Oxygen impact and reactivity trials: A new perspective on emergency response precautions

The objective of this research was to verify and qualify what has been traditionally taught as fact during first responder's hazardous materials training regarding response precautions to and the likely behaviors of liquid oxygen (LOx) during a release. Subject matter experts disagreed that the...

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Main Authors: Andrew Byrnes, Clayton Rawson, Brian Patchett, Daniel DeMille, Merrill Halling
Format: Article
Language:English
Published: Elsevier 2023-03-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S240584402301681X
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author Andrew Byrnes
Clayton Rawson
Brian Patchett
Daniel DeMille
Merrill Halling
author_facet Andrew Byrnes
Clayton Rawson
Brian Patchett
Daniel DeMille
Merrill Halling
author_sort Andrew Byrnes
collection DOAJ
description The objective of this research was to verify and qualify what has been traditionally taught as fact during first responder's hazardous materials training regarding response precautions to and the likely behaviors of liquid oxygen (LOx) during a release. Subject matter experts disagreed that these precautions were well-founded in precedent or science. Findings showed that impact pressure causes a reaction in LOx and asphalt under specific conditions. These conditions are not realistic during an emergency response. No reactions were observed by combining LOx with common saturated and unsaturated hydrocarbons and alcohols. No reactions were observed driving fire apparatus through a LOx pool on asphalt. No reactions were observed by combining LOx and combustible materials. No reactions were observed when spark ignition was used as a source for combustion. Pilot ignition sources were introduced directly into a LOx pool on asphalt without a significant reaction. Immediate and violent reactions were observed when pilot ignition or arc ignition was used to initiate combustion when combustible materials were in an ultra-high gaseous or liquid oxygen environment. Without flaming or arc ignition sources, no reactions were observed.
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spelling doaj.art-40d71374773d4785b535d1a310f3d17f2023-04-05T08:25:47ZengElsevierHeliyon2405-84402023-03-0193e14474Oxygen impact and reactivity trials: A new perspective on emergency response precautionsAndrew Byrnes0Clayton Rawson1Brian Patchett2Daniel DeMille3Merrill Halling4Utah Valley University, Emergency Services, 3131 Mike Jense Parkway, Provo, UT 84601, USA; Corresponding author. Utah Valley University, 3131 Mike Jense Parkway, Provo, UT 84601, USA,Utah Valley University, Chemistry, 800 W. University Parkway, Orem, UT 84058, USAUtah Valley University, Physics, 800 W. University Parkway, Orem, UT 84058, USAUtah Valley University, Utah Fire and Rescue Academy, 3131 Mike Jense Parkway, Provo, UT 84601, USAUtah Valley University, Chemistry, 800 W. University Parkway, Orem, UT 84058, USAThe objective of this research was to verify and qualify what has been traditionally taught as fact during first responder's hazardous materials training regarding response precautions to and the likely behaviors of liquid oxygen (LOx) during a release. Subject matter experts disagreed that these precautions were well-founded in precedent or science. Findings showed that impact pressure causes a reaction in LOx and asphalt under specific conditions. These conditions are not realistic during an emergency response. No reactions were observed by combining LOx with common saturated and unsaturated hydrocarbons and alcohols. No reactions were observed driving fire apparatus through a LOx pool on asphalt. No reactions were observed by combining LOx and combustible materials. No reactions were observed when spark ignition was used as a source for combustion. Pilot ignition sources were introduced directly into a LOx pool on asphalt without a significant reaction. Immediate and violent reactions were observed when pilot ignition or arc ignition was used to initiate combustion when combustible materials were in an ultra-high gaseous or liquid oxygen environment. Without flaming or arc ignition sources, no reactions were observed.http://www.sciencedirect.com/science/article/pii/S240584402301681Ximpact PressureAdiabaticAsphaltCombustible materialsIgnitionCombustion
spellingShingle Andrew Byrnes
Clayton Rawson
Brian Patchett
Daniel DeMille
Merrill Halling
Oxygen impact and reactivity trials: A new perspective on emergency response precautions
Heliyon
impact Pressure
Adiabatic
Asphalt
Combustible materials
Ignition
Combustion
title Oxygen impact and reactivity trials: A new perspective on emergency response precautions
title_full Oxygen impact and reactivity trials: A new perspective on emergency response precautions
title_fullStr Oxygen impact and reactivity trials: A new perspective on emergency response precautions
title_full_unstemmed Oxygen impact and reactivity trials: A new perspective on emergency response precautions
title_short Oxygen impact and reactivity trials: A new perspective on emergency response precautions
title_sort oxygen impact and reactivity trials a new perspective on emergency response precautions
topic impact Pressure
Adiabatic
Asphalt
Combustible materials
Ignition
Combustion
url http://www.sciencedirect.com/science/article/pii/S240584402301681X
work_keys_str_mv AT andrewbyrnes oxygenimpactandreactivitytrialsanewperspectiveonemergencyresponseprecautions
AT claytonrawson oxygenimpactandreactivitytrialsanewperspectiveonemergencyresponseprecautions
AT brianpatchett oxygenimpactandreactivitytrialsanewperspectiveonemergencyresponseprecautions
AT danieldemille oxygenimpactandreactivitytrialsanewperspectiveonemergencyresponseprecautions
AT merrillhalling oxygenimpactandreactivitytrialsanewperspectiveonemergencyresponseprecautions