Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate

The title compound (2) was prepared in high yield by catalytic transfer hydrogenation of the 6-nitro precursor (1), using hydrazine hydrate as the hydrogen source. Under the conditions employed, the ester groups remain unaffected. The new compound was fully characterised by elemental analysis, 1H-NM...

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Main Authors: Norbert Haider, Katharina Tropper
Format: Article
Language:English
Published: MDPI AG 2015-03-01
Series:Molbank
Subjects:
Online Access:http://www.mdpi.com/1422-8599/2015/1/M849
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author Norbert Haider
Katharina Tropper
author_facet Norbert Haider
Katharina Tropper
author_sort Norbert Haider
collection DOAJ
description The title compound (2) was prepared in high yield by catalytic transfer hydrogenation of the 6-nitro precursor (1), using hydrazine hydrate as the hydrogen source. Under the conditions employed, the ester groups remain unaffected. The new compound was fully characterised by elemental analysis, 1H-NMR, 13C-NMR, MS and HRMS data.
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spelling doaj.art-40e11299a2d94a0cb58688eb764b83302022-12-22T01:59:14ZengMDPI AGMolbank1422-85992015-03-0120151M84910.3390/M849M849Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylateNorbert Haider0Katharina Tropper1Department of Pharmaceutical Chemistry, Faculty of Life Sciences, University of Vienna, Althanstraße 14, A-1090 Vienna, AustriaDepartment of Pharmaceutical Chemistry, Faculty of Life Sciences, University of Vienna, Althanstraße 14, A-1090 Vienna, AustriaThe title compound (2) was prepared in high yield by catalytic transfer hydrogenation of the 6-nitro precursor (1), using hydrazine hydrate as the hydrogen source. Under the conditions employed, the ester groups remain unaffected. The new compound was fully characterised by elemental analysis, 1H-NMR, 13C-NMR, MS and HRMS data.http://www.mdpi.com/1422-8599/2015/1/M849catalytic transfer hydrogenationhydrazine hydrateaminocarbazoles
spellingShingle Norbert Haider
Katharina Tropper
Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate
Molbank
catalytic transfer hydrogenation
hydrazine hydrate
aminocarbazoles
title Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate
title_full Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate
title_fullStr Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate
title_full_unstemmed Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate
title_short Dimethyl 6-Amino-1-methyl-9H-carbazole-2,3-dicarboxylate
title_sort dimethyl 6 amino 1 methyl 9h carbazole 2 3 dicarboxylate
topic catalytic transfer hydrogenation
hydrazine hydrate
aminocarbazoles
url http://www.mdpi.com/1422-8599/2015/1/M849
work_keys_str_mv AT norberthaider dimethyl6amino1methyl9hcarbazole23dicarboxylate
AT katharinatropper dimethyl6amino1methyl9hcarbazole23dicarboxylate