Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
Chlorinated polyethylene rubber (CM)/nitrile rubber (NBR) blend vulcanizates were prepared by mechanical blending method with CM and NBR as main raw materials, the cross-linking density of CM phase in CM/NBR blend vulcanizate and the stress-strain relationship of CM/NBR blend vulcaizate were charact...
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Format: | Article |
Language: | zho |
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Editorial Office of China Synthetic Rubber Industry
2024-12-01
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Series: | Hecheng xiangjiao gongye |
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Online Access: | http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202306002 |
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author | SUN Zhen-hao, DENG Tao |
author_facet | SUN Zhen-hao, DENG Tao |
author_sort | SUN Zhen-hao, DENG Tao |
collection | DOAJ |
description | Chlorinated polyethylene rubber (CM)/nitrile rubber (NBR) blend vulcanizates were prepared by mechanical blending method with CM and NBR as main raw materials, the cross-linking density of CM phase in CM/NBR blend vulcanizate and the stress-strain relationship of CM/NBR blend vulcaizate were characterized by regulating the dose of vulcanization system of CM phase in CM/NBR blend combined with the means of equilibrium swelling method, testing mechanical properties and theoretical calculation, and the influence of the change of cross-linking density of CM phase on matching degree of the modulus of two phase in CM/NBR blend vulcanizate and mechanical properties of CM/NBR blend vulcanizate were studied. The results showed that the change of the modulus of CM/NBR blend vulcanizate caused by the increase in cross-linking density of CM phase was greater than that of its own; with the increase of modulus, the influence of the change of cross-linking density of CM phase on the modulus of CM/NBR blend vulcanizate increased; by comparing the stress-strain relationship of CM phase and NBR phase in CM/NBR blend vulcanizate and the change of mechanical properties of CM/NBR blend vulcanizate, it was proved that the decrease of the cross-linking density of CM phase was a process of the gradual matching of the modulus of the two phase; compared with the error of the measured stress-strain relation, that of the stress-strain relationship predicted by fitting model was relatively smaller, which indicated that fitting model had certain applicability.
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first_indexed | 2024-03-08T17:23:35Z |
format | Article |
id | doaj.art-40c4a5469fde48b3899a2486d77d8332 |
institution | Directory Open Access Journal |
issn | 1000-1255 |
language | zho |
last_indexed | 2024-03-08T17:23:35Z |
publishDate | 2024-12-01 |
publisher | Editorial Office of China Synthetic Rubber Industry |
record_format | Article |
series | Hecheng xiangjiao gongye |
spelling | doaj.art-40c4a5469fde48b3899a2486d77d83322024-01-03T01:43:12ZzhoEditorial Office of China Synthetic Rubber IndustryHecheng xiangjiao gongye1000-12552024-12-0146645746410.19908/j.cnki.ISSN1000-1255.2023.06.0457Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phaseSUN Zhen-hao, DENG Tao0"School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China"Chlorinated polyethylene rubber (CM)/nitrile rubber (NBR) blend vulcanizates were prepared by mechanical blending method with CM and NBR as main raw materials, the cross-linking density of CM phase in CM/NBR blend vulcanizate and the stress-strain relationship of CM/NBR blend vulcaizate were characterized by regulating the dose of vulcanization system of CM phase in CM/NBR blend combined with the means of equilibrium swelling method, testing mechanical properties and theoretical calculation, and the influence of the change of cross-linking density of CM phase on matching degree of the modulus of two phase in CM/NBR blend vulcanizate and mechanical properties of CM/NBR blend vulcanizate were studied. The results showed that the change of the modulus of CM/NBR blend vulcanizate caused by the increase in cross-linking density of CM phase was greater than that of its own; with the increase of modulus, the influence of the change of cross-linking density of CM phase on the modulus of CM/NBR blend vulcanizate increased; by comparing the stress-strain relationship of CM phase and NBR phase in CM/NBR blend vulcanizate and the change of mechanical properties of CM/NBR blend vulcanizate, it was proved that the decrease of the cross-linking density of CM phase was a process of the gradual matching of the modulus of the two phase; compared with the error of the measured stress-strain relation, that of the stress-strain relationship predicted by fitting model was relatively smaller, which indicated that fitting model had certain applicability. http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202306002chlorinated polyethylene rubbernitrile rubbermechanical blendingvulcanizateequilibrium swelling methodcross-linking densityfitting modelmechanical property |
spellingShingle | SUN Zhen-hao, DENG Tao Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase Hecheng xiangjiao gongye chlorinated polyethylene rubber nitrile rubber mechanical blending vulcanizate equilibrium swelling method cross-linking density fitting model mechanical property |
title | Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase |
title_full | Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase |
title_fullStr | Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase |
title_full_unstemmed | Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase |
title_short | Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase |
title_sort | calculation of stress strain relationship of chlorinated polyethylene rubber nitrile rubber blend by regulating cross linking density of chlorinated polyethylene rubber phase |
topic | chlorinated polyethylene rubber nitrile rubber mechanical blending vulcanizate equilibrium swelling method cross-linking density fitting model mechanical property |
url | http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202306002 |
work_keys_str_mv | AT sunzhenhaodengtao calculationofstressstrainrelationshipofchlorinatedpolyethylenerubbernitrilerubberblendbyregulatingcrosslinkingdensityofchlorinatedpolyethylenerubberphase |