Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)
The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molec...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-01-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314615024293 |
| _version_ | 1828159869869359104 |
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| author | Muhammad Ali Ehsan Muhammad Mazhar Edward R. T. Tiekink |
| author_facet | Muhammad Ali Ehsan Muhammad Mazhar Edward R. T. Tiekink |
| author_sort | Muhammad Ali Ehsan |
| collection | DOAJ |
| description | The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C—H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C—H...π(phenyl) interactions. |
| first_indexed | 2024-04-12T00:09:17Z |
| format | Article |
| id | doaj.art-42e832f589d842d4ae0ae120dac0216b |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-12T00:09:17Z |
| publishDate | 2016-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-42e832f589d842d4ae0ae120dac0216b2022-12-22T03:56:01ZengInternational Union of CrystallographyIUCrData2414-31462016-01-0111x15242910.1107/S2414314615024293sj4002Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)Muhammad Ali Ehsan0Muhammad Mazhar1Edward R. T. Tiekink2Center of Research Excellence in Nanotechnology (CENT), King Fahd University of Petrolium & Minerals, Dhahran 31261, Saudia ArabiaDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, MalaysiaCentre for Crystalline Materials, Faculty of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, MalaysiaThe title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C—H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C—H...π(phenyl) interactions.http://scripts.iucr.org/cgi-bin/paper?S2414314615024293crystal structurecadmiumdithiocarbamate |
| spellingShingle | Muhammad Ali Ehsan Muhammad Mazhar Edward R. T. Tiekink Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) IUCrData crystal structure cadmium dithiocarbamate |
| title | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_full | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_fullStr | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_full_unstemmed | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_short | Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II) |
| title_sort | bis n benzyl n methyldithiocarbamato κ2s s pyridine κn cadmium ii |
| topic | crystal structure cadmium dithiocarbamate |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314615024293 |
| work_keys_str_mv | AT muhammadaliehsan bisnbenzylnmethyldithiocarbamatok2sspyridinekncadmiumii AT muhammadmazhar bisnbenzylnmethyldithiocarbamatok2sspyridinekncadmiumii AT edwardrttiekink bisnbenzylnmethyldithiocarbamatok2sspyridinekncadmiumii |