Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide

Band-gap alignment engineering has now been extensively studied due to its high potential for application. Here we demonstrate a simple route to synthesize two metal oxide layers and align them together according to their bandgaps on the surface of crystalline silicon (c-Si) solar cells. The metal o...

Full description

Bibliographic Details
Main Authors: Lingling Zhou, Lufei Xiao, Hai Yang, Jie Liu, Xibin Yu
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Nanomaterials
Subjects:
Online Access:http://www.mdpi.com/2079-4991/8/7/505
_version_ 1824013550967848960
author Lingling Zhou
Lufei Xiao
Hai Yang
Jie Liu
Xibin Yu
author_facet Lingling Zhou
Lufei Xiao
Hai Yang
Jie Liu
Xibin Yu
author_sort Lingling Zhou
collection DOAJ
description Band-gap alignment engineering has now been extensively studied due to its high potential for application. Here we demonstrate a simple route to synthesize two metal oxide layers and align them together according to their bandgaps on the surface of crystalline silicon (c-Si) solar cells. The metal oxide layers not only extend absorption spectrum to generate extra carriers but also more efficiently separate electron–hole pairs. As a consequence, the photovoltaic performance of SnO2/CdO/Si double-layer solar cell (DLSC) is highly improved compared to the controlled Si solar cell, CdO/Si and SnO2/Si single-layer solar cells (SLSCs). Via alignment engineering, the SnO2/CdO/Si DLSC produces a short circuit photocurrent (Jsc) of 38.20 mA/cm2, an open circuit photovoltage (Voc) of 0.575 V and a fill factor (FF) of 68.7%, a conversion efficiency (η) of 15.09% under AM1.5 illumination.
first_indexed 2024-12-18T22:03:06Z
format Article
id doaj.art-4264af957ae6469797097b2d3f96b99f
institution Directory Open Access Journal
issn 2079-4991
language English
last_indexed 2024-12-18T22:03:06Z
publishDate 2018-07-01
publisher MDPI AG
record_format Article
series Nanomaterials
spelling doaj.art-4264af957ae6469797097b2d3f96b99f2022-12-21T20:50:13ZengMDPI AGNanomaterials2079-49912018-07-018750510.3390/nano8070505nano8070505Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal OxideLingling Zhou0Lufei Xiao1Hai Yang2Jie Liu3Xibin Yu4Department of Food and Environmental Engineering, Chuzhou Vocational and Technical College, Chuzhou 239000, ChinaDepartment of Food and Environmental Engineering, Chuzhou Vocational and Technical College, Chuzhou 239000, ChinaThe Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, ChinaThe Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, ChinaThe Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Department of Chemistry, Shanghai Normal University, Shanghai 200234, ChinaBand-gap alignment engineering has now been extensively studied due to its high potential for application. Here we demonstrate a simple route to synthesize two metal oxide layers and align them together according to their bandgaps on the surface of crystalline silicon (c-Si) solar cells. The metal oxide layers not only extend absorption spectrum to generate extra carriers but also more efficiently separate electron–hole pairs. As a consequence, the photovoltaic performance of SnO2/CdO/Si double-layer solar cell (DLSC) is highly improved compared to the controlled Si solar cell, CdO/Si and SnO2/Si single-layer solar cells (SLSCs). Via alignment engineering, the SnO2/CdO/Si DLSC produces a short circuit photocurrent (Jsc) of 38.20 mA/cm2, an open circuit photovoltage (Voc) of 0.575 V and a fill factor (FF) of 68.7%, a conversion efficiency (η) of 15.09% under AM1.5 illumination.http://www.mdpi.com/2079-4991/8/7/505silicon solar cellssemiconductorselectron–hole pairs
spellingShingle Lingling Zhou
Lufei Xiao
Hai Yang
Jie Liu
Xibin Yu
Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
Nanomaterials
silicon solar cells
semiconductors
electron–hole pairs
title Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
title_full Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
title_fullStr Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
title_full_unstemmed Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
title_short Greatly Enhanced Photovoltaic Performance of Crystalline Silicon Solar Cells via Metal Oxide
title_sort greatly enhanced photovoltaic performance of crystalline silicon solar cells via metal oxide
topic silicon solar cells
semiconductors
electron–hole pairs
url http://www.mdpi.com/2079-4991/8/7/505
work_keys_str_mv AT linglingzhou greatlyenhancedphotovoltaicperformanceofcrystallinesiliconsolarcellsviametaloxide
AT lufeixiao greatlyenhancedphotovoltaicperformanceofcrystallinesiliconsolarcellsviametaloxide
AT haiyang greatlyenhancedphotovoltaicperformanceofcrystallinesiliconsolarcellsviametaloxide
AT jieliu greatlyenhancedphotovoltaicperformanceofcrystallinesiliconsolarcellsviametaloxide
AT xibinyu greatlyenhancedphotovoltaicperformanceofcrystallinesiliconsolarcellsviametaloxide