Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells

Abstract Semiconductor photovoltaics have been investigated for many years, and various materials and device architectures have been developed aiming for low cost and high efficiency. Despite the critical advances in the field, there are confusions in understanding such diode based solar cells, espe...

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Main Author: Jizheng Wang
Format: Article
Language:English
Published: Wiley 2022-11-01
Series:EcoMat
Subjects:
Online Access:https://doi.org/10.1002/eom2.12263
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author Jizheng Wang
author_facet Jizheng Wang
author_sort Jizheng Wang
collection DOAJ
description Abstract Semiconductor photovoltaics have been investigated for many years, and various materials and device architectures have been developed aiming for low cost and high efficiency. Despite the critical advances in the field, there are confusions in understanding such diode based solar cells, especially on open‐circuit voltage and fill factor. This review intends to provide a succinct summary and interpretation for the core elements that are related to a solar cell device. First, the fundamental concepts of PN junction and diode solar cell are introduced. Second, Fermi and quasi‐Fermi levels are described, followed by understanding open‐circuit voltage and fill factor. Thirdly, the effects of heterojunction band offset are discussed. In the end, a brief conclusion is presented.
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spelling doaj.art-410db524667f40e2affdbbafabdba7732022-12-22T04:36:36ZengWileyEcoMat2567-31732022-11-0146n/an/a10.1002/eom2.12263Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cellsJizheng Wang0Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids Institute of Chemistry, Chinese Academy of Sciences Beijing People's Republic of ChinaAbstract Semiconductor photovoltaics have been investigated for many years, and various materials and device architectures have been developed aiming for low cost and high efficiency. Despite the critical advances in the field, there are confusions in understanding such diode based solar cells, especially on open‐circuit voltage and fill factor. This review intends to provide a succinct summary and interpretation for the core elements that are related to a solar cell device. First, the fundamental concepts of PN junction and diode solar cell are introduced. Second, Fermi and quasi‐Fermi levels are described, followed by understanding open‐circuit voltage and fill factor. Thirdly, the effects of heterojunction band offset are discussed. In the end, a brief conclusion is presented.https://doi.org/10.1002/eom2.12263band offsetdiodeFermi levelfill factoropen‐circuit voltagePN junction
spellingShingle Jizheng Wang
Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells
EcoMat
band offset
diode
Fermi level
fill factor
open‐circuit voltage
PN junction
title Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells
title_full Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells
title_fullStr Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells
title_full_unstemmed Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells
title_short Open‐circuit voltage, fill factor, and heterojunction band offset in semiconductor diode solar cells
title_sort open circuit voltage fill factor and heterojunction band offset in semiconductor diode solar cells
topic band offset
diode
Fermi level
fill factor
open‐circuit voltage
PN junction
url https://doi.org/10.1002/eom2.12263
work_keys_str_mv AT jizhengwang opencircuitvoltagefillfactorandheterojunctionbandoffsetinsemiconductordiodesolarcells