Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices

<p>Abstract</p> <p>A vertically aligned carbon nanofiber array coated with anatase TiO<sub>2</sub> (CNF/TiO<sub>2</sub>) is an attractive possible replacement for the sintered TiO<sub>2</sub> nanoparticle network in the original dye-sensitized so...

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Main Authors: Rochford Caitlin, Wu Judy, Liu Jianwei, Li Jun, Javier Baca F, Li Zhuangzhi
Format: Article
Language:English
Published: SpringerOpen 2010-01-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1007/s11671-010-9665-3
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author Rochford Caitlin
Wu Judy
Liu Jianwei
Li Jun
Javier Baca F
Li Zhuangzhi
author_facet Rochford Caitlin
Wu Judy
Liu Jianwei
Li Jun
Javier Baca F
Li Zhuangzhi
author_sort Rochford Caitlin
collection DOAJ
description <p>Abstract</p> <p>A vertically aligned carbon nanofiber array coated with anatase TiO<sub>2</sub> (CNF/TiO<sub>2</sub>) is an attractive possible replacement for the sintered TiO<sub>2</sub> nanoparticle network in the original dye-sensitized solar cell (DSSC) design due to the potential for improved charge transport and reduced charge recombination. Although the reported efficiency of 1.1% in these modified DSSC&#8217;s is encouraging, the limiting factors must be identified before a higher efficiency can be obtained. This work employs a single nanowire approach to investigate the charge transport in individual CNF/TiO<sub>2</sub> core&#8211;shell nanowires with adsorbed N719 dye molecules in dark and under illumination. The results shed light on the role of charge traps and dye adsorption on the (photo) conductivity of nanocrystalline TiO<sub>2</sub> CNF&#8217;s as related to dye-sensitized solar cell performance.</p>
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spelling doaj.art-4382e1abd0fe496880b593655106a6922023-09-02T14:04:00ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2010-01-015914801486Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire DevicesRochford CaitlinWu JudyLiu JianweiLi JunJavier Baca FLi Zhuangzhi<p>Abstract</p> <p>A vertically aligned carbon nanofiber array coated with anatase TiO<sub>2</sub> (CNF/TiO<sub>2</sub>) is an attractive possible replacement for the sintered TiO<sub>2</sub> nanoparticle network in the original dye-sensitized solar cell (DSSC) design due to the potential for improved charge transport and reduced charge recombination. Although the reported efficiency of 1.1% in these modified DSSC&#8217;s is encouraging, the limiting factors must be identified before a higher efficiency can be obtained. This work employs a single nanowire approach to investigate the charge transport in individual CNF/TiO<sub>2</sub> core&#8211;shell nanowires with adsorbed N719 dye molecules in dark and under illumination. The results shed light on the role of charge traps and dye adsorption on the (photo) conductivity of nanocrystalline TiO<sub>2</sub> CNF&#8217;s as related to dye-sensitized solar cell performance.</p>http://dx.doi.org/10.1007/s11671-010-9665-3PhotoconductivityNanowireTitanium dioxideDye-sensitized solar cellCore&#8211;shell
spellingShingle Rochford Caitlin
Wu Judy
Liu Jianwei
Li Jun
Javier Baca F
Li Zhuangzhi
Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices
Nanoscale Research Letters
Photoconductivity
Nanowire
Titanium dioxide
Dye-sensitized solar cell
Core&#8211;shell
title Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices
title_full Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices
title_fullStr Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices
title_full_unstemmed Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices
title_short Investigation into Photoconductivity in Single CNF/TiO<sub>2</sub>-Dye Core&#8211;Shell Nanowire Devices
title_sort investigation into photoconductivity in single cnf tio sub 2 sub dye core 8211 shell nanowire devices
topic Photoconductivity
Nanowire
Titanium dioxide
Dye-sensitized solar cell
Core&#8211;shell
url http://dx.doi.org/10.1007/s11671-010-9665-3
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AT liujianwei investigationintophotoconductivityinsinglecnftiosub2subdyecore8211shellnanowiredevices
AT lijun investigationintophotoconductivityinsinglecnftiosub2subdyecore8211shellnanowiredevices
AT javierbacaf investigationintophotoconductivityinsinglecnftiosub2subdyecore8211shellnanowiredevices
AT lizhuangzhi investigationintophotoconductivityinsinglecnftiosub2subdyecore8211shellnanowiredevices