Crystal structure of piperidinium 4-nitrophenolate
In the title molecular salt, C5H12N+·C6H4NO3−, the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N—H...O hydrogen bonds link adjace...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-12-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814025306 |
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| author | N. Swarna Sowmya S. Sampathkrishnan S. Sudhahar G. Chakkaravarthi R. Mohan Kumar |
| author_facet | N. Swarna Sowmya S. Sampathkrishnan S. Sudhahar G. Chakkaravarthi R. Mohan Kumar |
| author_sort | N. Swarna Sowmya |
| collection | DOAJ |
| description | In the title molecular salt, C5H12N+·C6H4NO3−, the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N—H...O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C—H...π interactions, forming sheets lying parallel to (001). |
| first_indexed | 2024-12-10T17:32:35Z |
| format | Article |
| id | doaj.art-431555474b554fad8951aeb1c01ef974 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:32:35Z |
| publishDate | 2014-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-431555474b554fad8951aeb1c01ef9742022-12-22T01:39:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-12-01701255956110.1107/S1600536814025306su5022Crystal structure of piperidinium 4-nitrophenolateN. Swarna Sowmya0S. Sampathkrishnan1S. Sudhahar2G. Chakkaravarthi3R. Mohan Kumar4Department of Applied Physics, Sri Venkateswara College of Engineering, Chennai 602 117, IndiaDepartment of Applied Physics, Sri Venkateswara College of Engineering, Chennai 602 117, IndiaDepartment of Physics, Presidency College, Chennai 600 005, IndiaDepartment of Physics, CPCL Polytechnic College, Chennai 600 068, IndiaDepartment of Physics, Presidency College, Chennai 600 005, IndiaIn the title molecular salt, C5H12N+·C6H4NO3−, the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N—H...O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C—H...π interactions, forming sheets lying parallel to (001).http://scripts.iucr.org/cgi-bin/paper?S1600536814025306crystal structuremolecular saltpiperidinium4-nitrophenolhydrogen bondingC—H...π interactions |
| spellingShingle | N. Swarna Sowmya S. Sampathkrishnan S. Sudhahar G. Chakkaravarthi R. Mohan Kumar Crystal structure of piperidinium 4-nitrophenolate Acta Crystallographica Section E crystal structure molecular salt piperidinium 4-nitrophenol hydrogen bonding C—H...π interactions |
| title | Crystal structure of piperidinium 4-nitrophenolate |
| title_full | Crystal structure of piperidinium 4-nitrophenolate |
| title_fullStr | Crystal structure of piperidinium 4-nitrophenolate |
| title_full_unstemmed | Crystal structure of piperidinium 4-nitrophenolate |
| title_short | Crystal structure of piperidinium 4-nitrophenolate |
| title_sort | crystal structure of piperidinium 4 nitrophenolate |
| topic | crystal structure molecular salt piperidinium 4-nitrophenol hydrogen bonding C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814025306 |
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