[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II)
The NiII atom in the title complex, [Ni(C11H13N3OS)(C5H5N)], exists within a square-planar N3O donor set provided by N,N′,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N fi...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812026177 |
| _version_ | 1818321402449625088 |
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| author | Reza Takjoo Seik Weng Ng Edward R. T. Tiekink |
| author_facet | Reza Takjoo Seik Weng Ng Edward R. T. Tiekink |
| author_sort | Reza Takjoo |
| collection | DOAJ |
| description | The NiII atom in the title complex, [Ni(C11H13N3OS)(C5H5N)], exists within a square-planar N3O donor set provided by N,N′,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N five-membered chelate bite angle of 83.28 (12)°. The pyridine molecule forms a dihedral angle of 44.43 (6)° with the N3O donor set. Supramolecular stacks along the a axis mediated by alternating π–π interactions between the pyridine and five- [centroid–centroid distance = 3.4784 (16) Å] and six-membered [3.4633 (17) Å] chelate rings, feature in the crystal packing. |
| first_indexed | 2024-12-13T10:40:20Z |
| format | Article |
| id | doaj.art-41c5515caafb4ded87ba12db05e53098 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:40:20Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-41c5515caafb4ded87ba12db05e530982022-12-21T23:50:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687m911m91110.1107/S1600536812026177[2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II)Reza TakjooSeik Weng NgEdward R. T. TiekinkThe NiII atom in the title complex, [Ni(C11H13N3OS)(C5H5N)], exists within a square-planar N3O donor set provided by N,N′,O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N—Ni—N five-membered chelate bite angle of 83.28 (12)°. The pyridine molecule forms a dihedral angle of 44.43 (6)° with the N3O donor set. Supramolecular stacks along the a axis mediated by alternating π–π interactions between the pyridine and five- [centroid–centroid distance = 3.4784 (16) Å] and six-membered [3.4633 (17) Å] chelate rings, feature in the crystal packing.http://scripts.iucr.org/cgi-bin/paper?S1600536812026177 |
| spellingShingle | Reza Takjoo Seik Weng Ng Edward R. T. Tiekink [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II) Acta Crystallographica Section E |
| title | [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II) |
| title_full | [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II) |
| title_fullStr | [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II) |
| title_full_unstemmed | [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II) |
| title_short | [2-(1-{2-[Azanidyl(ethylsulfanyl)methylidene-κN]hydrazin-1-ylidene-κN1}ethyl)phenolato-κO](pyridine-κN)nickel(II) |
| title_sort | 2 1 2 azanidyl ethylsulfanyl methylidene amp 954 n hydrazin 1 ylidene amp 954 n1 ethyl phenolato amp 954 o pyridine amp 954 n nickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812026177 |
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