X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus

Picrolite artefacts comprise some of the most distinctive material remains in the prehistory of the island of Cyprus, in the Eastern Mediterranean. Picrolite exploitation dates from at least 12,000 years ago for the manufacture of personal ornaments and items with a symbolic function. It is commonly...

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Main Authors: Theodora Moutsiou, Demetrios Ioannides, Andreas Charalambous, Sebastian Schöder, Sam M. Webb, Mathieu Thoury, Vasiliki Kassianidou, Zomenia Zomeni, Christian Reepmeyer
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Heritage
Subjects:
Online Access:https://www.mdpi.com/2571-9408/5/2/37
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author Theodora Moutsiou
Demetrios Ioannides
Andreas Charalambous
Sebastian Schöder
Sam M. Webb
Mathieu Thoury
Vasiliki Kassianidou
Zomenia Zomeni
Christian Reepmeyer
author_facet Theodora Moutsiou
Demetrios Ioannides
Andreas Charalambous
Sebastian Schöder
Sam M. Webb
Mathieu Thoury
Vasiliki Kassianidou
Zomenia Zomeni
Christian Reepmeyer
author_sort Theodora Moutsiou
collection DOAJ
description Picrolite artefacts comprise some of the most distinctive material remains in the prehistory of the island of Cyprus, in the Eastern Mediterranean. Picrolite exploitation dates from at least 12,000 years ago for the manufacture of personal ornaments and items with a symbolic function. It is commonly assumed that picrolite nodules were collected in secondary deposits on an ad hoc basis. This narrative, however, ignores the fact that picrolite carriers can only be found in very specific locations on the island, discrete from each other. Here we report initial outcomes of the application of handheld portable X-ray fluorescence (HHpXRF) and synchrotron-based X-ray fluorescence spectroscopy (SR-μXRF) to the analysis of picrolite raw materials performed at the newly opened PUMA beamline of the SOLEIL Synchrotron Radiation Facility. Our work refines the basic characteristics of the elemental constituents of the picrolite raw material and highlights key micro-structural differences between two distinct source regions on the Troodos Massif in western Cyprus. Picrolite source characterisation is expected to contribute significant new knowledge to the study of rare raw material consumption, prehistoric social organisation, networking and possible long-distance exchange of this idiosyncratic raw material within and beyond the island’s geographic boundaries.
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spelling doaj.art-424427e89f0b4e73953d3140bef492202023-11-23T16:54:10ZengMDPI AGHeritage2571-94082022-03-015266467610.3390/heritage5020037X-ray Fluorescence Spectroscopy of Picrolite Raw Material on CyprusTheodora Moutsiou0Demetrios Ioannides1Andreas Charalambous2Sebastian Schöder3Sam M. Webb4Mathieu Thoury5Vasiliki Kassianidou6Zomenia Zomeni7Christian Reepmeyer8Archaeological Research Unit, University of Cyprus, P.O. Box 20537, Nicosia 1678, CyprusArchaeological Research Unit, University of Cyprus, P.O. Box 20537, Nicosia 1678, CyprusArchaeological Research Unit, University of Cyprus, P.O. Box 20537, Nicosia 1678, CyprusPUMA Beamline, Synchrotron SOLEIL, Saint-Aubin BP48, F-91192 Gif-sur-Yvette, FranceSLAC National Accelerator Laboratory, Stanford University, 2575 Sand Hill Rd., Mailstop 0069, Menlo Park, CA 94025, USAIPANEMA, Synchrotron SOLEIL, Saint-Aubin BP48, F-91192 Gif-sur-Yvette, FranceArchaeological Research Unit, University of Cyprus, P.O. Box 20537, Nicosia 1678, CyprusGeological Survey Department, P.O. Box 24543, Lefkosia 1301, CyprusArchaeological Research Unit, University of Cyprus, P.O. Box 20537, Nicosia 1678, CyprusPicrolite artefacts comprise some of the most distinctive material remains in the prehistory of the island of Cyprus, in the Eastern Mediterranean. Picrolite exploitation dates from at least 12,000 years ago for the manufacture of personal ornaments and items with a symbolic function. It is commonly assumed that picrolite nodules were collected in secondary deposits on an ad hoc basis. This narrative, however, ignores the fact that picrolite carriers can only be found in very specific locations on the island, discrete from each other. Here we report initial outcomes of the application of handheld portable X-ray fluorescence (HHpXRF) and synchrotron-based X-ray fluorescence spectroscopy (SR-μXRF) to the analysis of picrolite raw materials performed at the newly opened PUMA beamline of the SOLEIL Synchrotron Radiation Facility. Our work refines the basic characteristics of the elemental constituents of the picrolite raw material and highlights key micro-structural differences between two distinct source regions on the Troodos Massif in western Cyprus. Picrolite source characterisation is expected to contribute significant new knowledge to the study of rare raw material consumption, prehistoric social organisation, networking and possible long-distance exchange of this idiosyncratic raw material within and beyond the island’s geographic boundaries.https://www.mdpi.com/2571-9408/5/2/37picroliteX-ray fluorescencesynchrotron microspectroscopysourcingCyprus
spellingShingle Theodora Moutsiou
Demetrios Ioannides
Andreas Charalambous
Sebastian Schöder
Sam M. Webb
Mathieu Thoury
Vasiliki Kassianidou
Zomenia Zomeni
Christian Reepmeyer
X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus
Heritage
picrolite
X-ray fluorescence
synchrotron microspectroscopy
sourcing
Cyprus
title X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus
title_full X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus
title_fullStr X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus
title_full_unstemmed X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus
title_short X-ray Fluorescence Spectroscopy of Picrolite Raw Material on Cyprus
title_sort x ray fluorescence spectroscopy of picrolite raw material on cyprus
topic picrolite
X-ray fluorescence
synchrotron microspectroscopy
sourcing
Cyprus
url https://www.mdpi.com/2571-9408/5/2/37
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