Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon

In this article efficiency of activated carbon as a potent adsorbent of cationic dyes dyes present in waste water was studied in this research. Activated carbon (AC) from starch was used to adsorb methylene blue (MB) from an aqueous solution. Various parameters such as adsorbent concentration, tempe...

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Main Authors: Fatima Zahra Benhachem, Tarik Attar, Fouzia Bouabdallah
Format: Article
Language:English
Published: Iranian Chemical Science and Technologies Association 2019-02-01
Series:Chemical Review and Letters
Subjects:
Online Access:http://www.chemrevlett.com/article_87964_5fbc3a408b777230ca27c4a7257fee35.pdf
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author Fatima Zahra Benhachem
Tarik Attar
Fouzia Bouabdallah
author_facet Fatima Zahra Benhachem
Tarik Attar
Fouzia Bouabdallah
author_sort Fatima Zahra Benhachem
collection DOAJ
description In this article efficiency of activated carbon as a potent adsorbent of cationic dyes dyes present in waste water was studied in this research. Activated carbon (AC) from starch was used to adsorb methylene blue (MB) from an aqueous solution. Various parameters such as adsorbent concentration, temperature, initial dye concentration, contact time, and pH were investigated and the optimum parameters were determined based on the experimental outcomes. The extent of methylene blue removal increased with the increased in contact time, adsorbent mass, solution pH and amount of adsorbent used. Thermodynamic parameters like the Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were also determined and they showed that the adsorption process was feasible, spontaneous, and exothermic in the temperature range of 293–333 K. The experimental equilibrium data were analyzed using the isotherms of Langmuir, Freundlich, and Tempkin. Two simplified kinetic models including pseudo-first-order and pseudo-second-order equation were selected to follow the adsorption processes.
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spelling doaj.art-43548d0ff11e4c7591e2877fdadcf0812022-12-21T22:12:14ZengIranian Chemical Science and Technologies AssociationChemical Review and Letters2676-72792645-49472019-02-0121333910.22034/crl.2019.8796487964Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbonFatima Zahra Benhachem0Tarik Attar1Fouzia Bouabdallah2Department of Chemistry, institute of exact sciences, University Center Ahmed Zabana of Relizane. AlgeriaSuperior School of Applied Sciences of Tlemcen, Bel Horizon, Tlemcen, AlgeriaLaboratory for the Application of Organic Electrolytes and Polyelectrolytes (LAEPO), Department of Chemistry, Faculty of Science, University of Tlemcen, AlgeriaIn this article efficiency of activated carbon as a potent adsorbent of cationic dyes dyes present in waste water was studied in this research. Activated carbon (AC) from starch was used to adsorb methylene blue (MB) from an aqueous solution. Various parameters such as adsorbent concentration, temperature, initial dye concentration, contact time, and pH were investigated and the optimum parameters were determined based on the experimental outcomes. The extent of methylene blue removal increased with the increased in contact time, adsorbent mass, solution pH and amount of adsorbent used. Thermodynamic parameters like the Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were also determined and they showed that the adsorption process was feasible, spontaneous, and exothermic in the temperature range of 293–333 K. The experimental equilibrium data were analyzed using the isotherms of Langmuir, Freundlich, and Tempkin. Two simplified kinetic models including pseudo-first-order and pseudo-second-order equation were selected to follow the adsorption processes.http://www.chemrevlett.com/article_87964_5fbc3a408b777230ca27c4a7257fee35.pdfactivated carbonmethylene bluestarchisothermkinetics
spellingShingle Fatima Zahra Benhachem
Tarik Attar
Fouzia Bouabdallah
Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
Chemical Review and Letters
activated carbon
methylene blue
starch
isotherm
kinetics
title Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
title_full Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
title_fullStr Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
title_full_unstemmed Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
title_short Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
title_sort kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon
topic activated carbon
methylene blue
starch
isotherm
kinetics
url http://www.chemrevlett.com/article_87964_5fbc3a408b777230ca27c4a7257fee35.pdf
work_keys_str_mv AT fatimazahrabenhachem kineticstudyofadsorptionmethylenebluedyefromaqueoussolutionsusingactivatedcarbon
AT tarikattar kineticstudyofadsorptionmethylenebluedyefromaqueoussolutionsusingactivatedcarbon
AT fouziabouabdallah kineticstudyofadsorptionmethylenebluedyefromaqueoussolutionsusingactivatedcarbon