Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate
The title compound, (C7H10N)3[SbCl5]Cl·H2O, consists of 4-methylanilinium cations, Cl− and [SbCl5]2− anions and water molecules. The five Cl atoms bound to Sb [Sb—Cl = 2.4043 (9)–2.6262 (11)&#819...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812009427 |
| _version_ | 1798030851415474176 |
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| author | Qian Xu |
| author_facet | Qian Xu |
| author_sort | Qian Xu |
| collection | DOAJ |
| description | The title compound, (C7H10N)3[SbCl5]Cl·H2O, consists of 4-methylanilinium cations, Cl− and [SbCl5]2− anions and water molecules. The five Cl atoms bound to Sb [Sb—Cl = 2.4043 (9)–2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl5]2− anions related by an inversion center are joined by Sb...Cl interactions [Sb...Cl = 3.7273 (14) Å] into an [Sb2Cl10]4− dimer with two bridging Cl atoms. The anions, water molecules and ammonium groups of the cations are linked by N—H...Cl, N—H...O and O—H...Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methylanilinium cations are packed between these layers. |
| first_indexed | 2024-04-11T19:46:53Z |
| format | Article |
| id | doaj.art-41e2cd7a2eb641c0b5b6ca5d3a1810ec |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:46:53Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-41e2cd7a2eb641c0b5b6ca5d3a1810ec2022-12-22T04:06:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m438m43810.1107/S1600536812009427Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrateQian XuThe title compound, (C7H10N)3[SbCl5]Cl·H2O, consists of 4-methylanilinium cations, Cl− and [SbCl5]2− anions and water molecules. The five Cl atoms bound to Sb [Sb—Cl = 2.4043 (9)–2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl5]2− anions related by an inversion center are joined by Sb...Cl interactions [Sb...Cl = 3.7273 (14) Å] into an [Sb2Cl10]4− dimer with two bridging Cl atoms. The anions, water molecules and ammonium groups of the cations are linked by N—H...Cl, N—H...O and O—H...Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methylanilinium cations are packed between these layers.http://scripts.iucr.org/cgi-bin/paper?S1600536812009427 |
| spellingShingle | Qian Xu Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate Acta Crystallographica Section E |
| title | Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate |
| title_full | Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate |
| title_fullStr | Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate |
| title_full_unstemmed | Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate |
| title_short | Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate |
| title_sort | tris 4 methylanilinium pentachloridoantimonate iii chloride monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812009427 |
| work_keys_str_mv | AT qianxu tris4methylaniliniumpentachloridoantimonateiiichloridemonohydrate |