Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands
Herein, we describe the synthesis and single crystal X-ray diffraction characterization of several Pb(II) complexes using Schiff base hydrazido-based ligands and different counterions (NO<sub>3</sub><sup>−</sup>, I<sup>−</sup> and ClO<sub>...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-06-01
|
| Series: | Crystals |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4352/9/6/323 |
| _version_ | 1798002556161490944 |
|---|---|
| author | Ghodrat Mahmoudi Saikat Kumar Seth Fedor I. Zubkov Elena López-Torres Alessia Bacchi Vladimir Stilinović Antonio Frontera |
| author_facet | Ghodrat Mahmoudi Saikat Kumar Seth Fedor I. Zubkov Elena López-Torres Alessia Bacchi Vladimir Stilinović Antonio Frontera |
| author_sort | Ghodrat Mahmoudi |
| collection | DOAJ |
| description | Herein, we describe the synthesis and single crystal X-ray diffraction characterization of several Pb(II) complexes using Schiff base hydrazido-based ligands and different counterions (NO<sub>3</sub><sup>−</sup>, I<sup>−</sup> and ClO<sub>4</sub>). In the three complexes reported in this work, the lead(II) metal exhibits a high coordination number (n > 8) and thus it is apparently not involved in tetrel bonding interactions. Moreover, the aromatic ligands participate in noncovalent interactions that play an important role in the formation of several supramolecular assemblies in the solid state of the three Pb(II) complexes. These assemblies have been analyzed by means of Hirshfeld surface analysis and DFT calculations. |
| first_indexed | 2024-04-11T11:53:58Z |
| format | Article |
| id | doaj.art-4306944c09814e7597e85c620a88ee9b |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T11:53:58Z |
| publishDate | 2019-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-4306944c09814e7597e85c620a88ee9b2022-12-22T04:25:13ZengMDPI AGCrystals2073-43522019-06-019632310.3390/cryst9060323cryst9060323Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based LigandsGhodrat Mahmoudi0Saikat Kumar Seth1Fedor I. Zubkov2Elena López-Torres3Alessia Bacchi4Vladimir Stilinović5Antonio Frontera6Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh P.O. Box 55181-83111, IranDepartment of Physics, Jadavpur University, Kolkata 700032, IndiaOrganic Chemistry Department, Faculty of Science, Peoples’ Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St., Moscow 117198, RussiaDepartamento de Química Inorgánica, Facultad de Ciencias, Módulo 07, Universidad Autónoma de Madrid, Ctra. de Colmenar Viejo, Km 15, 28049 Madrid, SpainDipartimento di Scienze Chimiche, della Vita e della Sostenibilità Ambientale, Università di Parma, Viale delle Scienze 11A, 43124 Parma, ItalyDepartment of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, CroatiaDepartament de Química, Universitat de les Illes Balears, Ctra. de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), SpainHerein, we describe the synthesis and single crystal X-ray diffraction characterization of several Pb(II) complexes using Schiff base hydrazido-based ligands and different counterions (NO<sub>3</sub><sup>−</sup>, I<sup>−</sup> and ClO<sub>4</sub>). In the three complexes reported in this work, the lead(II) metal exhibits a high coordination number (n > 8) and thus it is apparently not involved in tetrel bonding interactions. Moreover, the aromatic ligands participate in noncovalent interactions that play an important role in the formation of several supramolecular assemblies in the solid state of the three Pb(II) complexes. These assemblies have been analyzed by means of Hirshfeld surface analysis and DFT calculations.https://www.mdpi.com/2073-4352/9/6/323lead(II) coordinationcrystal engineeringnoncovalent interactionsπ-stackinghydrogen bonding |
| spellingShingle | Ghodrat Mahmoudi Saikat Kumar Seth Fedor I. Zubkov Elena López-Torres Alessia Bacchi Vladimir Stilinović Antonio Frontera Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands Crystals lead(II) coordination crystal engineering noncovalent interactions π-stacking hydrogen bonding |
| title | Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands |
| title_full | Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands |
| title_fullStr | Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands |
| title_full_unstemmed | Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands |
| title_short | Supramolecular Assemblies in Pb(II) Complexes with Hydrazido-Based Ligands |
| title_sort | supramolecular assemblies in pb ii complexes with hydrazido based ligands |
| topic | lead(II) coordination crystal engineering noncovalent interactions π-stacking hydrogen bonding |
| url | https://www.mdpi.com/2073-4352/9/6/323 |
| work_keys_str_mv | AT ghodratmahmoudi supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands AT saikatkumarseth supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands AT fedorizubkov supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands AT elenalopeztorres supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands AT alessiabacchi supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands AT vladimirstilinovic supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands AT antoniofrontera supramolecularassembliesinpbiicomplexeswithhydrazidobasedligands |