3D and 2D aromatic units behave like oil and water in the case of benzocarborane derivatives
2D/2D fusion of aromatic halves leading to a global aromatic is found in many polycyclic aromatic hydrocarbons, whereas 2D/3D aromaticity is difficult to achieve. Here the authors report a computational chemistry investigation showing that 3D/2D aromatic combination is not possible.
Main Authors: | Jordi Poater, Clara Viñas, Miquel Solà, Francesc Teixidor |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2022-07-01
|
Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-022-31267-7 |
Similar Items
-
A Critical Assessment of the Performance of Magnetic and Electronic Indices of Aromaticity
by: Miquel Solà, et al.
Published: (2010-06-01) -
Towards the Application of Purely Inorganic Icosahedral Boron Clusters in Emerging Nanomedicine
by: Francesc Teixidor, et al.
Published: (2023-05-01) -
History of Cobaltabis(dicarbollide) in Potentiometry, No Need for Ionophores to Get an Excellent Selectivity
by: Anca-Iulia Stoica, et al.
Published: (2022-11-01) -
N,O-Type Carborane-Based Materials
by: José Giner Planas, et al.
Published: (2016-05-01) -
Xanthomatous hypophysitis behaving like pituitary adenoma
by: MA Xiao⁃li, et al.
Published: (2023-07-01)