1-(2-Chlorophenyl)-3-(2-ethylhexanoyl)thiourea

In the title compound, C15H21ClN2OS, the central chromophore moiety (C2N2OS) is approximately planar, with a maximum deviation of −0.027 (1) Å, and is oriented at a dihedral angle of 86.7 (1)° with respect to the chlorophenyl ring. An intramo...

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Bibliographic Details
Main Authors: N. Radha, Bohari M. Yamin, K. Ramamurthi, S. Selvanayagam, R. Santhakumari
Format: Article
Language:English
Published: International Union of Crystallography 2013-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681301828X
Description
Summary:In the title compound, C15H21ClN2OS, the central chromophore moiety (C2N2OS) is approximately planar, with a maximum deviation of −0.027 (1) Å, and is oriented at a dihedral angle of 86.7 (1)° with respect to the chlorophenyl ring. An intramolecular N—H...O hydrogen bond stabilizes the molecular conformation. In the crystal, molecules associate via N—H...S hydrogen bonds, forming inversion dimers with motif R22(8). These dimers are further connected by N—H...O hydrogen bonds, forming R22(12) dimers. As a result, hydrogen-bonded chains running along [110] are formed. C—H...S interactions also occur. The terminal two C atoms of the butyl chain are disordered over two positions with an occupancy ratio of 0.54:0.46.
ISSN:1600-5368