Micro and nanosized materials with high entropy

The stability of high-entropy alloys, like equiatomic and non-equiatomic micro- and nanostructural ones, is relevant when creating stable multicomponent compositions with improved performance. The implementation of such materials is possible by mechanical alloying, magnetron sputtering, as well as b...

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Main Authors: E.D. Kurbanova, R.M. Belyakova, V.A. Polukhin
Format: Article
Language:Russian
Published: Tver State University 2023-12-01
Series:Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
Subjects:
Online Access:https://physchemaspects.ru/2023/doi-10-26456-pcascnn-2023-15-472/?lang=en
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author E.D. Kurbanova
R.M. Belyakova
V.A. Polukhin
author_facet E.D. Kurbanova
R.M. Belyakova
V.A. Polukhin
author_sort E.D. Kurbanova
collection DOAJ
description The stability of high-entropy alloys, like equiatomic and non-equiatomic micro- and nanostructural ones, is relevant when creating stable multicomponent compositions with improved performance. The implementation of such materials is possible by mechanical alloying, magnetron sputtering, as well as by the electrochemical method using the «top-down and bottom-to-top» strategy at moderate temperatures < 200°C with controlled production of both micro-from 0,5 to 20 μm and nanoscale high-entropy alloys with particles from 2 to 10 nm. The well-studied «structure-property» relationship for classical alloys is not yet completely clear for nano-high-entropy alloys, but it is obvious that it is possible to form excellent mechanical characteristics by selecting chemical compositions and a special heat treatment regime. Regarding the chemical composition, requirements are imposed both on the main components and alloying additives. Preliminarily, not only compositions are selected, but also methods for the synthesis of high-entropy alloys, including ab initio (density functional theory), neural network prediction, and classical molecular dynamic simulation with possible conditions for the formation of model nano- high-entropy alloy samples, as well as derivative options. The resulting descriptions are compared with real methods of high-entropy alloys synthesis, for example, exposure to various synthetic media.
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spelling doaj.art-412705989ccc44dc851db5c1b50badc92023-12-03T11:38:31ZrusTver State UniversityФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов2226-44422658-43602023-12-011547248010.26456/pcascnn/2023.15.472Micro and nanosized materials with high entropyE.D. Kurbanova0R.M. Belyakova1V.A. Polukhin2Institute of Metallurgy of the Ural Branch of the RAS, Yekaterinburg, Russia Institute of Metallurgy of the Ural Branch of the RAS, Yekaterinburg, Russia Institute of Metallurgy of the Ural Branch of the RAS, Yekaterinburg, Russia The stability of high-entropy alloys, like equiatomic and non-equiatomic micro- and nanostructural ones, is relevant when creating stable multicomponent compositions with improved performance. The implementation of such materials is possible by mechanical alloying, magnetron sputtering, as well as by the electrochemical method using the «top-down and bottom-to-top» strategy at moderate temperatures < 200°C with controlled production of both micro-from 0,5 to 20 μm and nanoscale high-entropy alloys with particles from 2 to 10 nm. The well-studied «structure-property» relationship for classical alloys is not yet completely clear for nano-high-entropy alloys, but it is obvious that it is possible to form excellent mechanical characteristics by selecting chemical compositions and a special heat treatment regime. Regarding the chemical composition, requirements are imposed both on the main components and alloying additives. Preliminarily, not only compositions are selected, but also methods for the synthesis of high-entropy alloys, including ab initio (density functional theory), neural network prediction, and classical molecular dynamic simulation with possible conditions for the formation of model nano- high-entropy alloy samples, as well as derivative options. The resulting descriptions are compared with real methods of high-entropy alloys synthesis, for example, exposure to various synthetic media.https://physchemaspects.ru/2023/doi-10-26456-pcascnn-2023-15-472/?lang=enmulticomponentamorphous and nanocrystalline alloyshigh-entropy alloysnano- high-entropy alloysstrain hardeninglandscape-local fluctuationsstrengththermal stabilitylayered compositesthermodynamic calculations
spellingShingle E.D. Kurbanova
R.M. Belyakova
V.A. Polukhin
Micro and nanosized materials with high entropy
Физико-химические аспекты изучения кластеров, наноструктур и наноматериалов
multicomponent
amorphous and nanocrystalline alloys
high-entropy alloys
nano- high-entropy alloys
strain hardening
landscape-local fluctuations
strength
thermal stability
layered composites
thermodynamic calculations
title Micro and nanosized materials with high entropy
title_full Micro and nanosized materials with high entropy
title_fullStr Micro and nanosized materials with high entropy
title_full_unstemmed Micro and nanosized materials with high entropy
title_short Micro and nanosized materials with high entropy
title_sort micro and nanosized materials with high entropy
topic multicomponent
amorphous and nanocrystalline alloys
high-entropy alloys
nano- high-entropy alloys
strain hardening
landscape-local fluctuations
strength
thermal stability
layered composites
thermodynamic calculations
url https://physchemaspects.ru/2023/doi-10-26456-pcascnn-2023-15-472/?lang=en
work_keys_str_mv AT edkurbanova microandnanosizedmaterialswithhighentropy
AT rmbelyakova microandnanosizedmaterialswithhighentropy
AT vapolukhin microandnanosizedmaterialswithhighentropy