Exergetic Analysis of a Cryogenic Air Separation Unit

This case study analyzes a cryogenic air separation unit (ASU) with a production of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mover accent="true"><mi>V</mi>&l...

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Main Authors: Sorin Bucsa, Alexandru Serban, Mugur C. Balan, Claudia Ionita, Gabriel Nastase, Catalina Dobre, Alexandru Dobrovicescu
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/24/2/272
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author Sorin Bucsa
Alexandru Serban
Mugur C. Balan
Claudia Ionita
Gabriel Nastase
Catalina Dobre
Alexandru Dobrovicescu
author_facet Sorin Bucsa
Alexandru Serban
Mugur C. Balan
Claudia Ionita
Gabriel Nastase
Catalina Dobre
Alexandru Dobrovicescu
author_sort Sorin Bucsa
collection DOAJ
description This case study analyzes a cryogenic air separation unit (ASU) with a production of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mover accent="true"><mi>V</mi><mo>˙</mo></mover><mrow><msub><mi>O</mi><mn>2</mn></msub></mrow></msub><mo>=</mo><mn>58,300</mn><mo> </mo><mrow><mo>[</mo><mrow><mfrac><mrow><msup><mi>m</mi><mn>3</mn></msup><mi>N</mi></mrow><mi>h</mi></mfrac></mrow><mo>]</mo></mrow></mrow></semantics></math></inline-formula> of gaseous oxygen with a concentration greater than 98.5%, operating in Romania on a steel plant platform. The goal of the paper is to provide an extensive model of exergetic analysis that could be used in an optimization procedure when decisional parameters are changed or structural design modifications are implemented. For each key part of the Air Separation Unit, an exergetic product and fuel were defined and, based on their definition, the coefficient of performance of each functional zone was calculated. The information about the magnitude of the exergetic losses offers solutions for their future recovery. The analysis of the exergy destructions suggests when it is worth making a larger investment. The exergetic analysis of the compression area of the ASU points out an exergy destruction and loss of 37% from the total plant’s electrical energy input. The exergy loss with the heat transferred to the cooling system of compressors can be recovered; for the exergy destruction portion, the challenge between investment and operating costs should be considered. The exergy destruction of the air separation columns found the High Pressure Column (HPC) to be more destructive than the Low Pressure Column. The share of the exergy destruction in the total plant’s electrical energy input is 8.3% for the HPC. The local COP of the HPC, calculated depending on the total exergy of the local product and fuel, is 62.66%. The calculus of the air separation column is performed with the ChemSep simulator.
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spelling doaj.art-431650001c984095a182818899bd053f2023-11-23T19:48:42ZengMDPI AGEntropy1099-43002022-02-0124227210.3390/e24020272Exergetic Analysis of a Cryogenic Air Separation UnitSorin Bucsa0Alexandru Serban1Mugur C. Balan2Claudia Ionita3Gabriel Nastase4Catalina Dobre5Alexandru Dobrovicescu6Department of Engineering Thermodynamics, University Politehnica of Bucharest, 060042 Bucharest, RomaniaDepartment of Engineering Thermodynamics, University Politehnica of Bucharest, 060042 Bucharest, RomaniaDepartment of Thermodynamics, Technical University of Cluj-Napoca, 400114 Cluj-Napoca, RomaniaDepartment of Engineering Thermodynamics, University Politehnica of Bucharest, 060042 Bucharest, RomaniaDepartment of Engineering Thermodynamics, University Politehnica of Bucharest, 060042 Bucharest, RomaniaDepartment of Engineering Thermodynamics, University Politehnica of Bucharest, 060042 Bucharest, RomaniaDepartment of Engineering Thermodynamics, University Politehnica of Bucharest, 060042 Bucharest, RomaniaThis case study analyzes a cryogenic air separation unit (ASU) with a production of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mover accent="true"><mi>V</mi><mo>˙</mo></mover><mrow><msub><mi>O</mi><mn>2</mn></msub></mrow></msub><mo>=</mo><mn>58,300</mn><mo> </mo><mrow><mo>[</mo><mrow><mfrac><mrow><msup><mi>m</mi><mn>3</mn></msup><mi>N</mi></mrow><mi>h</mi></mfrac></mrow><mo>]</mo></mrow></mrow></semantics></math></inline-formula> of gaseous oxygen with a concentration greater than 98.5%, operating in Romania on a steel plant platform. The goal of the paper is to provide an extensive model of exergetic analysis that could be used in an optimization procedure when decisional parameters are changed or structural design modifications are implemented. For each key part of the Air Separation Unit, an exergetic product and fuel were defined and, based on their definition, the coefficient of performance of each functional zone was calculated. The information about the magnitude of the exergetic losses offers solutions for their future recovery. The analysis of the exergy destructions suggests when it is worth making a larger investment. The exergetic analysis of the compression area of the ASU points out an exergy destruction and loss of 37% from the total plant’s electrical energy input. The exergy loss with the heat transferred to the cooling system of compressors can be recovered; for the exergy destruction portion, the challenge between investment and operating costs should be considered. The exergy destruction of the air separation columns found the High Pressure Column (HPC) to be more destructive than the Low Pressure Column. The share of the exergy destruction in the total plant’s electrical energy input is 8.3% for the HPC. The local COP of the HPC, calculated depending on the total exergy of the local product and fuel, is 62.66%. The calculus of the air separation column is performed with the ChemSep simulator.https://www.mdpi.com/1099-4300/24/2/272chemical exergyrectification columncompression unit
spellingShingle Sorin Bucsa
Alexandru Serban
Mugur C. Balan
Claudia Ionita
Gabriel Nastase
Catalina Dobre
Alexandru Dobrovicescu
Exergetic Analysis of a Cryogenic Air Separation Unit
Entropy
chemical exergy
rectification column
compression unit
title Exergetic Analysis of a Cryogenic Air Separation Unit
title_full Exergetic Analysis of a Cryogenic Air Separation Unit
title_fullStr Exergetic Analysis of a Cryogenic Air Separation Unit
title_full_unstemmed Exergetic Analysis of a Cryogenic Air Separation Unit
title_short Exergetic Analysis of a Cryogenic Air Separation Unit
title_sort exergetic analysis of a cryogenic air separation unit
topic chemical exergy
rectification column
compression unit
url https://www.mdpi.com/1099-4300/24/2/272
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