Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery

All-vanadium redox flow batteries (VRFBs) are considered promising candidates for large-scale energy storage systems due to their flexible power scale design, high efficiency, deep discharge, long cycle life and environmental friendliness. The performance and efficiency of a VRFB is affected by many...

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Main Authors: Chin-Lung Hsieh, Po-Hong Tsai, Ning-Yih Hsu, Yong-Song Chen
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/12/2/313
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author Chin-Lung Hsieh
Po-Hong Tsai
Ning-Yih Hsu
Yong-Song Chen
author_facet Chin-Lung Hsieh
Po-Hong Tsai
Ning-Yih Hsu
Yong-Song Chen
author_sort Chin-Lung Hsieh
collection DOAJ
description All-vanadium redox flow batteries (VRFBs) are considered promising candidates for large-scale energy storage systems due to their flexible power scale design, high efficiency, deep discharge, long cycle life and environmental friendliness. The performance and efficiency of a VRFB is affected by many factors, including component materials, battery design, electrolyte composition and operating conditions. Among the key components, porous electrodes play a key role, as the electrochemical reaction occurs on the fiber surface of the electrode. As such, many studies have focused on improving reaction kinetics by modifying the surface of the electrode. In this work, the effect of varying the compression ratio (CR) of graphite felts on the performance and efficiency of a VRFB are investigated. The impedance of a single VRFB under varying CRs of graphite felts at various operating conditions were also measured. The results suggest that performance of a VRFB increases with increasing CR due to the decrease of area resistance and concentration overpotential. The porous electrode compressed from 6.5 to 4 mm demonstrates the optimal energy efficiency of 73% at the operating current density 80 mA cm−2 and electrolyte flow rate 100 mL min−1.
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spelling doaj.art-423c80d90d5848b7ab3ca538e4ecf7142022-12-22T04:01:36ZengMDPI AGEnergies1996-10732019-01-0112231310.3390/en12020313en12020313Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow BatteryChin-Lung Hsieh0Po-Hong Tsai1Ning-Yih Hsu2Yong-Song Chen3Institute of Nuclear Energy Research, Atomic Energy Council, No. 1000 Wenhua Rd., Jiaan Village, Longtan District, Taoyuan City 32546, TaiwanDepartment of Mechanical Engineering and Advanced Institute of Manufacturing with High-tech Innovations, National Chung Cheng University, No. 168, University Rd., Minhsiung Township, Chiayi County 62102, TaiwanInstitute of Nuclear Energy Research, Atomic Energy Council, No. 1000 Wenhua Rd., Jiaan Village, Longtan District, Taoyuan City 32546, TaiwanDepartment of Mechanical Engineering and Advanced Institute of Manufacturing with High-tech Innovations, National Chung Cheng University, No. 168, University Rd., Minhsiung Township, Chiayi County 62102, TaiwanAll-vanadium redox flow batteries (VRFBs) are considered promising candidates for large-scale energy storage systems due to their flexible power scale design, high efficiency, deep discharge, long cycle life and environmental friendliness. The performance and efficiency of a VRFB is affected by many factors, including component materials, battery design, electrolyte composition and operating conditions. Among the key components, porous electrodes play a key role, as the electrochemical reaction occurs on the fiber surface of the electrode. As such, many studies have focused on improving reaction kinetics by modifying the surface of the electrode. In this work, the effect of varying the compression ratio (CR) of graphite felts on the performance and efficiency of a VRFB are investigated. The impedance of a single VRFB under varying CRs of graphite felts at various operating conditions were also measured. The results suggest that performance of a VRFB increases with increasing CR due to the decrease of area resistance and concentration overpotential. The porous electrode compressed from 6.5 to 4 mm demonstrates the optimal energy efficiency of 73% at the operating current density 80 mA cm−2 and electrolyte flow rate 100 mL min−1.http://www.mdpi.com/1996-1073/12/2/313all-vanadium redox flow batterygraphite feltcompression ratioelectrode
spellingShingle Chin-Lung Hsieh
Po-Hong Tsai
Ning-Yih Hsu
Yong-Song Chen
Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery
Energies
all-vanadium redox flow battery
graphite felt
compression ratio
electrode
title Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery
title_full Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery
title_fullStr Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery
title_full_unstemmed Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery
title_short Effect of Compression Ratio of Graphite Felts on the Performance of an All-Vanadium Redox Flow Battery
title_sort effect of compression ratio of graphite felts on the performance of an all vanadium redox flow battery
topic all-vanadium redox flow battery
graphite felt
compression ratio
electrode
url http://www.mdpi.com/1996-1073/12/2/313
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AT pohongtsai effectofcompressionratioofgraphitefeltsontheperformanceofanallvanadiumredoxflowbattery
AT ningyihhsu effectofcompressionratioofgraphitefeltsontheperformanceofanallvanadiumredoxflowbattery
AT yongsongchen effectofcompressionratioofgraphitefeltsontheperformanceofanallvanadiumredoxflowbattery