Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)

The archaeological excavations at Villa San Pancrazio (Taormina, Italy) are bringing to light a vast Roman-Imperial residential quarter featuring luxurious dwellings decorated with wall paintings and mosaic floors, pointing it out as one of the most significant archaeological sites of the city. The...

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Main Authors: Olivia Gomez-Laserna, Anna Irto, Pablo Irizar, Gabriele Lando, Clemente Bretti, Irantzu Martinez-Arkarazo, Lorenzo Campagna, Paola Cardiano
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/11/11/1423
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author Olivia Gomez-Laserna
Anna Irto
Pablo Irizar
Gabriele Lando
Clemente Bretti
Irantzu Martinez-Arkarazo
Lorenzo Campagna
Paola Cardiano
author_facet Olivia Gomez-Laserna
Anna Irto
Pablo Irizar
Gabriele Lando
Clemente Bretti
Irantzu Martinez-Arkarazo
Lorenzo Campagna
Paola Cardiano
author_sort Olivia Gomez-Laserna
collection DOAJ
description The archaeological excavations at Villa San Pancrazio (Taormina, Italy) are bringing to light a vast Roman-Imperial residential quarter featuring luxurious dwellings decorated with wall paintings and mosaic floors, pointing it out as one of the most significant archaeological sites of the city. The polychrome and black and white mosaics recovered date back to the middle Imperial period, during the 2nd century AD. This work deals with the first archaeometric investigations of the materials employed for the <i>tesserae</i> production with the aim of elucidating the mineralogical composition and obtaining analytical evidence that can contribute to extracting information related to their production technology. For that purpose, a non-invasive methodology, based on micro energy dispersive X-ray fluorescence (μ-EDXRF) spectrometry and Raman spectroscopy, was used to characterize a wide selection of stone, ceramic and glass <i>tesserae</i>. Chemometric tools were exploited to manage the large set of elemental data collected on black and white lithic samples, providing essential clues for the subsequent investigations. The results evidenced the employment of natural lithotypes (calcareous sedimentary, dolomitic and volcanic) local and imported, and also artificial materials, such as ceramic made firing magnesium-rich clays, soda-lime-silica glasses made with different opacifying and coloring agents (such as calcium antimoniate, cobalt and copper).
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spelling doaj.art-42106276c17b4cae842b548cf63c54a62023-11-22T22:59:21ZengMDPI AGCrystals2073-43522021-11-011111142310.3390/cryst11111423Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)Olivia Gomez-Laserna0Anna Irto1Pablo Irizar2Gabriele Lando3Clemente Bretti4Irantzu Martinez-Arkarazo5Lorenzo Campagna6Paola Cardiano7Department of Analytical Chemistry, University of the Basque Country (UPV/EHU), Barrio Sarriena s/n, Leioa, E-48080 Bilbao, SpainDepartment of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Viale F. Stagno d’Alcontres 31, I-98166 Messina, ItalyDepartment of Analytical Chemistry, University of the Basque Country (UPV/EHU), Barrio Sarriena s/n, Leioa, E-48080 Bilbao, SpainDepartment of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Viale F. Stagno d’Alcontres 31, I-98166 Messina, ItalyDepartment of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Viale F. Stagno d’Alcontres 31, I-98166 Messina, ItalyDepartment of Analytical Chemistry, University of the Basque Country (UPV/EHU), Barrio Sarriena s/n, Leioa, E-48080 Bilbao, SpainDepartment of Ancient and Modern Cultures, University of Messina, Polo Universitario dell’Annunziata, I-98168 Messina, ItalyDepartment of Chemical, Biological, Pharmaceutical and Environmental Sciences, University of Messina, Viale F. Stagno d’Alcontres 31, I-98166 Messina, ItalyThe archaeological excavations at Villa San Pancrazio (Taormina, Italy) are bringing to light a vast Roman-Imperial residential quarter featuring luxurious dwellings decorated with wall paintings and mosaic floors, pointing it out as one of the most significant archaeological sites of the city. The polychrome and black and white mosaics recovered date back to the middle Imperial period, during the 2nd century AD. This work deals with the first archaeometric investigations of the materials employed for the <i>tesserae</i> production with the aim of elucidating the mineralogical composition and obtaining analytical evidence that can contribute to extracting information related to their production technology. For that purpose, a non-invasive methodology, based on micro energy dispersive X-ray fluorescence (μ-EDXRF) spectrometry and Raman spectroscopy, was used to characterize a wide selection of stone, ceramic and glass <i>tesserae</i>. Chemometric tools were exploited to manage the large set of elemental data collected on black and white lithic samples, providing essential clues for the subsequent investigations. The results evidenced the employment of natural lithotypes (calcareous sedimentary, dolomitic and volcanic) local and imported, and also artificial materials, such as ceramic made firing magnesium-rich clays, soda-lime-silica glasses made with different opacifying and coloring agents (such as calcium antimoniate, cobalt and copper).https://www.mdpi.com/2073-4352/11/11/1423Raman spectroscopyEDXRFchemometric analysisRoman TaorminaRoman mosaics
spellingShingle Olivia Gomez-Laserna
Anna Irto
Pablo Irizar
Gabriele Lando
Clemente Bretti
Irantzu Martinez-Arkarazo
Lorenzo Campagna
Paola Cardiano
Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)
Crystals
Raman spectroscopy
EDXRF
chemometric analysis
Roman Taormina
Roman mosaics
title Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)
title_full Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)
title_fullStr Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)
title_full_unstemmed Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)
title_short Non-Invasive Approach to Investigate the Mineralogy and Production Technology of the Mosaic <i>Tesserae</i> from the Roman <i>Domus</i> of Villa San Pancrazio (Taormina, Italy)
title_sort non invasive approach to investigate the mineralogy and production technology of the mosaic i tesserae i from the roman i domus i of villa san pancrazio taormina italy
topic Raman spectroscopy
EDXRF
chemometric analysis
Roman Taormina
Roman mosaics
url https://www.mdpi.com/2073-4352/11/11/1423
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