Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red
The synthesis and characterization of layered double hydroxide (LDH) and intercalated polyoxometalate are presented. We have reported the growth of polyoxometalate on (Ni, Mg) layered double hydroxide for degradation procion red (PR). The degradation parameters and organic dye removal efficiency of...
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| Format: | Article |
| Language: | English |
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Polish Society of Ecological Engineering (PTIE)
2023-08-01
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| Series: | Ecological Engineering & Environmental Technology |
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| Online Access: | http://www.ecoeet.com/Polyoxometalate-Intercalated-Layered-Double-Hydroxide-for-Degradation-of-Procion,168088,0,2.html |
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| author | Yuliza Hanifah Risfidian Mohadi Mardiyanto Mardiyanto Aldes Lesbani |
| author_facet | Yuliza Hanifah Risfidian Mohadi Mardiyanto Mardiyanto Aldes Lesbani |
| author_sort | Yuliza Hanifah |
| collection | DOAJ |
| description | The synthesis and characterization of layered double hydroxide (LDH) and intercalated polyoxometalate are presented. We have reported the growth of polyoxometalate on (Ni, Mg) layered double hydroxide for degradation procion red (PR). The degradation parameters and organic dye removal efficiency of Zn/Mg-LDH and both composite LDH-polyoxometalate have been determined by considering factors such as pH of dye solution, catalyst dosage, and time as variables of degradation. X-Ray, FTIR, and SEM spectroscopy confirmed the layered double hydroxide structure. XRD and FTIR analysis confirmed the single-phase of the as-made and polyoxometalate intercalated LDH. SEM images show the formation of aggregates of small various sizes. The catalytic activity of the material was evaluated in the degradation of PR as a model pollutant. The result showed that MgAl-SiW12O40 has a good degradation capacity for PR as compared to MgAl-PW12O40, ZnAl-SiW12O40, and ZnAl-PW12O40. The result shows that the LDH composite presents stability and has good photocatalytic activities toward the reduction of procion red. The materials utilized for the fifth regeneration are indicated by the FTIR results, which verified the LDH composite structure. The PR’s photodegradation process for immaculate ZnAl-LDH, MgAl-LDH, ZnAl-[PW12O40], ZnAl-[SiW12O40], MgAl-[PW12O40], MgAl-[SiW12O40] were 68%, 70%, 56%, 79%, 74%, and 80%. The LDH-polyoxometalate composite material’s capacity to successfully photodegrade, as measured by the percentage of degradation, revealed an increase in photodegradation catalysis and the ability of LDH to regenerate. |
| first_indexed | 2024-03-13T00:32:45Z |
| format | Article |
| id | doaj.art-40c1541298e046ccb9cf7a1042e3baef |
| institution | Directory Open Access Journal |
| issn | 2719-7050 |
| language | English |
| last_indexed | 2024-03-13T00:32:45Z |
| publishDate | 2023-08-01 |
| publisher | Polish Society of Ecological Engineering (PTIE) |
| record_format | Article |
| series | Ecological Engineering & Environmental Technology |
| spelling | doaj.art-40c1541298e046ccb9cf7a1042e3baef2023-07-10T09:58:24ZengPolish Society of Ecological Engineering (PTIE)Ecological Engineering & Environmental Technology2719-70502023-08-0124610911610.12912/27197050/168088168088Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion RedYuliza Hanifah0https://orcid.org/0000-0003-4152-5367Risfidian Mohadi1https://orcid.org/0000-0003-4974-4329Mardiyanto Mardiyanto2https://orcid.org/0000-0002-2951-4123Aldes Lesbani3https://orcid.org/0000-0001-5054-2324Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km.32 OganIlir 30662, IndonesiaGraduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km.32 OganIlir 30662, IndonesiaDepartment of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km.32 OganIlir 30662, IndonesiaGraduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km.32 OganIlir 30662, IndonesiaThe synthesis and characterization of layered double hydroxide (LDH) and intercalated polyoxometalate are presented. We have reported the growth of polyoxometalate on (Ni, Mg) layered double hydroxide for degradation procion red (PR). The degradation parameters and organic dye removal efficiency of Zn/Mg-LDH and both composite LDH-polyoxometalate have been determined by considering factors such as pH of dye solution, catalyst dosage, and time as variables of degradation. X-Ray, FTIR, and SEM spectroscopy confirmed the layered double hydroxide structure. XRD and FTIR analysis confirmed the single-phase of the as-made and polyoxometalate intercalated LDH. SEM images show the formation of aggregates of small various sizes. The catalytic activity of the material was evaluated in the degradation of PR as a model pollutant. The result showed that MgAl-SiW12O40 has a good degradation capacity for PR as compared to MgAl-PW12O40, ZnAl-SiW12O40, and ZnAl-PW12O40. The result shows that the LDH composite presents stability and has good photocatalytic activities toward the reduction of procion red. The materials utilized for the fifth regeneration are indicated by the FTIR results, which verified the LDH composite structure. The PR’s photodegradation process for immaculate ZnAl-LDH, MgAl-LDH, ZnAl-[PW12O40], ZnAl-[SiW12O40], MgAl-[PW12O40], MgAl-[SiW12O40] were 68%, 70%, 56%, 79%, 74%, and 80%. The LDH-polyoxometalate composite material’s capacity to successfully photodegrade, as measured by the percentage of degradation, revealed an increase in photodegradation catalysis and the ability of LDH to regenerate.http://www.ecoeet.com/Polyoxometalate-Intercalated-Layered-Double-Hydroxide-for-Degradation-of-Procion,168088,0,2.htmlphotocatalyticldhpolyoxometalateprocion red |
| spellingShingle | Yuliza Hanifah Risfidian Mohadi Mardiyanto Mardiyanto Aldes Lesbani Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red Ecological Engineering & Environmental Technology photocatalytic ldh polyoxometalate procion red |
| title | Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red |
| title_full | Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red |
| title_fullStr | Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red |
| title_full_unstemmed | Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red |
| title_short | Polyoxometalate Intercalated Layered Double Hydroxide for Degradation of Procion Red |
| title_sort | polyoxometalate intercalated layered double hydroxide for degradation of procion red |
| topic | photocatalytic ldh polyoxometalate procion red |
| url | http://www.ecoeet.com/Polyoxometalate-Intercalated-Layered-Double-Hydroxide-for-Degradation-of-Procion,168088,0,2.html |
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