Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites
In this study, we report the fabrication of graphitic carbon nitride doped zinc oxide nanocomposites, g-C<sub>3</sub>N<sub>4</sub>/ZnO, (Zn-Us) by using different amount of urea. They were further characterized by X-ray Diffraction (XRD), Fourier-transform infrared spectrosco...
Main Authors: | , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2020-12-01
|
Series: | Catalysts |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4344/10/12/1457 |
_version_ | 1797544805480267776 |
---|---|
author | Fahad A. Alharthi Abdulaziz Ali Alghamdi Hamdah S. Alanazi Amjad Abdullah Alsyahi Naushad Ahmad |
author_facet | Fahad A. Alharthi Abdulaziz Ali Alghamdi Hamdah S. Alanazi Amjad Abdullah Alsyahi Naushad Ahmad |
author_sort | Fahad A. Alharthi |
collection | DOAJ |
description | In this study, we report the fabrication of graphitic carbon nitride doped zinc oxide nanocomposites, g-C<sub>3</sub>N<sub>4</sub>/ZnO, (Zn-Us) by using different amount of urea. They were further characterized by X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Raman, UV-vis, Scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) techniques. The prepared nanocomposites were used as photocatalysts for the mineralization of the light sensitive dyes Methylene Blue (MB) and Rose Bengal (RB) under UV light irradiation, and corresponding photo-mechanism was proposed. Benefiting from these photocatalytic characteristics, urea derived g-C<sub>3</sub>N<sub>4</sub>/ZnO photocatalysts have been found to have excellent photodegradation activity against the MB and RB for 6 h and 4 h, respectively. Under the given experimental conditions, the degradation percentage of fabricated Zn-Us were shown ~90% for both model dyes. Compared to cationic MB dye, anionic RB dye is more actively degraded on the surface of prepared photocatalysts. The results obtained can be effectively used for future practical applications in wastewater treatment |
first_indexed | 2024-03-10T14:06:44Z |
format | Article |
id | doaj.art-42ede510b39c45b09b71a614907fa85e |
institution | Directory Open Access Journal |
issn | 2073-4344 |
language | English |
last_indexed | 2024-03-10T14:06:44Z |
publishDate | 2020-12-01 |
publisher | MDPI AG |
record_format | Article |
series | Catalysts |
spelling | doaj.art-42ede510b39c45b09b71a614907fa85e2023-11-21T00:37:24ZengMDPI AGCatalysts2073-43442020-12-011012145710.3390/catal10121457Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO NanocompositesFahad A. Alharthi0Abdulaziz Ali Alghamdi1Hamdah S. Alanazi2Amjad Abdullah Alsyahi3Naushad Ahmad4Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaDepartment of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaIn this study, we report the fabrication of graphitic carbon nitride doped zinc oxide nanocomposites, g-C<sub>3</sub>N<sub>4</sub>/ZnO, (Zn-Us) by using different amount of urea. They were further characterized by X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Raman, UV-vis, Scanning electron microscopy (SEM), and Transmission electron microscopy (TEM) techniques. The prepared nanocomposites were used as photocatalysts for the mineralization of the light sensitive dyes Methylene Blue (MB) and Rose Bengal (RB) under UV light irradiation, and corresponding photo-mechanism was proposed. Benefiting from these photocatalytic characteristics, urea derived g-C<sub>3</sub>N<sub>4</sub>/ZnO photocatalysts have been found to have excellent photodegradation activity against the MB and RB for 6 h and 4 h, respectively. Under the given experimental conditions, the degradation percentage of fabricated Zn-Us were shown ~90% for both model dyes. Compared to cationic MB dye, anionic RB dye is more actively degraded on the surface of prepared photocatalysts. The results obtained can be effectively used for future practical applications in wastewater treatmenthttps://www.mdpi.com/2073-4344/10/12/1457Rose Bengalg-(C3N4)ZnOMethylene BlueUV-lightphotocatalytic degradation |
spellingShingle | Fahad A. Alharthi Abdulaziz Ali Alghamdi Hamdah S. Alanazi Amjad Abdullah Alsyahi Naushad Ahmad Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites Catalysts Rose Bengal g-(C3N4) ZnO Methylene Blue UV-light photocatalytic degradation |
title | Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites |
title_full | Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites |
title_fullStr | Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites |
title_full_unstemmed | Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites |
title_short | Photocatalytic Degradation of the Light Sensitive Organic Dyes: Methylene Blue and Rose Bengal by Using Urea Derived g-C<sub>3</sub>N<sub>4</sub>/ZnO Nanocomposites |
title_sort | photocatalytic degradation of the light sensitive organic dyes methylene blue and rose bengal by using urea derived g c sub 3 sub n sub 4 sub zno nanocomposites |
topic | Rose Bengal g-(C3N4) ZnO Methylene Blue UV-light photocatalytic degradation |
url | https://www.mdpi.com/2073-4344/10/12/1457 |
work_keys_str_mv | AT fahadaalharthi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites AT abdulazizalialghamdi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites AT hamdahsalanazi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites AT amjadabdullahalsyahi photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites AT naushadahmad photocatalyticdegradationofthelightsensitiveorganicdyesmethyleneblueandrosebengalbyusingureaderivedgcsub3subnsub4subznonanocomposites |