Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy
Improving the reversibility of anionic redox and inhibiting irreversible oxygen evolution are the main challenges in the application of high reversible capacity Li-rich Mn-based cathode materials. A facile synchronous lithiation strategy combining the advantages of yttrium doping and LiYO2 surface c...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co., Ltd.
2024-01-01
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| Series: | Green Energy & Environment |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025722000978 |
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| author | Wenhua Yu Yanyan Wang Aimin Wu Aikui Li Zhiwen Qiu Xufeng Dong Chuang Dong Hao Huang |
| author_facet | Wenhua Yu Yanyan Wang Aimin Wu Aikui Li Zhiwen Qiu Xufeng Dong Chuang Dong Hao Huang |
| author_sort | Wenhua Yu |
| collection | DOAJ |
| description | Improving the reversibility of anionic redox and inhibiting irreversible oxygen evolution are the main challenges in the application of high reversible capacity Li-rich Mn-based cathode materials. A facile synchronous lithiation strategy combining the advantages of yttrium doping and LiYO2 surface coating is proposed. Yttrium doping effectively suppresses the oxygen evolution during the delithiation process by increasing the energy barrier of oxygen evolution reaction through strong Y–O bond energy. LiYO2 nanocoating has the function of structural constraint and protection, that protecting the lattice oxygen exposed to the surface, thus avoiding irreversible oxidation. As an Li+ conductor, LiYO2 nanocoating can provide a fast Li+ transfer channel, which enables the sample to have excellent rate performance. The synergistic effect of Y doping and nano-LiYO2 coating integration suppresses the oxygen release from the surface, accelerates the diffusion of Li+ from electrolyte to electrode and decreases the interfacial side reactions, enabling the lithium ion batteries to obtain good electrochemical performance. The lithium-ion full cell employing the Y-1 sample (cathode) and commercial graphite (anode) exhibit an excellent specific energy density of 442.9 Wh kg−1 at a current density of 0.1C, with very stable safety performance, which can be used in a wide temperature range (60 to −15 °C) stable operation. This result illustrates a new integration strategy for advanced cathode materials to achieve high specific energy density. |
| first_indexed | 2024-03-10T04:30:39Z |
| format | Article |
| id | doaj.art-427ea72a04b64b99aa827af12499a361 |
| institution | Directory Open Access Journal |
| issn | 2468-0257 |
| language | English |
| last_indexed | 2024-03-10T04:30:39Z |
| publishDate | 2024-01-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Green Energy & Environment |
| spelling | doaj.art-427ea72a04b64b99aa827af12499a3612023-11-23T04:28:57ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572024-01-0191138151Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategyWenhua Yu0Yanyan Wang1Aimin Wu2Aikui Li3Zhiwen Qiu4Xufeng Dong5Chuang Dong6Hao Huang7Key Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaKey Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaKey Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaDalian Engineering Research Center for New Electric Power Systerms, School of Electrical Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaKey Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaKey Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaKey Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, ChinaKey Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian, 116024, Liaoning Province, China; Corresponding author.Improving the reversibility of anionic redox and inhibiting irreversible oxygen evolution are the main challenges in the application of high reversible capacity Li-rich Mn-based cathode materials. A facile synchronous lithiation strategy combining the advantages of yttrium doping and LiYO2 surface coating is proposed. Yttrium doping effectively suppresses the oxygen evolution during the delithiation process by increasing the energy barrier of oxygen evolution reaction through strong Y–O bond energy. LiYO2 nanocoating has the function of structural constraint and protection, that protecting the lattice oxygen exposed to the surface, thus avoiding irreversible oxidation. As an Li+ conductor, LiYO2 nanocoating can provide a fast Li+ transfer channel, which enables the sample to have excellent rate performance. The synergistic effect of Y doping and nano-LiYO2 coating integration suppresses the oxygen release from the surface, accelerates the diffusion of Li+ from electrolyte to electrode and decreases the interfacial side reactions, enabling the lithium ion batteries to obtain good electrochemical performance. The lithium-ion full cell employing the Y-1 sample (cathode) and commercial graphite (anode) exhibit an excellent specific energy density of 442.9 Wh kg−1 at a current density of 0.1C, with very stable safety performance, which can be used in a wide temperature range (60 to −15 °C) stable operation. This result illustrates a new integration strategy for advanced cathode materials to achieve high specific energy density.http://www.sciencedirect.com/science/article/pii/S2468025722000978Lithium-rich manganese-based cathodesLithium ion batteriesOxygen redoxOxygen evolutionIntegrated strategy |
| spellingShingle | Wenhua Yu Yanyan Wang Aimin Wu Aikui Li Zhiwen Qiu Xufeng Dong Chuang Dong Hao Huang Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy Green Energy & Environment Lithium-rich manganese-based cathodes Lithium ion batteries Oxygen redox Oxygen evolution Integrated strategy |
| title | Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy |
| title_full | Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy |
| title_fullStr | Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy |
| title_full_unstemmed | Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy |
| title_short | Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy |
| title_sort | suppress oxygen evolution of lithium rich manganese based cathode materials via an integrated strategy |
| topic | Lithium-rich manganese-based cathodes Lithium ion batteries Oxygen redox Oxygen evolution Integrated strategy |
| url | http://www.sciencedirect.com/science/article/pii/S2468025722000978 |
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