/13/1/120
work_keys_str_mv AT lucaslum graphitisationofwastecarbonpowderwithfemtosecondlaserannealing
AT chongweitan graphitisationofwastecarbonpowderwithfemtosecondlaserannealing
AT chunfeisiah graphitisationofwastecarbonpowderwithfemtosecondlaserannealing
AT kunliang graphitisationofwastecarbonpowderwithfemtosecondlaserannealing
AT bengkangtay graphitisationofwastecarbonpowderwithfemtosecondlaserannealing