Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray

A bearing material in an artificial knee joint has to have good thermal and mechanical properties to prevent wear in order to be used as a tibial tray. Despite its well-known good properties, ultrahigh molecular weight polyethylene (UHMWPE) still needs to be modified to enhance its physical strength...

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Main Authors: Yusuf Bramastya Apriliyanto, Sri Sugiarti, Sulistioso Giat Sukaryo
Format: Article
Language:English
Published: Department of Chemistry, Universitas Gadjah Mada 2020-05-01
Series:Indonesian Journal of Chemistry
Subjects:
Online Access:https://jurnal.ugm.ac.id/ijc/article/view/44086
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author Yusuf Bramastya Apriliyanto
Sri Sugiarti
Sulistioso Giat Sukaryo
author_facet Yusuf Bramastya Apriliyanto
Sri Sugiarti
Sulistioso Giat Sukaryo
author_sort Yusuf Bramastya Apriliyanto
collection DOAJ
description A bearing material in an artificial knee joint has to have good thermal and mechanical properties to prevent wear in order to be used as a tibial tray. Despite its well-known good properties, ultrahigh molecular weight polyethylene (UHMWPE) still needs to be modified to enhance its physical strength in its use in artificial joints. In this research, composites made from UHMWPE and hydroxyapatite (HA) were prepared by mechanical alloying and hot press method and their thermal and mechanical properties were modified using gamma rays. The composites were prepared using various HA loading ratios and irradiated using gamma rays at doses of 0, 25, 50, and 75 kGy. The effects of HA loading and gamma irradiation on thermal and mechanical properties were studied by various methods. The results showed that the addition of HA enhanced the hardness of UHMWPE by 8–15% and the maximum stress up to 38%. Gamma irradiation enhanced the crystallinity by 113–172%, the melting point by 0.6–0.7%, and decreased the break elongation of composites by 23–48%. Addition of polyvinyl alcohol (5% w/w) in composites reduced their rigidity by 16–47% and hardness by 3–9%.
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spelling doaj.art-40a5424a5bde49f696cc3043771c15bd2022-12-21T21:19:43ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782020-05-0120359760710.22146/ijc.4408624804Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial TrayYusuf Bramastya Apriliyanto0Sri Sugiarti1Sulistioso Giat Sukaryo2Department of Chemistry, Bogor Agricultural University, Chemistry Building, Wing 1, 3rd Floor, Tanjung St., IPB Darmaga Campus, Bogor 16680, IndonesiaDepartment of Chemistry, Bogor Agricultural University, Chemistry Building, Wing 1, 3rd Floor, Tanjung St., IPB Darmaga Campus, Bogor 16680, IndonesiaCenter for Science and Advanced Material Technology, National Nuclear Energy Agency (PSTBM-BATAN), Puspiptek St., Tangsel-Banten 15314, IndonesiaA bearing material in an artificial knee joint has to have good thermal and mechanical properties to prevent wear in order to be used as a tibial tray. Despite its well-known good properties, ultrahigh molecular weight polyethylene (UHMWPE) still needs to be modified to enhance its physical strength in its use in artificial joints. In this research, composites made from UHMWPE and hydroxyapatite (HA) were prepared by mechanical alloying and hot press method and their thermal and mechanical properties were modified using gamma rays. The composites were prepared using various HA loading ratios and irradiated using gamma rays at doses of 0, 25, 50, and 75 kGy. The effects of HA loading and gamma irradiation on thermal and mechanical properties were studied by various methods. The results showed that the addition of HA enhanced the hardness of UHMWPE by 8–15% and the maximum stress up to 38%. Gamma irradiation enhanced the crystallinity by 113–172%, the melting point by 0.6–0.7%, and decreased the break elongation of composites by 23–48%. Addition of polyvinyl alcohol (5% w/w) in composites reduced their rigidity by 16–47% and hardness by 3–9%.https://jurnal.ugm.ac.id/ijc/article/view/44086tibial trayuhmwpe/ha compositesphysical propertiesirradiation, biomaterials
spellingShingle Yusuf Bramastya Apriliyanto
Sri Sugiarti
Sulistioso Giat Sukaryo
Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
Indonesian Journal of Chemistry
tibial tray
uhmwpe/ha composites
physical properties
irradiation, biomaterials
title Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
title_full Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
title_fullStr Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
title_full_unstemmed Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
title_short Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
title_sort enhancing thermal and mechanical properties of uhmwpe ha composite as tibial tray
topic tibial tray
uhmwpe/ha composites
physical properties
irradiation, biomaterials
url https://jurnal.ugm.ac.id/ijc/article/view/44086
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AT srisugiarti enhancingthermalandmechanicalpropertiesofuhmwpehacompositeastibialtray
AT sulistiosogiatsukaryo enhancingthermalandmechanicalpropertiesofuhmwpehacompositeastibialtray