Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method
In the present study, the effect of dolomite and olivine as catalysts on the carbon dioxide (CO<sub>2</sub>) gasification of a candidate renewable solid recovered fuel, known as Subcoal™ was determined. Thermogravimetric analysis (TGA) was used to produce the TGA curves and derivative th...
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MDPI AG
2022-03-01
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| Online Access: | https://www.mdpi.com/2305-7084/6/2/22 |
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| author | Ahmad Mohamed S. H. Al-Moftah Richard Marsh Julian Steer |
| author_facet | Ahmad Mohamed S. H. Al-Moftah Richard Marsh Julian Steer |
| author_sort | Ahmad Mohamed S. H. Al-Moftah |
| collection | DOAJ |
| description | In the present study, the effect of dolomite and olivine as catalysts on the carbon dioxide (CO<sub>2</sub>) gasification of a candidate renewable solid recovered fuel, known as Subcoal™ was determined. Thermogravimetric analysis (TGA) was used to produce the TGA curves and derivative thermogravimetry (DTG) for the gasification reaction at different loadings of the catalyst (5, 10, 15 wt.%). The XRD results showed that the crystallinity proportion in Subcoal™ powder and ash was 42% and 38%, respectively. The Arrhenius constants of the gasification reaction were estimated using the model-fitting Coats–Redfern (CR) method. The results showed that the mass loss reaction time and thermal degradation decreased with the increase in catalyst content. The degradation reaction for complete conversion mainly consists of three sequences: dehydration, devolatilisation, and char/ash formation. The complete amount of thermal degradation of the Subcoal™ sample obtained with dolomite was lower than with olivine. In terms of kinetic analysis, 19 mechanism models of heterogeneous solid-state reaction were compared by the CR method to identify the most applicable model to the case in consideration. Among all models, G14 provided excellent linearity for dolomite and G15 for olivine at 15 wt.% of catalyst. Both catalysts reduced the activation energy (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>E</mi><mi>a</mi></msub></mrow></semantics></math></inline-formula>) as the concentration increased. However, dolomite displayed higher CO<sub>2</sub> gasification efficiency of catalysis and reduction in <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>E</mi><mi>a</mi></msub></mrow></semantics></math></inline-formula>. At 15 wt.% loading, the <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>E</mi><mi>a</mi></msub></mrow></semantics></math></inline-formula> was 41.1 and 77.5 kJ/mol for dolomite and olivine, respectively. Calcination of the mineral catalyst is substantial in improving the activity through enlarging the active surface area and number of pores. In light of the study findings, dolomite is a suitable mineral catalyst for the industrial-scale of non-recyclable waste such as Subcoal™ gasification. |
| first_indexed | 2024-03-09T11:01:00Z |
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| spelling | doaj.art-41e6df05adc44f2a89dd1b3ca8073b062023-12-01T01:16:00ZengMDPI AGChemEngineering2305-70842022-03-01622210.3390/chemengineering6020022Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern MethodAhmad Mohamed S. H. Al-Moftah0Richard Marsh1Julian Steer2Cardiff School of Engineering, Cardiff University, Queen’s Buildings, The Parade, Cardiff CF24 3AA, UKCardiff School of Engineering, Cardiff University, Queen’s Buildings, The Parade, Cardiff CF24 3AA, UKCardiff School of Engineering, Cardiff University, Queen’s Buildings, The Parade, Cardiff CF24 3AA, UKIn the present study, the effect of dolomite and olivine as catalysts on the carbon dioxide (CO<sub>2</sub>) gasification of a candidate renewable solid recovered fuel, known as Subcoal™ was determined. Thermogravimetric analysis (TGA) was used to produce the TGA curves and derivative thermogravimetry (DTG) for the gasification reaction at different loadings of the catalyst (5, 10, 15 wt.%). The XRD results showed that the crystallinity proportion in Subcoal™ powder and ash was 42% and 38%, respectively. The Arrhenius constants of the gasification reaction were estimated using the model-fitting Coats–Redfern (CR) method. The results showed that the mass loss reaction time and thermal degradation decreased with the increase in catalyst content. The degradation reaction for complete conversion mainly consists of three sequences: dehydration, devolatilisation, and char/ash formation. The complete amount of thermal degradation of the Subcoal™ sample obtained with dolomite was lower than with olivine. In terms of kinetic analysis, 19 mechanism models of heterogeneous solid-state reaction were compared by the CR method to identify the most applicable model to the case in consideration. Among all models, G14 provided excellent linearity for dolomite and G15 for olivine at 15 wt.% of catalyst. Both catalysts reduced the activation energy (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>E</mi><mi>a</mi></msub></mrow></semantics></math></inline-formula>) as the concentration increased. However, dolomite displayed higher CO<sub>2</sub> gasification efficiency of catalysis and reduction in <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>E</mi><mi>a</mi></msub></mrow></semantics></math></inline-formula>. At 15 wt.% loading, the <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>E</mi><mi>a</mi></msub></mrow></semantics></math></inline-formula> was 41.1 and 77.5 kJ/mol for dolomite and olivine, respectively. Calcination of the mineral catalyst is substantial in improving the activity through enlarging the active surface area and number of pores. In light of the study findings, dolomite is a suitable mineral catalyst for the industrial-scale of non-recyclable waste such as Subcoal™ gasification.https://www.mdpi.com/2305-7084/6/2/22non-recyclable wasteSubcoal™non-isothermalolivinedolomiteTGA |
| spellingShingle | Ahmad Mohamed S. H. Al-Moftah Richard Marsh Julian Steer Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method ChemEngineering non-recyclable waste Subcoal™ non-isothermal olivine dolomite TGA |
| title | Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method |
| title_full | Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method |
| title_fullStr | Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method |
| title_full_unstemmed | Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method |
| title_short | Thermogravimetric Kinetic Analysis of Non-Recyclable Waste CO<sub>2</sub> Gasification with Catalysts Using Coats–Redfern Method |
| title_sort | thermogravimetric kinetic analysis of non recyclable waste co sub 2 sub gasification with catalysts using coats redfern method |
| topic | non-recyclable waste Subcoal™ non-isothermal olivine dolomite TGA |
| url | https://www.mdpi.com/2305-7084/6/2/22 |
| work_keys_str_mv | AT ahmadmohamedshalmoftah thermogravimetrickineticanalysisofnonrecyclablewastecosub2subgasificationwithcatalystsusingcoatsredfernmethod AT richardmarsh thermogravimetrickineticanalysisofnonrecyclablewastecosub2subgasificationwithcatalystsusingcoatsredfernmethod AT juliansteer thermogravimetrickineticanalysisofnonrecyclablewastecosub2subgasificationwithcatalystsusingcoatsredfernmethod |