Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate
The title complex, [Ni(C12H8N2)2(H2O)2][Ni(CN)4]·C4H8O·H2O, consists of a cationic [Ni(C12H8N2)2(H2O)2]2+ unit, an anionic [Ni(CN)4]2− unit, one uncoordinated water and one tetrahydrofuran molecule. In the cationic unit, the Ni2+ atom is coordinated by four N...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810036974 |
| _version_ | 1819104952196268032 |
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| author | Jun Wang Zhi-li Fang |
| author_facet | Jun Wang Zhi-li Fang |
| author_sort | Jun Wang |
| collection | DOAJ |
| description | The title complex, [Ni(C12H8N2)2(H2O)2][Ni(CN)4]·C4H8O·H2O, consists of a cationic [Ni(C12H8N2)2(H2O)2]2+ unit, an anionic [Ni(CN)4]2− unit, one uncoordinated water and one tetrahydrofuran molecule. In the cationic unit, the Ni2+ atom is coordinated by four N atoms and two O atoms from two 1,10-phenanthroline ligands and two water molecules in a distorted octahedral coordination environment. In the anionic unit, the Ni2+ atom is in a square-planar coordination by four C atoms from four monodentate terminal cyanide ligands. O—H...N and O—H...O hydrogen bonds link neighboring cationic and anionic units, forming a three-dimensional supramolecular network. The interstitial tetrahydrofuran molecule is independently disordered over two sites in a 1:1 ratio. |
| first_indexed | 2024-12-22T02:14:31Z |
| format | Article |
| id | doaj.art-40b1ecbf6d5b4d249e15c78e7ed7e8c3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:14:31Z |
| publishDate | 2010-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-40b1ecbf6d5b4d249e15c78e7ed7e8c32022-12-21T18:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-10-016610m1285m128510.1107/S1600536810036974Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrateJun WangZhi-li FangThe title complex, [Ni(C12H8N2)2(H2O)2][Ni(CN)4]·C4H8O·H2O, consists of a cationic [Ni(C12H8N2)2(H2O)2]2+ unit, an anionic [Ni(CN)4]2− unit, one uncoordinated water and one tetrahydrofuran molecule. In the cationic unit, the Ni2+ atom is coordinated by four N atoms and two O atoms from two 1,10-phenanthroline ligands and two water molecules in a distorted octahedral coordination environment. In the anionic unit, the Ni2+ atom is in a square-planar coordination by four C atoms from four monodentate terminal cyanide ligands. O—H...N and O—H...O hydrogen bonds link neighboring cationic and anionic units, forming a three-dimensional supramolecular network. The interstitial tetrahydrofuran molecule is independently disordered over two sites in a 1:1 ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536810036974 |
| spellingShingle | Jun Wang Zhi-li Fang Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate Acta Crystallographica Section E |
| title | Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate |
| title_full | Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate |
| title_fullStr | Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate |
| title_full_unstemmed | Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate |
| title_short | Diaquabis(1,10-phenanthroline)nickel(II) tetrakis(cyanido-κC)nickelate(II) tetrahydrofuran solvate monohydrate |
| title_sort | diaquabis 1 10 phenanthroline nickel ii tetrakis cyanido amp 954 c nickelate ii tetrahydrofuran solvate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810036974 |
| work_keys_str_mv | AT junwang diaquabis110phenanthrolinenickeliitetrakiscyanidoamp954cnickelateiitetrahydrofuransolvatemonohydrate AT zhilifang diaquabis110phenanthrolinenickeliitetrakiscyanidoamp954cnickelateiitetrahydrofuransolvatemonohydrate |