Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods

Zinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H2O2), based on the prepared ZnO NRs, was examined through the use of current-voltage measurements....

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Main Authors: Naif H. Al-Hardan, Muhammad Azmi Abdul Hamid, Roslinda Shamsudin, Norinsan Kamil Othman, Lim Kar Keng
Format: Article
Language:English
Published: MDPI AG 2016-06-01
Series:Sensors
Subjects:
Online Access:http://www.mdpi.com/1424-8220/16/7/1004
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author Naif H. Al-Hardan
Muhammad Azmi Abdul Hamid
Roslinda Shamsudin
Norinsan Kamil Othman
Lim Kar Keng
author_facet Naif H. Al-Hardan
Muhammad Azmi Abdul Hamid
Roslinda Shamsudin
Norinsan Kamil Othman
Lim Kar Keng
author_sort Naif H. Al-Hardan
collection DOAJ
description Zinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H2O2), based on the prepared ZnO NRs, was examined through the use of current-voltage measurements. The measured currents, as a function of H2O2 concentrations ranging from 10 μM to 700 μM, revealed two distinct behaviours and good performance, with a lower detection limit (LOD) of 42 μM for the low range of H2O2 concentrations (first region), and a LOD of 143.5 μM for the higher range of H2O2 concentrations (second region). The prepared ZnO NRs show excellent electrocatalytic activity. This enables a measurable and stable output current. The results were correlated with the oxidation process of the H2O2 and revealed a good performance for the ZnO NR non-enzymatic H2O2 sensor.
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spelling doaj.art-41287a977380462fb51bfccd42248cb92022-12-22T04:00:51ZengMDPI AGSensors1424-82202016-06-01167100410.3390/s16071004s16071004Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide NanorodsNaif H. Al-Hardan0Muhammad Azmi Abdul Hamid1Roslinda Shamsudin2Norinsan Kamil Othman3Lim Kar Keng4School of Applied Physics, Faculty of Science & Technology, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, MalaysiaSchool of Applied Physics, Faculty of Science & Technology, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, MalaysiaSchool of Applied Physics, Faculty of Science & Technology, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, MalaysiaSchool of Applied Physics, Faculty of Science & Technology, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, MalaysiaSchool of Applied Physics, Faculty of Science & Technology, Universiti Kebangsaan Malaysia (UKM), Bangi 43600, MalaysiaZinc oxide (ZnO) nanorods (NRs) have been synthesized via the hydrothermal process. The NRs were grown over a conductive glass substrate. A non-enzymatic electrochemical sensor for hydrogen peroxide (H2O2), based on the prepared ZnO NRs, was examined through the use of current-voltage measurements. The measured currents, as a function of H2O2 concentrations ranging from 10 μM to 700 μM, revealed two distinct behaviours and good performance, with a lower detection limit (LOD) of 42 μM for the low range of H2O2 concentrations (first region), and a LOD of 143.5 μM for the higher range of H2O2 concentrations (second region). The prepared ZnO NRs show excellent electrocatalytic activity. This enables a measurable and stable output current. The results were correlated with the oxidation process of the H2O2 and revealed a good performance for the ZnO NR non-enzymatic H2O2 sensor.http://www.mdpi.com/1424-8220/16/7/1004non-enzymatic biosensorzinc oxidenanorodshydrogen peroxide
spellingShingle Naif H. Al-Hardan
Muhammad Azmi Abdul Hamid
Roslinda Shamsudin
Norinsan Kamil Othman
Lim Kar Keng
Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
Sensors
non-enzymatic biosensor
zinc oxide
nanorods
hydrogen peroxide
title Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_full Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_fullStr Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_full_unstemmed Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_short Amperometric Non-Enzymatic Hydrogen Peroxide Sensor Based on Aligned Zinc Oxide Nanorods
title_sort amperometric non enzymatic hydrogen peroxide sensor based on aligned zinc oxide nanorods
topic non-enzymatic biosensor
zinc oxide
nanorods
hydrogen peroxide
url http://www.mdpi.com/1424-8220/16/7/1004
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AT roslindashamsudin amperometricnonenzymatichydrogenperoxidesensorbasedonalignedzincoxidenanorods
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