High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids

Using conventional solid-state techniques, BaTiO3- Li0.5Fe2.5O4composites doped with Gd/Nb are prepared. Investigations are made on the electric and micro-structural characteristics of composites at high frequencies. The tetragonal structure without phase change is confirmed by the composites BTO, B...

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Main Authors: Ganapathi Rao Gajula, Lakshmi Rekha Buddiga, B.B.V. Sailaja
Format: Article
Language:English
Published: Elsevier 2023-08-01
Series:Hybrid Advances
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2773207X23000611
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author Ganapathi Rao Gajula
Lakshmi Rekha Buddiga
B.B.V. Sailaja
author_facet Ganapathi Rao Gajula
Lakshmi Rekha Buddiga
B.B.V. Sailaja
author_sort Ganapathi Rao Gajula
collection DOAJ
description Using conventional solid-state techniques, BaTiO3- Li0.5Fe2.5O4composites doped with Gd/Nb are prepared. Investigations are made on the electric and micro-structural characteristics of composites at high frequencies. The tetragonal structure without phase change is confirmed by the composites BTO, BTOLF, BGN-1, and BGN-2. Using FESEM micrographs, the grain size of the composite samples BTO, BTOLF, BGN-1, and BGN-2 was determined. The Impedance (Z′), Complex Impedance (Z′′), and Mod of Impedance (|Z |) of all composites exhibit dispersion among the samples in the frequency range between 1 MHz and 1 GHz. The capacitance (C′) of BGN-2 falls between BTOLF and BGN-1 as a result of the effect of grain size.Due to the Gd/Nb doping in BTOLF, the true part of the composite's conductance (YS′) peak migrated towards lower and higher frequencies. All composites experience a rise in frequency beyond 1 GHz and a sharp peak in both the real component of the electric modulus (M') and the imaginary part of the electric modulus (M'').
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spelling doaj.art-42dde5744c3c4bf5b3fb70aa0e6e56692023-08-21T04:20:56ZengElsevierHybrid Advances2773-207X2023-08-013100078High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solidsGanapathi Rao Gajula0Lakshmi Rekha Buddiga1B.B.V. Sailaja2Department of CSE (Data Science), Institute of Aeronautical Engineering (Autonomous), Dundigal, Hyderabad, Telangana, 500043, India; Corresponding author.Department of Chemistry, Andhra University, Visakhapatnam, 530 003, AP, IndiaDepartment of Chemistry, Andhra University, Visakhapatnam, 530 003, AP, IndiaUsing conventional solid-state techniques, BaTiO3- Li0.5Fe2.5O4composites doped with Gd/Nb are prepared. Investigations are made on the electric and micro-structural characteristics of composites at high frequencies. The tetragonal structure without phase change is confirmed by the composites BTO, BTOLF, BGN-1, and BGN-2. Using FESEM micrographs, the grain size of the composite samples BTO, BTOLF, BGN-1, and BGN-2 was determined. The Impedance (Z′), Complex Impedance (Z′′), and Mod of Impedance (|Z |) of all composites exhibit dispersion among the samples in the frequency range between 1 MHz and 1 GHz. The capacitance (C′) of BGN-2 falls between BTOLF and BGN-1 as a result of the effect of grain size.Due to the Gd/Nb doping in BTOLF, the true part of the composite's conductance (YS′) peak migrated towards lower and higher frequencies. All composites experience a rise in frequency beyond 1 GHz and a sharp peak in both the real component of the electric modulus (M') and the imaginary part of the electric modulus (M'').http://www.sciencedirect.com/science/article/pii/S2773207X23000611BaTiO3FESEMImpedanceCapacitanceElectric modulusComposite
spellingShingle Ganapathi Rao Gajula
Lakshmi Rekha Buddiga
B.B.V. Sailaja
High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids
Hybrid Advances
BaTiO3
FESEM
Impedance
Capacitance
Electric modulus
Composite
title High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids
title_full High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids
title_fullStr High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids
title_full_unstemmed High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids
title_short High-frequency electric modulus, impedance and conductance studies of gadolinium/niobium substituted barium titanate-lithium ferrite solids
title_sort high frequency electric modulus impedance and conductance studies of gadolinium niobium substituted barium titanate lithium ferrite solids
topic BaTiO3
FESEM
Impedance
Capacitance
Electric modulus
Composite
url http://www.sciencedirect.com/science/article/pii/S2773207X23000611
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