Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation
Since 2020, 0.5% limits on the sulfur content of marine fuels have been in effect worldwide. One way to achieve this value is to mix the residual sulfur and distillate low sulfur components. The main problem with this method is the possibility of sedimentation instability of the compounded residual...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-07-01
|
| Series: | Journal of Marine Science and Engineering |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2077-1312/10/8/1017 |
| _version_ | 1797444289283751936 |
|---|---|
| author | Vladimir G. Povarov Ignaty Efimov Ksenia I. Smyshlyaeva Viacheslav A. Rudko |
| author_facet | Vladimir G. Povarov Ignaty Efimov Ksenia I. Smyshlyaeva Viacheslav A. Rudko |
| author_sort | Vladimir G. Povarov |
| collection | DOAJ |
| description | Since 2020, 0.5% limits on the sulfur content of marine fuels have been in effect worldwide. One way to achieve this value is to mix the residual sulfur and distillate low sulfur components. The main problem with this method is the possibility of sedimentation instability of the compounded residual marine fuel due to sedimentation of asphaltenes. In this paper, the application of the UNIFAC group solution model for calculating the solubility of asphaltenes in hydrocarbons is considered. This model makes it possible to represent organic compounds as a set of functional groups (ACH, AC, CH<sub>2</sub>, CH<sub>3</sub>), the qualitative and quantitative composition of which determines the thermodynamic properties of the solution. According to the asphaltene composition, average molecular weight (450–2500 mol/L) and group theories of solutions, a method for predicting the sedimentation stability of compounded residual marine fuels was proposed. The effect of the heat of fusion, temperature of fusion, molecular weight, and group composition on the solubility of asphaltenes in marine fuel has been evaluated. The comparison of the model approach with the data obtained experimentally is carried out. The results obtained make it possible to predict the sedimentation stability of the fuel system depending on the structure and composition of asphaltenes. |
| first_indexed | 2024-03-09T13:09:27Z |
| format | Article |
| id | doaj.art-4137de3087b24d3aa315247db7c65527 |
| institution | Directory Open Access Journal |
| issn | 2077-1312 |
| language | English |
| last_indexed | 2024-03-09T13:09:27Z |
| publishDate | 2022-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Journal of Marine Science and Engineering |
| spelling | doaj.art-4137de3087b24d3aa315247db7c655272023-11-30T21:43:14ZengMDPI AGJournal of Marine Science and Engineering2077-13122022-07-01108101710.3390/jmse10081017Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility CalculationVladimir G. Povarov0Ignaty Efimov1Ksenia I. Smyshlyaeva2Viacheslav A. Rudko3Scientific Center “Issues of Processing Mineral and Technogenic Resources”, Saint Petersburg Mining University, 199106 St. Petersburg, RussiaScientific Center “Issues of Processing Mineral and Technogenic Resources”, Saint Petersburg Mining University, 199106 St. Petersburg, RussiaScientific Center “Issues of Processing Mineral and Technogenic Resources”, Saint Petersburg Mining University, 199106 St. Petersburg, RussiaScientific Center “Issues of Processing Mineral and Technogenic Resources”, Saint Petersburg Mining University, 199106 St. Petersburg, RussiaSince 2020, 0.5% limits on the sulfur content of marine fuels have been in effect worldwide. One way to achieve this value is to mix the residual sulfur and distillate low sulfur components. The main problem with this method is the possibility of sedimentation instability of the compounded residual marine fuel due to sedimentation of asphaltenes. In this paper, the application of the UNIFAC group solution model for calculating the solubility of asphaltenes in hydrocarbons is considered. This model makes it possible to represent organic compounds as a set of functional groups (ACH, AC, CH<sub>2</sub>, CH<sub>3</sub>), the qualitative and quantitative composition of which determines the thermodynamic properties of the solution. According to the asphaltene composition, average molecular weight (450–2500 mol/L) and group theories of solutions, a method for predicting the sedimentation stability of compounded residual marine fuels was proposed. The effect of the heat of fusion, temperature of fusion, molecular weight, and group composition on the solubility of asphaltenes in marine fuel has been evaluated. The comparison of the model approach with the data obtained experimentally is carried out. The results obtained make it possible to predict the sedimentation stability of the fuel system depending on the structure and composition of asphaltenes.https://www.mdpi.com/2077-1312/10/8/1017SARAGCMSternary phase diagramsTSAasphaltenesUNIFAC |
| spellingShingle | Vladimir G. Povarov Ignaty Efimov Ksenia I. Smyshlyaeva Viacheslav A. Rudko Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation Journal of Marine Science and Engineering SARA GCMS ternary phase diagrams TSA asphaltenes UNIFAC |
| title | Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation |
| title_full | Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation |
| title_fullStr | Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation |
| title_full_unstemmed | Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation |
| title_short | Application of the UNIFAC Model for the Low-Sulfur Residue Marine Fuel Asphaltenes Solubility Calculation |
| title_sort | application of the unifac model for the low sulfur residue marine fuel asphaltenes solubility calculation |
| topic | SARA GCMS ternary phase diagrams TSA asphaltenes UNIFAC |
| url | https://www.mdpi.com/2077-1312/10/8/1017 |
| work_keys_str_mv | AT vladimirgpovarov applicationoftheunifacmodelforthelowsulfurresiduemarinefuelasphaltenessolubilitycalculation AT ignatyefimov applicationoftheunifacmodelforthelowsulfurresiduemarinefuelasphaltenessolubilitycalculation AT kseniaismyshlyaeva applicationoftheunifacmodelforthelowsulfurresiduemarinefuelasphaltenessolubilitycalculation AT viacheslavarudko applicationoftheunifacmodelforthelowsulfurresiduemarinefuelasphaltenessolubilitycalculation |