Cooperative Jahn–Teller effect and the role of strain in the tetragonal-to-cubic phase transition in MgxCu1 − xCr2O4
Temperature and composition dependences of the I41/amd → Fd\bar 3m phase transition in the MgxCu1 − xCr2O4 spinel solid solution, due to the melting of the cooperative Jahn–Teller distortion, have been studied by means of single-crystal X-ray diffraction. Crystals with x = 0, 0.10, 0.18, 0.43, 0.46,...
Main Authors: | Serena C. Tarantino, Mattia Giannini, Michael A. Carpenter, Michele Zema |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2016-09-01
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Series: | IUCrJ |
Subjects: | |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2052252516012574 |
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