Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase

Chlorinated polyethylene rubber (CM)/nitrile rubber (NBR) blend vulcanizates were prepared by mechanical blending method with CM and NBR as main raw materials, the cross-linking density of CM phase in CM/NBR blend vulcanizate and the stress-strain relationship of CM/NBR blend vulcaizate were charact...

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Main Author: SUN Zhen-hao, DENG Tao
Format: Article
Language:zho
Published: Editorial Office of China Synthetic Rubber Industry 2024-12-01
Series:Hecheng xiangjiao gongye
Subjects:
Online Access:http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202306002
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author SUN Zhen-hao, DENG Tao
author_facet SUN Zhen-hao, DENG Tao
author_sort SUN Zhen-hao, DENG Tao
collection DOAJ
description Chlorinated polyethylene rubber (CM)/nitrile rubber (NBR) blend vulcanizates were prepared by mechanical blending method with CM and NBR as main raw materials, the cross-linking density of CM phase in CM/NBR blend vulcanizate and the stress-strain relationship of CM/NBR blend vulcaizate were characterized by regulating the dose of vulcanization system of CM phase in CM/NBR blend combined with the means of equilibrium swelling method, testing mechanical properties and theoretical calculation, and the influence of the change of cross-linking density of CM phase on matching degree of the modulus of two phase in CM/NBR blend vulcanizate and mechanical properties of CM/NBR blend vulcanizate were studied. The results showed that the change of the modulus of CM/NBR blend vulcanizate caused by the increase in cross-linking density of CM phase was greater than that of its own; with the increase of modulus, the influence of the change of cross-linking density of CM phase on the modulus of CM/NBR blend vulcanizate increased; by comparing the stress-strain relationship of CM phase and NBR phase in CM/NBR blend vulcanizate and the change of mechanical properties of CM/NBR blend vulcanizate, it was proved that the decrease of the cross-linking density of CM phase was a process of the gradual matching of the modulus of the two phase; compared with the error of the measured stress-strain relation, that of the stress-strain relationship predicted by fitting model was relatively smaller, which indicated that fitting model had certain applicability.
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spelling doaj.art-40c4a5469fde48b3899a2486d77d83322024-01-03T01:43:12ZzhoEditorial Office of China Synthetic Rubber IndustryHecheng xiangjiao gongye1000-12552024-12-0146645746410.19908/j.cnki.ISSN1000-1255.2023.06.0457Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phaseSUN Zhen-hao, DENG Tao0"School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China"Chlorinated polyethylene rubber (CM)/nitrile rubber (NBR) blend vulcanizates were prepared by mechanical blending method with CM and NBR as main raw materials, the cross-linking density of CM phase in CM/NBR blend vulcanizate and the stress-strain relationship of CM/NBR blend vulcaizate were characterized by regulating the dose of vulcanization system of CM phase in CM/NBR blend combined with the means of equilibrium swelling method, testing mechanical properties and theoretical calculation, and the influence of the change of cross-linking density of CM phase on matching degree of the modulus of two phase in CM/NBR blend vulcanizate and mechanical properties of CM/NBR blend vulcanizate were studied. The results showed that the change of the modulus of CM/NBR blend vulcanizate caused by the increase in cross-linking density of CM phase was greater than that of its own; with the increase of modulus, the influence of the change of cross-linking density of CM phase on the modulus of CM/NBR blend vulcanizate increased; by comparing the stress-strain relationship of CM phase and NBR phase in CM/NBR blend vulcanizate and the change of mechanical properties of CM/NBR blend vulcanizate, it was proved that the decrease of the cross-linking density of CM phase was a process of the gradual matching of the modulus of the two phase; compared with the error of the measured stress-strain relation, that of the stress-strain relationship predicted by fitting model was relatively smaller, which indicated that fitting model had certain applicability. http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202306002chlorinated polyethylene rubbernitrile rubbermechanical blendingvulcanizateequilibrium swelling methodcross-linking densityfitting modelmechanical property
spellingShingle SUN Zhen-hao, DENG Tao
Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
Hecheng xiangjiao gongye
chlorinated polyethylene rubber
nitrile rubber
mechanical blending
vulcanizate
equilibrium swelling method
cross-linking density
fitting model
mechanical property
title Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
title_full Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
title_fullStr Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
title_full_unstemmed Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
title_short Calculation of stress-strain relationship of chlorinated polyethylene rubber/nitrile rubber blend by regulating cross-linking density of chlorinated polyethylene rubber phase
title_sort calculation of stress strain relationship of chlorinated polyethylene rubber nitrile rubber blend by regulating cross linking density of chlorinated polyethylene rubber phase
topic chlorinated polyethylene rubber
nitrile rubber
mechanical blending
vulcanizate
equilibrium swelling method
cross-linking density
fitting model
mechanical property
url http://hcxjgy.paperopen.com/oa/DArticle.aspx?type=view&id=202306002
work_keys_str_mv AT sunzhenhaodengtao calculationofstressstrainrelationshipofchlorinatedpolyethylenerubbernitrilerubberblendbyregulatingcrosslinkingdensityofchlorinatedpolyethylenerubberphase