Survey of CH3NH2 and its Formation Process

We present the observational results of a precursor of glycine, methylamine (CH _3 NH _2 ), together with methanol (CH _3 OH) and methanimine (CH _2 NH) for the high-mass star-forming regions NGC 6334I, G10.47+0.03, G31.41+0.3, and W51 e1/e2 using the Atacama Large Millimeter/submillimeter Array. Th...

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Main Authors: Taiki Suzuki, Liton Majumdar, Paul F. Goldsmith, Kazuki Tokuda, Harumi Minamoto, Masatoshi Ohishi, Masao Saito, Tomoya Hirota, Hideko Nomura, Yoko Oya
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:The Astrophysical Journal
Subjects:
Online Access:https://doi.org/10.3847/1538-4357/acdb6d
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author Taiki Suzuki
Liton Majumdar
Paul F. Goldsmith
Kazuki Tokuda
Harumi Minamoto
Masatoshi Ohishi
Masao Saito
Tomoya Hirota
Hideko Nomura
Yoko Oya
author_facet Taiki Suzuki
Liton Majumdar
Paul F. Goldsmith
Kazuki Tokuda
Harumi Minamoto
Masatoshi Ohishi
Masao Saito
Tomoya Hirota
Hideko Nomura
Yoko Oya
author_sort Taiki Suzuki
collection DOAJ
description We present the observational results of a precursor of glycine, methylamine (CH _3 NH _2 ), together with methanol (CH _3 OH) and methanimine (CH _2 NH) for the high-mass star-forming regions NGC 6334I, G10.47+0.03, G31.41+0.3, and W51 e1/e2 using the Atacama Large Millimeter/submillimeter Array. The molecular abundances of these sources were derived using the CASSIS spectrum analyzer and compared with our state-of-the-art three-phase chemical model NAUTILUS . We found that the observed abundance ratio of CH _3 NH _2 /CH _3 OH is between 0.008 and 1.0 for all sources, except for NGC 6334I MM3, where a ratio less than 0.002 is found. This may be due to its later evolutionary stage relative to the other cores. We also found that the observed CH _3 NH _2 /CH _3 OH ratio agrees well with the three-phase chemical model NAUTILUS , which includes the formation of CH _3 NH _2 on the grain surface via a series of hydrogenation processes of HCN. This result clearly shows the importance of hydrogenation processes to form CH _3 NH _2 .
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spelling doaj.art-41dfef1380c3454a83635b9ba82fefed2023-09-06T09:56:37ZengIOP PublishingThe Astrophysical Journal1538-43572023-01-01954218910.3847/1538-4357/acdb6dSurvey of CH3NH2 and its Formation ProcessTaiki Suzuki0https://orcid.org/0000-0003-3278-2513Liton Majumdar1https://orcid.org/0000-0001-7031-8039Paul F. Goldsmith2https://orcid.org/0000-0002-6622-8396Kazuki Tokuda3https://orcid.org/0000-0002-2062-1600Harumi Minamoto4Masatoshi Ohishi5https://orcid.org/0000-0003-2775-7487Masao Saito6https://orcid.org/0000-0003-0769-8627Tomoya Hirota7https://orcid.org/0000-0003-1659-095XHideko Nomura8https://orcid.org/0000-0002-7058-7682Yoko Oya9https://orcid.org/0000-0002-0197-8751Astrobiology Center , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, Japan ; taiki.suzuki@nao.ac.jp; National Astronomical Observatory of Japan , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, Japan; University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, JapanSchool of Earth and Planetary Sciences, National Institute of Science Education and Research , Jatni 752050, Odisha, India ; dr.liton.majumdar@gmail.com; Homi Bhabha National Institute , Training School Complex, Anushaktinagar, Mumbai 400094, IndiaJet Propulsion Laboratory, California Institute of Technology , 48010 Oak Grove Drive, Pasadena, CA 91109, USANational Astronomical Observatory of Japan , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, Japan; Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University , Nishi-ku, Fukuoka 819-0395, JapanDepartment of Earth and Planetary Sciences, Tokyo Institute of Technology , 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, JapanNational Astronomical Observatory of Japan , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, JapanNational Astronomical Observatory of Japan , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, JapanNational Astronomical Observatory of Japan , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, JapanNational Astronomical Observatory of Japan , 2-21-1 Osawa, Mitaka, Tokyo 181-8588, Japan; Department of Earth and Planetary Sciences, Tokyo Institute of Technology , 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551, JapanCenter for Gravitational Physics and Quantum Information, Yukawa Institute for Theoretical Physics, Kyoto University , Kyoto, 606-8502, JapanWe present the observational results of a precursor of glycine, methylamine (CH _3 NH _2 ), together with methanol (CH _3 OH) and methanimine (CH _2 NH) for the high-mass star-forming regions NGC 6334I, G10.47+0.03, G31.41+0.3, and W51 e1/e2 using the Atacama Large Millimeter/submillimeter Array. The molecular abundances of these sources were derived using the CASSIS spectrum analyzer and compared with our state-of-the-art three-phase chemical model NAUTILUS . We found that the observed abundance ratio of CH _3 NH _2 /CH _3 OH is between 0.008 and 1.0 for all sources, except for NGC 6334I MM3, where a ratio less than 0.002 is found. This may be due to its later evolutionary stage relative to the other cores. We also found that the observed CH _3 NH _2 /CH _3 OH ratio agrees well with the three-phase chemical model NAUTILUS , which includes the formation of CH _3 NH _2 on the grain surface via a series of hydrogenation processes of HCN. This result clearly shows the importance of hydrogenation processes to form CH _3 NH _2 .https://doi.org/10.3847/1538-4357/acdb6dAstrochemistry Interstellar mediumInterstellar moleculesInterstellar abundancesStar formation
spellingShingle Taiki Suzuki
Liton Majumdar
Paul F. Goldsmith
Kazuki Tokuda
Harumi Minamoto
Masatoshi Ohishi
Masao Saito
Tomoya Hirota
Hideko Nomura
Yoko Oya
Survey of CH3NH2 and its Formation Process
The Astrophysical Journal
Astrochemistry
Interstellar medium
Interstellar molecules
Interstellar abundances
Star formation
title Survey of CH3NH2 and its Formation Process
title_full Survey of CH3NH2 and its Formation Process
title_fullStr Survey of CH3NH2 and its Formation Process
title_full_unstemmed Survey of CH3NH2 and its Formation Process
title_short Survey of CH3NH2 and its Formation Process
title_sort survey of ch3nh2 and its formation process
topic Astrochemistry
Interstellar medium
Interstellar molecules
Interstellar abundances
Star formation
url https://doi.org/10.3847/1538-4357/acdb6d
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