Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites

In this study, we report the fabrication of graphitic carbon nitride doped zinc oxide nanocomposites, g-C<sub>3</sub>N<sub>4</sub>/ZnO, (Zn-Us) by using different amount of urea. They were further characterized by X-ray Diffraction (XRD), Fourier-transform infrared spectrosco...

Full description

Bibliographic Details
Main Authors: Fahad A. Alharthi, Abdulaziz Ali Alghamdi, Hamdah S. Alanazi, Amjad Abdullah Alsyahi, Naushad Ahmad
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/10/12/1457
_version_ 1797544805480267776
author Fahad A. Alharthi
Abdulaziz Ali Alghamdi
Hamdah S. Alanazi
Amjad Abdullah Alsyahi
Naushad Ahmad
author_facet Fahad A. Alharthi
Abdulaziz Ali Alghamdi
Hamdah S. Alanazi
Amjad Abdullah Alsyahi
Naushad Ahmad
author_sort Fahad A. Alharthi
collection DOAJ
description In this study, we report the fabrication of graphitic carbon nitride doped zinc oxide nanocomposites, g-C<sub>3</sub>N<sub>4</sub>/ZnO, (Zn-Us) by using different amount of urea. They were further characterized by X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Raman, UV-vis, Scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) techniques. The prepared nanocomposites were used as photocatalysts for the mineralization of the light sensitive dyes Methylene Blue (MB) and Rose Bengal (RB) under UV light irradiation, and corresponding photo-mechanism was proposed. Benefiting from these photocatalytic characteristics, urea derived g-C<sub>3</sub>N<sub>4</sub>/ZnO photocatalysts have been found to have excellent photodegradation activity against the MB and RB for 6 h and 4 h, respectively. Under the given experimental conditions, the degradation percentage of fabricated Zn-Us were shown ~90% for both model dyes. Compared to cationic MB dye, anionic RB dye is more actively degraded on the surface of prepared photocatalysts. The results obtained can be effectively used for future practical applications in wastewater treatment
first_indexed 2024-03-10T14:06:44Z
format Article
id doaj.art-42ede510b39c45b09b71a614907fa85e
institution Directory Open Access Journal
issn 2073-4344
language English
last_indexed 2024-03-10T14:06:44Z
publishDate 2020-12-01
publisher MDPI AG
record_format Article
series Catalysts
spelling doaj.art-42ede510b39c45b09b71a614907fa85e2023-11-21T00:37:24ZengMDPI AGCatalysts2073-43442020-12-011012145710.3390/catal10121457Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO NanocompositesFahad A. Alharthi0Abdulaziz Ali Alghamdi1Hamdah S. Alanazi2Amjad Abdullah Alsyahi3Naushad Ahmad4Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaIn this study, we report the fabrication of graphitic carbon nitride doped zinc oxide nanocomposites, g-C<sub>3</sub>N<sub>4</sub>/ZnO, (Zn-Us) by using different amount of urea. They were further characterized by X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Raman, UV-vis, Scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) techniques. The prepared nanocomposites were used as photocatalysts for the mineralization of the light sensitive dyes Methylene Blue (MB) and Rose Bengal (RB) under UV light irradiation, and corresponding photo-mechanism was proposed. Benefiting from these photocatalytic characteristics, urea derived g-C<sub>3</sub>N<sub>4</sub>/ZnO photocatalysts have been found to have excellent photodegradation activity against the MB and RB for 6 h and 4 h, respectively. Under the given experimental conditions, the degradation percentage of fabricated Zn-Us were shown ~90% for both model dyes. Compared to cationic MB dye, anionic RB dye is more actively degraded on the surface of prepared photocatalysts. The results obtained can be effectively used for future practical applications in wastewater treatmenthttps://www.mdpi.com/2073-4344/10/12/1457Rose Bengalg-(C3N4)ZnOMethylene BlueUV-lightphotocatalytic degradation
spellingShingle Fahad A. Alharthi
Abdulaziz Ali Alghamdi
Hamdah S. Alanazi
Amjad Abdullah Alsyahi
Naushad Ahmad
Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
Catalysts
Rose Bengal
g-(C3N4)
ZnO
Methylene Blue
UV-light
photocatalytic degradation
title Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
title_full Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
title_fullStr Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
title_full_unstemmed Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
title_short Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
title_sort photocatalytic degradation of the light sensitive organic dyes methylene blue and rose bengal by using urea derived g c sub 3 sub n sub 4 sub zno nanocomposites
topic Rose Bengal
g-(C3N4)
ZnO
Methylene Blue
UV-light
photocatalytic degradation
url https://www.mdpi.com/2073-4344/10/12/1457
work_keys_str_mv AT fahadaalharthi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites
AT abdulazizalialghamdi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites
AT hamdahsalanazi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites
AT amjadabdullahalsyahi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites
AT naushadahmad photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites