Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)

Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)

The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molec...

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Bibliographic Details
Main Authors: Muhammad Ali Ehsan, Muhammad Mazhar, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2016-01-01
Series:IUCrData
Subjects:
crystal structure
cadmium
dithiocarbamate
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314615024293
Description
Summary:The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C—H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C—H...π(phenyl) interactions.
ISSN:2414-3146

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