Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials
A novel flexible supercapacitor device was developed from a polyethylene terephthalate substrate, reused from beverage bottles, and a conductive ink based on carbon black (CB) and cellulose acetate (CA). The weight composition of the conductive ink was evaluated to determine the best mass percentage...
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MDPI AG
2022-06-01
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author | Giovanni G. Daniele Daniel C. de Souza Paulo Roberto de Oliveira Luiz O. Orzari Rodrigo V. Blasques Rafael L. Germscheidt Emilly C. da Silva Leandro A. Pocrifka Juliano A. Bonacin Bruno C. Janegitz |
author_facet | Giovanni G. Daniele Daniel C. de Souza Paulo Roberto de Oliveira Luiz O. Orzari Rodrigo V. Blasques Rafael L. Germscheidt Emilly C. da Silva Leandro A. Pocrifka Juliano A. Bonacin Bruno C. Janegitz |
author_sort | Giovanni G. Daniele |
collection | DOAJ |
description | A novel flexible supercapacitor device was developed from a polyethylene terephthalate substrate, reused from beverage bottles, and a conductive ink based on carbon black (CB) and cellulose acetate (CA). The weight composition of the conductive ink was evaluated to determine the best mass percentage ratio between CB and CA in terms of capacitive behavior. The evaluation was performed by using different electrochemical techniques: cyclic voltammetry, obtaining the highest capacitance value for the device with the 66.7/33.3 wt% CB/CA in a basic H<sub>2</sub>SO<sub>4</sub> solution, reaching 135.64 F g<sup>−1</sup>. The device was applied in potentiostatic charge/discharge measurements, achieving values of 2.45 Wh kg<sup>−1</sup> for specific energy and around 1000 W kg<sup>−1</sup> for specific power. Therefore, corroborated with electrochemical impedance spectroscopy assays, the relatively low-price proposed device presented a suitable performance for application as supercapacitors, being manufactured from reused materials, contributing to the energy storage field enhancement. |
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issn | 2311-5629 |
language | English |
last_indexed | 2024-03-10T00:11:57Z |
publishDate | 2022-06-01 |
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spelling | doaj.art-42faf3c16111495c8de1e559f4b1d4102023-11-23T15:58:34ZengMDPI AGC2311-56292022-06-01823210.3390/c8020032Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly MaterialsGiovanni G. Daniele0Daniel C. de Souza1Paulo Roberto de Oliveira2Luiz O. Orzari3Rodrigo V. Blasques4Rafael L. Germscheidt5Emilly C. da Silva6Leandro A. Pocrifka7Juliano A. Bonacin8Bruno C. Janegitz9Laboratory of Sensors, Nanomedicine and Nanostructured Materials, Federal University of São Carlos, Araras 13600-970, São Paulo, BrazilLaboratory of Sensors, Nanomedicine and Nanostructured Materials, Federal University of São Carlos, Araras 13600-970, São Paulo, BrazilLaboratory of Sensors, Nanomedicine and Nanostructured Materials, Federal University of São Carlos, Araras 13600-970, São Paulo, BrazilLaboratory of Sensors, Nanomedicine and Nanostructured Materials, Federal University of São Carlos, Araras 13600-970, São Paulo, BrazilLaboratory of Sensors, Nanomedicine and Nanostructured Materials, Federal University of São Carlos, Araras 13600-970, São Paulo, BrazilInstitute of Chemistry, University of Campinas, Campinas 13083-859, São Paulo, BrazilLaboratory of Electrochemistry and Energy, Chemistry Graduate Program of Federal University of Amazonas, Manaus 69067-005, Amazonas, BrazilLaboratory of Electrochemistry and Energy, Chemistry Graduate Program of Federal University of Amazonas, Manaus 69067-005, Amazonas, BrazilInstitute of Chemistry, University of Campinas, Campinas 13083-859, São Paulo, BrazilLaboratory of Sensors, Nanomedicine and Nanostructured Materials, Federal University of São Carlos, Araras 13600-970, São Paulo, BrazilA novel flexible supercapacitor device was developed from a polyethylene terephthalate substrate, reused from beverage bottles, and a conductive ink based on carbon black (CB) and cellulose acetate (CA). The weight composition of the conductive ink was evaluated to determine the best mass percentage ratio between CB and CA in terms of capacitive behavior. The evaluation was performed by using different electrochemical techniques: cyclic voltammetry, obtaining the highest capacitance value for the device with the 66.7/33.3 wt% CB/CA in a basic H<sub>2</sub>SO<sub>4</sub> solution, reaching 135.64 F g<sup>−1</sup>. The device was applied in potentiostatic charge/discharge measurements, achieving values of 2.45 Wh kg<sup>−1</sup> for specific energy and around 1000 W kg<sup>−1</sup> for specific power. Therefore, corroborated with electrochemical impedance spectroscopy assays, the relatively low-price proposed device presented a suitable performance for application as supercapacitors, being manufactured from reused materials, contributing to the energy storage field enhancement.https://www.mdpi.com/2311-5629/8/2/32disposable devicesupercapacitorcarbon materialcarbon blackcellulose acetate |
spellingShingle | Giovanni G. Daniele Daniel C. de Souza Paulo Roberto de Oliveira Luiz O. Orzari Rodrigo V. Blasques Rafael L. Germscheidt Emilly C. da Silva Leandro A. Pocrifka Juliano A. Bonacin Bruno C. Janegitz Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials C disposable device supercapacitor carbon material carbon black cellulose acetate |
title | Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials |
title_full | Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials |
title_fullStr | Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials |
title_full_unstemmed | Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials |
title_short | Development of Disposable and Flexible Supercapacitor Based on Carbonaceous and Ecofriendly Materials |
title_sort | development of disposable and flexible supercapacitor based on carbonaceous and ecofriendly materials |
topic | disposable device supercapacitor carbon material carbon black cellulose acetate |
url | https://www.mdpi.com/2311-5629/8/2/32 |
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