Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries
Hard carbon is considered as the most commercially applicable anode for sodium-ion batteries. Lignin has the characteristics of sustainable, low cost, high carbon content (>60%) and abundant oxygen functional groups, which is expected to be used as a promising candidate precursor for low-cost har...
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KeAi Communications Co., Ltd.
2023-09-01
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| Series: | Resources Chemicals and Materials |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2772443323000302 |
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| author | Shunsheng Yang Zhihong Zhang Xueqing Qiu Lei Zhong Jiahong Huang Huiting Zhang Jianhui Ma Qingwei Meng Xihong Zu Wenli Zhang |
| author_facet | Shunsheng Yang Zhihong Zhang Xueqing Qiu Lei Zhong Jiahong Huang Huiting Zhang Jianhui Ma Qingwei Meng Xihong Zu Wenli Zhang |
| author_sort | Shunsheng Yang |
| collection | DOAJ |
| description | Hard carbon is considered as the most commercially applicable anode for sodium-ion batteries. Lignin has the characteristics of sustainable, low cost, high carbon content (>60%) and abundant oxygen functional groups, which is expected to be used as a promising candidate precursor for low-cost hard carbons. The structure and electrochemical performances of hard carbons could be regulated by adjusting carbonization temperature. The microstructure and electrochemical performance of LDHC anode are highly dependent on the carbonization temperature. Increasing carbonization temperature could reduce specific surface area and improve initial coulombic efficiency. The slope and plateau capacity of the LDHC anode could also be adjusted by changing the carbonization temperature. The LDHC prepared at 1200 °C showed the best sodium-ion storage performance, with an initial coulombic efficiency of 78.9% and a reversible sodium-ion storage capacity of 284.7 mAh g−1. |
| first_indexed | 2024-03-12T05:57:19Z |
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| id | doaj.art-433d773c1d7b44ff988f96bd112d0bc7 |
| institution | Directory Open Access Journal |
| issn | 2772-4433 |
| language | English |
| last_indexed | 2024-03-12T05:57:19Z |
| publishDate | 2023-09-01 |
| publisher | KeAi Communications Co., Ltd. |
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| series | Resources Chemicals and Materials |
| spelling | doaj.art-433d773c1d7b44ff988f96bd112d0bc72023-09-03T04:24:38ZengKeAi Communications Co., Ltd.Resources Chemicals and Materials2772-44332023-09-0123245251Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteriesShunsheng Yang0Zhihong Zhang1Xueqing Qiu2Lei Zhong3Jiahong Huang4Huiting Zhang5Jianhui Ma6Qingwei Meng7Xihong Zu8Wenli Zhang9Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, China; School of Advanced Manufacturing, Guangdong University of Technology (GDUT), Jieyang, Jieyang 522000, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, China; School of Advanced Manufacturing, Guangdong University of Technology (GDUT), Jieyang, Jieyang 522000, ChinaGuangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, China; School of Advanced Manufacturing, Guangdong University of Technology (GDUT), Jieyang, Jieyang 522000, China; Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang 515200, China; Corresponding author at: Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology (GDUT), 100 Waihuan Xi Road, Panyu District, Guangzhou 510006, China.Hard carbon is considered as the most commercially applicable anode for sodium-ion batteries. Lignin has the characteristics of sustainable, low cost, high carbon content (>60%) and abundant oxygen functional groups, which is expected to be used as a promising candidate precursor for low-cost hard carbons. The structure and electrochemical performances of hard carbons could be regulated by adjusting carbonization temperature. The microstructure and electrochemical performance of LDHC anode are highly dependent on the carbonization temperature. Increasing carbonization temperature could reduce specific surface area and improve initial coulombic efficiency. The slope and plateau capacity of the LDHC anode could also be adjusted by changing the carbonization temperature. The LDHC prepared at 1200 °C showed the best sodium-ion storage performance, with an initial coulombic efficiency of 78.9% and a reversible sodium-ion storage capacity of 284.7 mAh g−1.http://www.sciencedirect.com/science/article/pii/S2772443323000302LigninHard carbonAnodeSodium-ion battery |
| spellingShingle | Shunsheng Yang Zhihong Zhang Xueqing Qiu Lei Zhong Jiahong Huang Huiting Zhang Jianhui Ma Qingwei Meng Xihong Zu Wenli Zhang Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries Resources Chemicals and Materials Lignin Hard carbon Anode Sodium-ion battery |
| title | Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries |
| title_full | Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries |
| title_fullStr | Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries |
| title_full_unstemmed | Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries |
| title_short | Engineering of the microstructures of enzymatic hydrolysis lignin-derived hard carbon anodes for sodium-ion batteries |
| title_sort | engineering of the microstructures of enzymatic hydrolysis lignin derived hard carbon anodes for sodium ion batteries |
| topic | Lignin Hard carbon Anode Sodium-ion battery |
| url | http://www.sciencedirect.com/science/article/pii/S2772443323000302 |
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