Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film
The fac-[Re(CO)3(dcbH2)(trans-stpy)]+ complex, dcbH2 = 2,2’-bipyridine-4,4’-dicarboxylic acid and trans-stpy = trans-4-styrylpyridine, has been strategically designed to absorb visible light up to 436 nm. For device purpose, the complex is also engineered to adsorb to the mesoporous TiO2 thin film t...
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Elsevier
2021-12-01
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Series: | Journal of Photochemistry and Photobiology |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2666469021000464 |
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author | Lais S. Matos Ronaldo C. Amaral Neyde Y. Murakami Iha |
author_facet | Lais S. Matos Ronaldo C. Amaral Neyde Y. Murakami Iha |
author_sort | Lais S. Matos |
collection | DOAJ |
description | The fac-[Re(CO)3(dcbH2)(trans-stpy)]+ complex, dcbH2 = 2,2’-bipyridine-4,4’-dicarboxylic acid and trans-stpy = trans-4-styrylpyridine, has been strategically designed to absorb visible light up to 436 nm. For device purpose, the complex is also engineered to adsorb to the mesoporous TiO2 thin film through carboxylic acid groups. In this work, an efficient visible trans-to-cis photoisomerization is described for the first time for an anchored-rhenium(I) complex on the TiO2 surface. |
first_indexed | 2024-12-17T15:19:24Z |
format | Article |
id | doaj.art-428d77c163704a50a4aa513bd6c0e261 |
institution | Directory Open Access Journal |
issn | 2666-4690 |
language | English |
last_indexed | 2024-12-17T15:19:24Z |
publishDate | 2021-12-01 |
publisher | Elsevier |
record_format | Article |
series | Journal of Photochemistry and Photobiology |
spelling | doaj.art-428d77c163704a50a4aa513bd6c0e2612022-12-21T21:43:26ZengElsevierJournal of Photochemistry and Photobiology2666-46902021-12-018100061Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 filmLais S. Matos0Ronaldo C. Amaral1Neyde Y. Murakami Iha2Laboratory of Photochemistry and Energy Conversion, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo–USP, Av. Prof. Lineu Prestes, 748, São Paulo, SP 05508-000, BrazilLaboratory of Photochemistry and Energy Conversion, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo–USP, Av. Prof. Lineu Prestes, 748, São Paulo, SP 05508-000, Brazil; Instituto Federal de Educação, Ciência e Tecnologia de São Paulo-IFSP, Campus Sorocaba, R. Maria Cinto de Biaggi, 130, Sorocaba, SP 18095-410, BrazilLaboratory of Photochemistry and Energy Conversion, Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo–USP, Av. Prof. Lineu Prestes, 748, São Paulo, SP 05508-000, Brazil; Corresponding author.The fac-[Re(CO)3(dcbH2)(trans-stpy)]+ complex, dcbH2 = 2,2’-bipyridine-4,4’-dicarboxylic acid and trans-stpy = trans-4-styrylpyridine, has been strategically designed to absorb visible light up to 436 nm. For device purpose, the complex is also engineered to adsorb to the mesoporous TiO2 thin film through carboxylic acid groups. In this work, an efficient visible trans-to-cis photoisomerization is described for the first time for an anchored-rhenium(I) complex on the TiO2 surface.http://www.sciencedirect.com/science/article/pii/S2666469021000464TiO2-Re(I) trans-cis photoisomerizationVisible sensitizationImmobilization on TiO2Rhenium(I) tricarbonyl complex |
spellingShingle | Lais S. Matos Ronaldo C. Amaral Neyde Y. Murakami Iha Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film Journal of Photochemistry and Photobiology TiO2-Re(I) trans-cis photoisomerization Visible sensitization Immobilization on TiO2 Rhenium(I) tricarbonyl complex |
title | Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film |
title_full | Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film |
title_fullStr | Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film |
title_full_unstemmed | Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film |
title_short | Outstanding visible trans-to-cis photoinduced isomerization of fac-[Re(CO)3(dcbH2)(trans-stpy)]+ on thin TiO2 film |
title_sort | outstanding visible trans to cis photoinduced isomerization of fac re co 3 dcbh2 trans stpy on thin tio2 film |
topic | TiO2-Re(I) trans-cis photoisomerization Visible sensitization Immobilization on TiO2 Rhenium(I) tricarbonyl complex |
url | http://www.sciencedirect.com/science/article/pii/S2666469021000464 |
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