Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium

Aluminium corrosion in hydrochloric acid media is a huge challenge in the chemical industry; hence, creating green and more efficient inhibitors is an urgent task. Furthermore, the increasing amount of solid waste and its disposal consequences has been a major economic and environmental problem. The...

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Main Authors: Omotayo Sanni, Jianwei Ren, Tien-Chien Jen
Format: Article
Language:English
Published: Elsevier 2022-12-01
Series:Results in Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2590123022003462
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author Omotayo Sanni
Jianwei Ren
Tien-Chien Jen
author_facet Omotayo Sanni
Jianwei Ren
Tien-Chien Jen
author_sort Omotayo Sanni
collection DOAJ
description Aluminium corrosion in hydrochloric acid media is a huge challenge in the chemical industry; hence, creating green and more efficient inhibitors is an urgent task. Furthermore, the increasing amount of solid waste and its disposal consequences has been a major economic and environmental problem. Therefore, this study aims to determine the protective effect of coconut shell as a potential corrosion inhibitor for AA2024-T3 aluminium alloy in 1 M hydrochloric acid solutions using weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy techniques. The results show that the inhibition efficiency increases with an increase in the coconut shell concentration, and the maximum inhibition efficiency reaches 97.91% at 1 g/L. The potentiodynamic polarization study shows that the inhibitor acts as a mixed-type corrosion inhibitor. The adsorption of the inhibitor obeyed the Langmuir adsorption isotherm. The surface characterization confirmed the presence of barrier layers covering the aluminum surface. The mechanical properties were also determined and discussed. As compared to the wide range of reported corrosion inhibitors in the literature, the coconut shell has shown to be highly effective for AA2024-T3aluminium alloy. Therefore, it can be suggested that coconut shell waste is a potential corrosion inhibitor for AA2024-T3aluminium alloy in the chemical industry.
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spelling doaj.art-437108da4636421284047810d5f591852022-12-22T02:31:38ZengElsevierResults in Engineering2590-12302022-12-0116100676Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid mediumOmotayo Sanni0Jianwei Ren1Tien-Chien Jen2Corresponding author.; Department of Mechanical Engineering Science, University of Johannesburg, Cnr Kingsway and University Roads, Auckland Park, 2092, Johannesburg, South AfricaCorresponding author.; Department of Mechanical Engineering Science, University of Johannesburg, Cnr Kingsway and University Roads, Auckland Park, 2092, Johannesburg, South AfricaDepartment of Mechanical Engineering Science, University of Johannesburg, Cnr Kingsway and University Roads, Auckland Park, 2092, Johannesburg, South AfricaAluminium corrosion in hydrochloric acid media is a huge challenge in the chemical industry; hence, creating green and more efficient inhibitors is an urgent task. Furthermore, the increasing amount of solid waste and its disposal consequences has been a major economic and environmental problem. Therefore, this study aims to determine the protective effect of coconut shell as a potential corrosion inhibitor for AA2024-T3 aluminium alloy in 1 M hydrochloric acid solutions using weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy techniques. The results show that the inhibition efficiency increases with an increase in the coconut shell concentration, and the maximum inhibition efficiency reaches 97.91% at 1 g/L. The potentiodynamic polarization study shows that the inhibitor acts as a mixed-type corrosion inhibitor. The adsorption of the inhibitor obeyed the Langmuir adsorption isotherm. The surface characterization confirmed the presence of barrier layers covering the aluminum surface. The mechanical properties were also determined and discussed. As compared to the wide range of reported corrosion inhibitors in the literature, the coconut shell has shown to be highly effective for AA2024-T3aluminium alloy. Therefore, it can be suggested that coconut shell waste is a potential corrosion inhibitor for AA2024-T3aluminium alloy in the chemical industry.http://www.sciencedirect.com/science/article/pii/S2590123022003462AA2024-T3aluminium alloyGreen inhibitorAgricultural wasteCorrosion
spellingShingle Omotayo Sanni
Jianwei Ren
Tien-Chien Jen
Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium
Results in Engineering
AA2024-T3aluminium alloy
Green inhibitor
Agricultural waste
Corrosion
title Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium
title_full Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium
title_fullStr Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium
title_full_unstemmed Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium
title_short Agro-industrial wastes as corrosion inhibitor for 2024-T3 aluminum alloy in hydrochloric acid medium
title_sort agro industrial wastes as corrosion inhibitor for 2024 t3 aluminum alloy in hydrochloric acid medium
topic AA2024-T3aluminium alloy
Green inhibitor
Agricultural waste
Corrosion
url http://www.sciencedirect.com/science/article/pii/S2590123022003462
work_keys_str_mv AT omotayosanni agroindustrialwastesascorrosioninhibitorfor2024t3aluminumalloyinhydrochloricacidmedium
AT jianweiren agroindustrialwastesascorrosioninhibitorfor2024t3aluminumalloyinhydrochloricacidmedium
AT tienchienjen agroindustrialwastesascorrosioninhibitorfor2024t3aluminumalloyinhydrochloricacidmedium