Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate

The title molecule, C20H31NO8, has pseudo-C2 symmetry about the C—N bond, with the bis(tert-butoxycarbonyl)amino group twisted from the benzene ring plane by ca 60° and the bulky tert-butoxycarbonyl (Boc) groups are orientated away from the substituted aniline group. As pa...

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Main Authors: Ben Capuano, Ian T. Crosby, Craig M. Forsyth, Yelena Khakham, David T. Manallack
Format: Article
Language:English
Published: International Union of Crystallography 2009-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809009246
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author Ben Capuano
Ian T. Crosby
Craig M. Forsyth
Yelena Khakham
David T. Manallack
author_facet Ben Capuano
Ian T. Crosby
Craig M. Forsyth
Yelena Khakham
David T. Manallack
author_sort Ben Capuano
collection DOAJ
description The title molecule, C20H31NO8, has pseudo-C2 symmetry about the C—N bond, with the bis(tert-butoxycarbonyl)amino group twisted from the benzene ring plane by ca 60° and the bulky tert-butoxycarbonyl (Boc) groups are orientated away from the substituted aniline group. As part of an antibacterial drug discovery programme furnishing analogues of platensimycin, we unexpectedly synthesized the bis-Boc-protected aniline.
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spelling doaj.art-42c70d98083c4779b73f999116c305252022-12-21T19:25:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654o819o81910.1107/S1600536809009246Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetateBen CapuanoIan T. CrosbyCraig M. ForsythYelena KhakhamDavid T. ManallackThe title molecule, C20H31NO8, has pseudo-C2 symmetry about the C—N bond, with the bis(tert-butoxycarbonyl)amino group twisted from the benzene ring plane by ca 60° and the bulky tert-butoxycarbonyl (Boc) groups are orientated away from the substituted aniline group. As part of an antibacterial drug discovery programme furnishing analogues of platensimycin, we unexpectedly synthesized the bis-Boc-protected aniline.http://scripts.iucr.org/cgi-bin/paper?S1600536809009246
spellingShingle Ben Capuano
Ian T. Crosby
Craig M. Forsyth
Yelena Khakham
David T. Manallack
Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate
Acta Crystallographica Section E
title Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate
title_full Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate
title_fullStr Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate
title_full_unstemmed Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate
title_short Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate
title_sort di tert butyl n 2 6 bis methoxymethoxy phenyl iminodiacetate
url http://scripts.iucr.org/cgi-bin/paper?S1600536809009246
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AT yelenakhakham ditertbutyln26bismethoxymethoxyphenyliminodiacetate
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