Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate]
The title compound, Mn4(H2O)4[Ge(OH)2(HPO4)2(PO4)2], was synthesized by the solvothermal method. Its crystal structure is isotypic with the iron and cobalt analogues [Huang et al. (2012). Inorg. Chem. 51, 3316–3323]. In the crystal structure, the framework is built from undulating mang...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681201673X |
| _version_ | 1818997293325484032 |
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| author | Jin-Xiao Mi Xin Zhang Hong-Ming Chen Lei Wen Ya-Xi Huang |
| author_facet | Jin-Xiao Mi Xin Zhang Hong-Ming Chen Lei Wen Ya-Xi Huang |
| author_sort | Jin-Xiao Mi |
| collection | DOAJ |
| description | The title compound, Mn4(H2O)4[Ge(OH)2(HPO4)2(PO4)2], was synthesized by the solvothermal method. Its crystal structure is isotypic with the iron and cobalt analogues [Huang et al. (2012). Inorg. Chem. 51, 3316–3323]. In the crystal structure, the framework is built from undulating manganese phosphate sheets parallel to (010) interconnected by GeO6 octahedra (at the inversion center), resulting in a three-dimensional network with eight-membered ring channels into which all the protons point. The undulating manganese phosphate sheet consists of zigzag manganese octahedral chains along [10-1], built from MnO4(OH)(OH2) octahedra and MnO5(OH2) octahedra by sharing their trans or skew edges, which are interconnected by PO3(OH) and PO4 tetrahedra via corner-sharing. The crystal structure features extensive O—H...O hydrogen-bonding interactions. |
| first_indexed | 2024-12-20T21:43:20Z |
| format | Article |
| id | doaj.art-413f782384764d9b8e23a3e0157e8267 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:43:20Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-413f782384764d9b8e23a3e0157e82672022-12-21T19:25:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685i37i3810.1107/S160053681201673XTetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate]Jin-Xiao MiXin ZhangHong-Ming ChenLei WenYa-Xi HuangThe title compound, Mn4(H2O)4[Ge(OH)2(HPO4)2(PO4)2], was synthesized by the solvothermal method. Its crystal structure is isotypic with the iron and cobalt analogues [Huang et al. (2012). Inorg. Chem. 51, 3316–3323]. In the crystal structure, the framework is built from undulating manganese phosphate sheets parallel to (010) interconnected by GeO6 octahedra (at the inversion center), resulting in a three-dimensional network with eight-membered ring channels into which all the protons point. The undulating manganese phosphate sheet consists of zigzag manganese octahedral chains along [10-1], built from MnO4(OH)(OH2) octahedra and MnO5(OH2) octahedra by sharing their trans or skew edges, which are interconnected by PO3(OH) and PO4 tetrahedra via corner-sharing. The crystal structure features extensive O—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S160053681201673X |
| spellingShingle | Jin-Xiao Mi Xin Zhang Hong-Ming Chen Lei Wen Ya-Xi Huang Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate] Acta Crystallographica Section E |
| title | Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate] |
| title_full | Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate] |
| title_fullStr | Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate] |
| title_full_unstemmed | Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate] |
| title_short | Tetraaquatetramanganese(II) catena-[germanodihydroxidodi(hydrogenphosphate)diphosphate] |
| title_sort | tetraaquatetramanganese ii catena germanodihydroxidodi hydrogenphosphate diphosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681201673X |
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