MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural
Platform chemical 2,5-furandicarboxylic acid (FDCA) has potential applications to replace petroleum-based chemicals. Metal Organic Framework (MOF) can be used as a catalyst to oxidize 5-hydroxymethylfurfural (HMF), producing FDCA. MOF-199 and Ni-BTC were synthesized using solvothermal method with tr...
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2023-12-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
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| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/20060 |
| _version_ | 1797383049246146560 |
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| author | Idra Herlina Yuni Krisyuningsih Krisnandi Muhammad Ridwan |
| author_facet | Idra Herlina Yuni Krisyuningsih Krisnandi Muhammad Ridwan |
| author_sort | Idra Herlina |
| collection | DOAJ |
| description | Platform chemical 2,5-furandicarboxylic acid (FDCA) has potential applications to replace petroleum-based chemicals. Metal Organic Framework (MOF) can be used as a catalyst to oxidize 5-hydroxymethylfurfural (HMF), producing FDCA. MOF-199 and Ni-BTC were synthesized using solvothermal method with trimesic acid (benzene 1,3,5-tricarboxylic acid/H3BTC) as a linker and Cu or Ni as a metal nod. The physical and chemical properties of catalysts were discovered through characterization using X-ray Diffraction (XRD), Fourier Transform Infra Red (FT-IR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy - Energy Dispersive X-ray (SEM-EDX), and Ammonia Temperature-programmed Desorption (NH3-TPD). FDCA and its intermediate compounds were produced by converting HMF to FDCA in a small glass batch reactor. The yields of products were then determined by High-Performance Liquid Chromatography (HPLC). HPLC results indicated that there was no DFF (2,5-diformylfuran) signal, indicating that FDCA was formed by FFCA (5-formylfuroic acid) and HMFCA (5-hydroxymethylfuroic acid) formation reaction pathway. The maximum conversion (71%) was obtained using Ni-BTC as a catalyst at 130 °C for 5 h, with FDCA yield of 61.8%. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
| first_indexed | 2024-03-08T21:14:10Z |
| format | Article |
| id | doaj.art-421893096b204408b9b912fa25236460 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-08T21:14:10Z |
| publishDate | 2023-12-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-421893096b204408b9b912fa252364602023-12-22T01:17:56ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932023-12-0118472473510.9767/bcrec.200608405MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-HydroxymethylfurfuralIdra Herlina0https://orcid.org/0000-0002-3820-3204Yuni Krisyuningsih Krisnandi1https://orcid.org/0000-0002-2753-5596Muhammad Ridwan2https://orcid.org/0000-0002-0201-2684Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Indonesia, Depok 16424, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Science, Universitas Indonesia, Depok 16424, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Science, Universitas Indonesia, Depok 16424, IndonesiaPlatform chemical 2,5-furandicarboxylic acid (FDCA) has potential applications to replace petroleum-based chemicals. Metal Organic Framework (MOF) can be used as a catalyst to oxidize 5-hydroxymethylfurfural (HMF), producing FDCA. MOF-199 and Ni-BTC were synthesized using solvothermal method with trimesic acid (benzene 1,3,5-tricarboxylic acid/H3BTC) as a linker and Cu or Ni as a metal nod. The physical and chemical properties of catalysts were discovered through characterization using X-ray Diffraction (XRD), Fourier Transform Infra Red (FT-IR), Thermogravimetric Analysis (TGA), Scanning Electron Microscopy - Energy Dispersive X-ray (SEM-EDX), and Ammonia Temperature-programmed Desorption (NH3-TPD). FDCA and its intermediate compounds were produced by converting HMF to FDCA in a small glass batch reactor. The yields of products were then determined by High-Performance Liquid Chromatography (HPLC). HPLC results indicated that there was no DFF (2,5-diformylfuran) signal, indicating that FDCA was formed by FFCA (5-formylfuroic acid) and HMFCA (5-hydroxymethylfuroic acid) formation reaction pathway. The maximum conversion (71%) was obtained using Ni-BTC as a catalyst at 130 °C for 5 h, with FDCA yield of 61.8%. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/20060mof-199ni-btc5-hydroxymethylfurfural2,5-furandicarboxylic acid |
| spellingShingle | Idra Herlina Yuni Krisyuningsih Krisnandi Muhammad Ridwan MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural Bulletin of Chemical Reaction Engineering & Catalysis mof-199 ni-btc 5-hydroxymethylfurfural 2,5-furandicarboxylic acid |
| title | MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural |
| title_full | MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural |
| title_fullStr | MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural |
| title_full_unstemmed | MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural |
| title_short | MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfural |
| title_sort | mof 199 and ni btc synthesis physicochemical properties and catalytic activity in oxidation of 5 hydroxymethylfurfural |
| topic | mof-199 ni-btc 5-hydroxymethylfurfural 2,5-furandicarboxylic acid |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/20060 |
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