Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation
Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which display benzylic selectivity in the hydrosilylation of internal alkenes and Markovnikov selectivity with terminal styrenes and...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Nature Portfolio
2018-01-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-02472-6 |
| _version_ | 1818422042208239616 |
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| author | Meng-Yang Hu Qiao He Song-Jie Fan Zi-Chen Wang Luo-Yan Liu Yi-Jiang Mu Qian Peng Shou-Fei Zhu |
| author_facet | Meng-Yang Hu Qiao He Song-Jie Fan Zi-Chen Wang Luo-Yan Liu Yi-Jiang Mu Qian Peng Shou-Fei Zhu |
| author_sort | Meng-Yang Hu |
| collection | DOAJ |
| description | Hydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which display benzylic selectivity in the hydrosilylation of internal alkenes and Markovnikov selectivity with terminal styrenes and 1,3-dienes. |
| first_indexed | 2024-12-14T13:19:58Z |
| format | Article |
| id | doaj.art-42378608055b4234b3f7d3430235ee8b |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-14T13:19:58Z |
| publishDate | 2018-01-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-42378608055b4234b3f7d3430235ee8b2022-12-21T22:59:58ZengNature PortfolioNature Communications2041-17232018-01-019111110.1038/s41467-017-02472-6Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylationMeng-Yang Hu0Qiao He1Song-Jie Fan2Zi-Chen Wang3Luo-Yan Liu4Yi-Jiang Mu5Qian Peng6Shou-Fei Zhu7State Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryState Key Laboratory and Institute of Elemento-Organic ChemistryHydrosilylation of alkenes poses substantial challenges in terms of regioselectivity. Here, the authors report iron complexes with 1,10-phenantroline ligand scaffolds which display benzylic selectivity in the hydrosilylation of internal alkenes and Markovnikov selectivity with terminal styrenes and 1,3-dienes.https://doi.org/10.1038/s41467-017-02472-6 |
| spellingShingle | Meng-Yang Hu Qiao He Song-Jie Fan Zi-Chen Wang Luo-Yan Liu Yi-Jiang Mu Qian Peng Shou-Fei Zhu Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation Nature Communications |
| title | Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation |
| title_full | Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation |
| title_fullStr | Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation |
| title_full_unstemmed | Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation |
| title_short | Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation |
| title_sort | ligands with 1 10 phenanthroline scaffold for highly regioselective iron catalyzed alkene hydrosilylation |
| url | https://doi.org/10.1038/s41467-017-02472-6 |
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