Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries

Aimed at the growing interest in printed batteries, widely used industrial gravure printing was recently proven to be able to produce high-quality electrodes for lithium-ion batteries (LiBs), demonstrating its utility in the study of new functional materials. Here, for the first time, gravure printi...

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Main Authors: Maria Montanino, Anna De Girolamo Del Mauro, Claudia Paoletti, Giuliano Sico
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/12/10/999
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author Maria Montanino
Anna De Girolamo Del Mauro
Claudia Paoletti
Giuliano Sico
author_facet Maria Montanino
Anna De Girolamo Del Mauro
Claudia Paoletti
Giuliano Sico
author_sort Maria Montanino
collection DOAJ
description Aimed at the growing interest in printed batteries, widely used industrial gravure printing was recently proven to be able to produce high-quality electrodes for lithium-ion batteries (LiBs), demonstrating its utility in the study of new functional materials. Here, for the first time, gravure printing was investigated for the mass production of well-known low-cost graphite-based anodes for LiBs. Graphite was also chosen as a case study to explore the influence of process parameters on the layer microstructure and the performance of the printed anodes. In particular, upon decreasing the size of the active material nanoparticles through ball-milling, an enhancement in anode performance was observed, which is related to an improvement in the material distribution in the printed layer, even in the case of increasing mass loading through a multilayer approach. A further improvement in performance, close to the theoretical capacity, was possible by changing the ink parameters, obtaining a denser microstructure of the printed anode. Such good results further demonstrate the possibility of using gravure printing for the mass production of electrodes for printed batteries and, in general, components in the field of energy.
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spelling doaj.art-430475642287481bb7e28e68b81394372023-11-24T01:14:03ZengMDPI AGMembranes2077-03752022-10-01121099910.3390/membranes12100999Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed BatteriesMaria Montanino0Anna De Girolamo Del Mauro1Claudia Paoletti2Giuliano Sico3ENEA Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Portici Research Centre, 80055 Portici, ItalyENEA Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Portici Research Centre, 80055 Portici, ItalyENEA Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, 00123 Roma, ItalyENEA Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Portici Research Centre, 80055 Portici, ItalyAimed at the growing interest in printed batteries, widely used industrial gravure printing was recently proven to be able to produce high-quality electrodes for lithium-ion batteries (LiBs), demonstrating its utility in the study of new functional materials. Here, for the first time, gravure printing was investigated for the mass production of well-known low-cost graphite-based anodes for LiBs. Graphite was also chosen as a case study to explore the influence of process parameters on the layer microstructure and the performance of the printed anodes. In particular, upon decreasing the size of the active material nanoparticles through ball-milling, an enhancement in anode performance was observed, which is related to an improvement in the material distribution in the printed layer, even in the case of increasing mass loading through a multilayer approach. A further improvement in performance, close to the theoretical capacity, was possible by changing the ink parameters, obtaining a denser microstructure of the printed anode. Such good results further demonstrate the possibility of using gravure printing for the mass production of electrodes for printed batteries and, in general, components in the field of energy.https://www.mdpi.com/2077-0375/12/10/999gravure printingprinted batteriesanodeslithium-ion batteriesmultilayergraphite
spellingShingle Maria Montanino
Anna De Girolamo Del Mauro
Claudia Paoletti
Giuliano Sico
Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries
Membranes
gravure printing
printed batteries
anodes
lithium-ion batteries
multilayer
graphite
title Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries
title_full Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries
title_fullStr Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries
title_full_unstemmed Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries
title_short Gravure Printing of Graphite-Based Anodes for Lithium-Ion Printed Batteries
title_sort gravure printing of graphite based anodes for lithium ion printed batteries
topic gravure printing
printed batteries
anodes
lithium-ion batteries
multilayer
graphite
url https://www.mdpi.com/2077-0375/12/10/999
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AT annadegirolamodelmauro gravureprintingofgraphitebasedanodesforlithiumionprintedbatteries
AT claudiapaoletti gravureprintingofgraphitebasedanodesforlithiumionprintedbatteries
AT giulianosico gravureprintingofgraphitebasedanodesforlithiumionprintedbatteries