Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray
A bearing material in an artificial knee joint has to have good thermal and mechanical properties to prevent wear in order to be used as a tibial tray. Despite its well-known good properties, ultrahigh molecular weight polyethylene (UHMWPE) still needs to be modified to enhance its physical strength...
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Format: | Article |
Language: | English |
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Department of Chemistry, Universitas Gadjah Mada
2020-05-01
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Series: | Indonesian Journal of Chemistry |
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Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/44086 |
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author | Yusuf Bramastya Apriliyanto Sri Sugiarti Sulistioso Giat Sukaryo |
author_facet | Yusuf Bramastya Apriliyanto Sri Sugiarti Sulistioso Giat Sukaryo |
author_sort | Yusuf Bramastya Apriliyanto |
collection | DOAJ |
description | A bearing material in an artificial knee joint has to have good thermal and mechanical properties to prevent wear in order to be used as a tibial tray. Despite its well-known good properties, ultrahigh molecular weight polyethylene (UHMWPE) still needs to be modified to enhance its physical strength in its use in artificial joints. In this research, composites made from UHMWPE and hydroxyapatite (HA) were prepared by mechanical alloying and hot press method and their thermal and mechanical properties were modified using gamma rays. The composites were prepared using various HA loading ratios and irradiated using gamma rays at doses of 0, 25, 50, and 75 kGy. The effects of HA loading and gamma irradiation on thermal and mechanical properties were studied by various methods. The results showed that the addition of HA enhanced the hardness of UHMWPE by 8–15% and the maximum stress up to 38%. Gamma irradiation enhanced the crystallinity by 113–172%, the melting point by 0.6–0.7%, and decreased the break elongation of composites by 23–48%. Addition of polyvinyl alcohol (5% w/w) in composites reduced their rigidity by 16–47% and hardness by 3–9%. |
first_indexed | 2024-12-18T05:18:54Z |
format | Article |
id | doaj.art-40a5424a5bde49f696cc3043771c15bd |
institution | Directory Open Access Journal |
issn | 1411-9420 2460-1578 |
language | English |
last_indexed | 2024-12-18T05:18:54Z |
publishDate | 2020-05-01 |
publisher | Department of Chemistry, Universitas Gadjah Mada |
record_format | Article |
series | Indonesian Journal of Chemistry |
spelling | doaj.art-40a5424a5bde49f696cc3043771c15bd2022-12-21T21:19:43ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782020-05-0120359760710.22146/ijc.4408624804Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial TrayYusuf Bramastya Apriliyanto0Sri Sugiarti1Sulistioso Giat Sukaryo2Department of Chemistry, Bogor Agricultural University, Chemistry Building, Wing 1, 3rd Floor, Tanjung St., IPB Darmaga Campus, Bogor 16680, IndonesiaDepartment of Chemistry, Bogor Agricultural University, Chemistry Building, Wing 1, 3rd Floor, Tanjung St., IPB Darmaga Campus, Bogor 16680, IndonesiaCenter for Science and Advanced Material Technology, National Nuclear Energy Agency (PSTBM-BATAN), Puspiptek St., Tangsel-Banten 15314, IndonesiaA bearing material in an artificial knee joint has to have good thermal and mechanical properties to prevent wear in order to be used as a tibial tray. Despite its well-known good properties, ultrahigh molecular weight polyethylene (UHMWPE) still needs to be modified to enhance its physical strength in its use in artificial joints. In this research, composites made from UHMWPE and hydroxyapatite (HA) were prepared by mechanical alloying and hot press method and their thermal and mechanical properties were modified using gamma rays. The composites were prepared using various HA loading ratios and irradiated using gamma rays at doses of 0, 25, 50, and 75 kGy. The effects of HA loading and gamma irradiation on thermal and mechanical properties were studied by various methods. The results showed that the addition of HA enhanced the hardness of UHMWPE by 8–15% and the maximum stress up to 38%. Gamma irradiation enhanced the crystallinity by 113–172%, the melting point by 0.6–0.7%, and decreased the break elongation of composites by 23–48%. Addition of polyvinyl alcohol (5% w/w) in composites reduced their rigidity by 16–47% and hardness by 3–9%.https://jurnal.ugm.ac.id/ijc/article/view/44086tibial trayuhmwpe/ha compositesphysical propertiesirradiation, biomaterials |
spellingShingle | Yusuf Bramastya Apriliyanto Sri Sugiarti Sulistioso Giat Sukaryo Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray Indonesian Journal of Chemistry tibial tray uhmwpe/ha composites physical properties irradiation, biomaterials |
title | Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray |
title_full | Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray |
title_fullStr | Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray |
title_full_unstemmed | Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray |
title_short | Enhancing Thermal and Mechanical Properties of UHMWPE/HA Composite as Tibial Tray |
title_sort | enhancing thermal and mechanical properties of uhmwpe ha composite as tibial tray |
topic | tibial tray uhmwpe/ha composites physical properties irradiation, biomaterials |
url | https://jurnal.ugm.ac.id/ijc/article/view/44086 |
work_keys_str_mv | AT yusufbramastyaapriliyanto enhancingthermalandmechanicalpropertiesofuhmwpehacompositeastibialtray AT srisugiarti enhancingthermalandmechanicalpropertiesofuhmwpehacompositeastibialtray AT sulistiosogiatsukaryo enhancingthermalandmechanicalpropertiesofuhmwpehacompositeastibialtray |