Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
Band-gap alignment engineering has now been extensively studied due to its high potential for application. Here we demonstrate a simple route to synthesize two metal oxide layers and align them together according to their bandgaps on the surface of crystalline silicon (c-Si) solar cells. The metal o...
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MDPI AG
2018-07-01
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Online Access: | http://www.mdpi.com/2079-4991/8/7/505 |
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author | Lingling Zhou Lufei Xiao Hai Yang Jie Liu Xibin Yu |
author_facet | Lingling Zhou Lufei Xiao Hai Yang Jie Liu Xibin Yu |
author_sort | Lingling Zhou |
collection | DOAJ |
description | Band-gap alignment engineering has now been extensively studied due to its high potential for application. Here we demonstrate a simple route to synthesize two metal oxide layers and align them together according to their bandgaps on the surface of crystalline silicon (c-Si) solar cells. The metal oxide layers not only extend absorption spectrum to generate extra carriers but also more efficiently separate electron–hole pairs. As a consequence, the photovoltaic performance of SnO2/CdO/Si double-layer solar cell (DLSC) is highly improved compared to the controlled Si solar cell, CdO/Si and SnO2/Si single-layer solar cells (SLSCs). Via alignment engineering, the SnO2/CdO/Si DLSC produces a short circuit photocurrent (Jsc) of 38.20 mA/cm2, an open circuit photovoltage (Voc) of 0.575 V and a fill factor (FF) of 68.7%, a conversion efficiency (η) of 15.09% under AM1.5 illumination. |
first_indexed | 2024-12-18T22:03:06Z |
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issn | 2079-4991 |
language | English |
last_indexed | 2024-12-18T22:03:06Z |
publishDate | 2018-07-01 |
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series | Nanomaterials |
spelling | doaj.art-4264af957ae6469797097b2d3f96b99f2022-12-21T20:50:13ZengMDPI AGNanomaterials2079-49912018-07-018750510.3390/nano8070505nano8070505Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal OxideLingling Zhou0Lufei Xiao1Hai Yang2Jie Liu3Xibin Yu4Department of Food and Environmental Engineering, Chuzhou Vocational and Technical College, Chuzhou 239000, ChinaDepartment of Food and Environmental Engineering, Chuzhou Vocational and Technical College, Chuzhou 239000, ChinaThe Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, ChinaThe Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, ChinaThe Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, ChinaBand-gap alignment engineering has now been extensively studied due to its high potential for application. Here we demonstrate a simple route to synthesize two metal oxide layers and align them together according to their bandgaps on the surface of crystalline silicon (c-Si) solar cells. The metal oxide layers not only extend absorption spectrum to generate extra carriers but also more efficiently separate electron–hole pairs. As a consequence, the photovoltaic performance of SnO2/CdO/Si double-layer solar cell (DLSC) is highly improved compared to the controlled Si solar cell, CdO/Si and SnO2/Si single-layer solar cells (SLSCs). Via alignment engineering, the SnO2/CdO/Si DLSC produces a short circuit photocurrent (Jsc) of 38.20 mA/cm2, an open circuit photovoltage (Voc) of 0.575 V and a fill factor (FF) of 68.7%, a conversion efficiency (η) of 15.09% under AM1.5 illumination.http://www.mdpi.com/2079-4991/8/7/505silicon solar cellssemiconductorselectron–hole pairs |
spellingShingle | Lingling Zhou Lufei Xiao Hai Yang Jie Liu Xibin Yu Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide Nanomaterials silicon solar cells semiconductors electron–hole pairs |
title | Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide |
title_full | Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide |
title_fullStr | Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide |
title_full_unstemmed | Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide |
title_short | Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide |
title_sort | greatly enhanced photovoltaic performance of crystalline silicon solar cells via metal oxide |
topic | silicon solar cells semiconductors electron–hole pairs |
url | http://www.mdpi.com/2079-4991/8/7/505 |
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