Techniques for the Thermodynamic Consistency of Constitutive Equations

The paper investigates the techniques associated with the exploitation of the second law of thermodynamics as a restriction on the physically admissible processes. Though the exploitation consists of the use of the arbitrariness occurring in the Clausius–Duhem inequality, the approach emphasizes two...

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Main Authors: Angelo Morro, Claudio Giorgi
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Thermo
Subjects:
Online Access:https://www.mdpi.com/2673-7264/3/2/16
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author Angelo Morro
Claudio Giorgi
author_facet Angelo Morro
Claudio Giorgi
author_sort Angelo Morro
collection DOAJ
description The paper investigates the techniques associated with the exploitation of the second law of thermodynamics as a restriction on the physically admissible processes. Though the exploitation consists of the use of the arbitrariness occurring in the Clausius–Duhem inequality, the approach emphasizes two uncommon features within the thermodynamic analysis: the representation formula, of vectors and tensors, and the entropy production. The representation is shown to be fruitful whenever more terms of the Clausius–Duhem inequality are not independent. Among the examples developed to show this feature, the paper yields the constitutive equation for hypo-elastic solids and for Maxwell–Cattaneo-like equations of heat conduction. The entropy production is assumed to be given by a constitutive function per se and not merely the expression inherited by the other constitutive functions. This feature results in more general expressions of the representation formulae and is crucial for the compact description of hysteretic phenomena.
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spelling doaj.art-431245a406194f2fa6e453e20edade4c2023-11-18T12:53:32ZengMDPI AGThermo2673-72642023-05-013226027610.3390/thermo3020016Techniques for the Thermodynamic Consistency of Constitutive EquationsAngelo Morro0Claudio Giorgi1Dipartimento di Informatica, Bioingegneria, Robotica e Ingegneria dei Sistemi, Università di Genova, Via All’Opera Pia 13, 16145 Genova, ItalyDipartimento di Ingegneria Civile Ambiente Territorio Architettura e Matematica, Università di Brescia, Via Valotti 9, 25133 Brescia, ItalyThe paper investigates the techniques associated with the exploitation of the second law of thermodynamics as a restriction on the physically admissible processes. Though the exploitation consists of the use of the arbitrariness occurring in the Clausius–Duhem inequality, the approach emphasizes two uncommon features within the thermodynamic analysis: the representation formula, of vectors and tensors, and the entropy production. The representation is shown to be fruitful whenever more terms of the Clausius–Duhem inequality are not independent. Among the examples developed to show this feature, the paper yields the constitutive equation for hypo-elastic solids and for Maxwell–Cattaneo-like equations of heat conduction. The entropy production is assumed to be given by a constitutive function per se and not merely the expression inherited by the other constitutive functions. This feature results in more general expressions of the representation formulae and is crucial for the compact description of hysteretic phenomena.https://www.mdpi.com/2673-7264/3/2/16thermodynamic consistencyconstitutive equationsexploitation of the second lawrate equations
spellingShingle Angelo Morro
Claudio Giorgi
Techniques for the Thermodynamic Consistency of Constitutive Equations
Thermo
thermodynamic consistency
constitutive equations
exploitation of the second law
rate equations
title Techniques for the Thermodynamic Consistency of Constitutive Equations
title_full Techniques for the Thermodynamic Consistency of Constitutive Equations
title_fullStr Techniques for the Thermodynamic Consistency of Constitutive Equations
title_full_unstemmed Techniques for the Thermodynamic Consistency of Constitutive Equations
title_short Techniques for the Thermodynamic Consistency of Constitutive Equations
title_sort techniques for the thermodynamic consistency of constitutive equations
topic thermodynamic consistency
constitutive equations
exploitation of the second law
rate equations
url https://www.mdpi.com/2673-7264/3/2/16
work_keys_str_mv AT angelomorro techniquesforthethermodynamicconsistencyofconstitutiveequations
AT claudiogiorgi techniquesforthethermodynamicconsistencyofconstitutiveequations