Effect of Yttrium on Microstructure and Magnetocaloric Properties in La<sub>1−x</sub>Y<sub>x</sub>Fe<sub>11.5</sub>Si<sub>1.5</sub> Compounds

The effects of Y on the phase composition and magnetocaloric effect in La<sub>1&#8722;x</sub>Y<sub>x</sub>Fe<sub>11.5</sub>Si<sub>1.5</sub> compounds were studied. Y<sub>2</sub>Fe<sub>17</sub>-type phase and &#945;-Fe ph...

Full description

Bibliographic Details
Main Authors: Yuanyuan Wu, Jianing Xue, Chang Liu, He Zhou, Yi Long
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/8/11/2198
Description
Summary:The effects of Y on the phase composition and magnetocaloric effect in La<sub>1&#8722;x</sub>Y<sub>x</sub>Fe<sub>11.5</sub>Si<sub>1.5</sub> compounds were studied. Y<sub>2</sub>Fe<sub>17</sub>-type phase and &#945;-Fe phase appear in the annealed La<sub>1&#8722;x</sub>Y<sub>x</sub>Fe<sub>11.5</sub>Si<sub>1.5</sub> compounds when x &#8805; 0.07 due to small solid solubility of Y in NaZn<sub>13</sub> phase. Y<sub>2</sub>Fe<sub>17</sub> phase obstructs the formation of the 1:13 phase, leading to the decrease of magnetic entropy changes. But for x &lt; 0.1, La<sub>1&#8722;x</sub>Y<sub>x</sub>Fe<sub>11.5</sub>Si<sub>1.5</sub> compounds exhibit high magnetic entropy changes and low hysteresis loss compared with that of LaFe<sub>11.5</sub>Si<sub>1.5</sub>. Consequently, the La<sub>1&#8722;x</sub>Y<sub>x</sub>Fe<sub>11.5</sub>Si<sub>1.5</sub> compounds (x &lt; 0.1) are useful to realize large magnetocaloric effect with smaller hysteresis loss.
ISSN:2076-3417