The Facile Microwave-Assisted Coprecipitation Route to Obtain Polyoxoniobate (Na<sub>7</sub>(H<sub>3</sub>O)Nb<sub>6</sub>O<sub>19</sub>·14H<sub>2</sub>O) Nanorods Modified with Copper for CO<sub>2</sub> Photoreduction

The Facile Microwave-Assisted Coprecipitation Route to Obtain Polyoxoniobate (Na<sub>7</sub>(H<sub>3</sub>O)Nb<sub>6</sub>O<sub>19</sub>·14H<sub>2</sub>O) Nanorods Modified with Copper for CO<sub>2</sub> Photoreduction

The CO<sub>2</sub> reduction by solar means has been discussed as an alternative to emission abatement, a fundamental topic for sustainable, carbon-free production in the future. However, the choice of efficient systems, starting with the catalysts, is still a critical issue, especially...

Full description

Bibliographic Details
Main Authors:	Joelma R. C. Souza, Juliana A. Torres, Lucas S. Ribeiro, Jose B. G. Filho, Fabiana L. Santos, Nicholas Malgioglio, Luiz Fernando Gorup, Alexandre H. Pinto, André E. Nogueira
Format:	Article
Language:	English
Published:	MDPI AG 2023-06-01
Series:	AppliedChem
Subjects:	polyoxometalates microwave-assisted hydrothermal synthesis photocatalysis greenhouse gas
Online Access:	https://www.mdpi.com/2673-9623/3/2/20

Similar Items

Synthesis and Structures of the Capped and Sandwiched Cobalt Heptamolybdate Polyoxometalate (NH<sub>4</sub>)<sub>6</sub>{[Co(H<sub>2</sub>O)<sub>5</sub>][Mo<sub>7</sub>O<sub>24</sub>][Co(H<sub>2</sub>O)<sub>2</sub>][Mo<sub>7</sub>O<sub>24</sub>][Co(H<sub>2</sub>O)<sub>5</sub>]} · 6 H<sub>2</sub>O and Its Extended Structure (NH<sub>4</sub>)<sub>6</sub>{[Co(H<sub>2</sub>O)<sub>2</sub>]<sub>3</sub>[Mo<sub>7</sub>O<sub>24</sub>]<sub>2</sub>}
by: Matthieu R. Spriet, et al.
Published: (2022-08-01)

Morphology Control of TiO<sub>2</sub> Nanorods Using KBr Salt for Enhancing the Photocatalytic Activity of TiO<sub>2</sub> and MoS<sub>2</sub>/TiO<sub>2</sub> Heterostructures
by: Zeineb A. Thiehmed, et al.
Published: (2022-08-01)

Influence of the Structure of Hydrothermal-Synthesized TiO<sub>2</sub> Nanowires Formed by Annealing on the Photocatalytic Reduction of CO<sub>2</sub> in H<sub>2</sub>O Vapor
by: Andrey M. Tarasov, et al.
Published: (2024-08-01)

Mo<sub>2</sub>C as Pre-Catalyst for the C-H Allylic Oxygenation of Alkenes and Terpenoids in the Presence of H<sub>2</sub>O<sub>2</sub>
by: Michael G. Kallitsakis, et al.
Published: (2022-07-01)

A New Fe<sup>III</sup> Substituted Arsenotungstate [Fe<sup>III</sup><sub>2</sub>(As<sup>III</sup>W<sub>6</sub>O<sub>23</sub>)<sub>2</sub>(As<sup>III</sup>O<sub>3</sub>H)<sub>2</sub>]<sup>12−</sup>: Synthesis, Structure, Characterization and Magnetic Properties
by: Masooma Ibrahim, et al.
Published: (2020-10-01)

Phase Formation in NaH<sub>2</sub>PO<sub>4</sub>–VOSO<sub>4</sub>–NaF–H<sub>2</sub>O System and Rapid Synthesis of Na<sub>3</sub>V<sub>2</sub>O<sub>2x</sub>(PO<sub>4</sub>)<sub>2</sub>F<sub>3-2x</sub>
by: Zhi Lin
Published: (2023-12-01)

Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H<sub>2</sub>O)(CH<sub>3</sub>COO)(P<sub>2</sub>W<sub>17</sub>O<sub>61</sub>)}<sub>2</sub>]<sup>16−</sup>
by: Masooma Ibrahim, et al.
Published: (2020-09-01)

Photocatalytic Efficiency of TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub> and TiO<sub>2</sub>/WO<sub>3</sub> Nanocomposites
by: Federico Giuffrida, et al.
Published: (2023-02-01)

Application of the [WO<sub>2</sub>(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>2</sub>] Complex in Hydrothermal Synthesis of WO<sub>3</sub> Film and Study of Its Electrochromic Properties
by: Philipp Yu. Gorobtsov, et al.
Published: (2023-07-01)

Exploring Pt-Impregnated CdS/TiO<sub>2</sub> Heterostructures for CO<sub>2</sub> Photoreduction
by: Lidia García-Santos, et al.
Published: (2024-11-01)

Synthesis, Crystal Structure, Electrochemistry and Electro-Catalytic Properties of the Manganese-Containing Polyoxotungstate, [(Mn(H<sub>2</sub>O)<sub>3</sub>)<sub>2</sub>(H<sub>2</sub>W<sub>12</sub>O<sub>42</sub>)]<sup>6−</sup>
by: Anne-Lucie Teillout, et al.
Published: (2019-02-01)

Nanomaterial with Core–Shell Structure Composed of {P<sub>2</sub>W<sub>18</sub>O<sub>62</sub>} and Cobalt Homobenzotrizoate for Supercapacitors and H<sub>2</sub>O<sub>2</sub>-Sensing Applications
by: Lanyue Zhang, et al.
Published: (2023-03-01)

Photocatalytic Hydrogen Production from Aqueous Solutions of Glucose and Xylose over Layered Perovskite-like Oxides HCa<sub>2</sub>Nb<sub>3</sub>O<sub>10</sub>, H<sub>2</sub>La<sub>2</sub>Ti<sub>3</sub>O<sub>10</sub> and Their Inorganic-Organic Derivatives
by: Sergei A. Kurnosenko, et al.
Published: (2022-08-01)

Incorporation of NiO into SiO<sub>2</sub>, TiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, and Na<sub>4.2</sub>Ca<sub>2.8</sub>(Si<sub>6</sub>O<sub>18</sub>) Matrices: Medium Effect on the Optical Properties and Catalytic Degradation of Methylene Blue
by: Carlos Diaz, et al.
Published: (2020-12-01)

The Composite TiO<sub>2</sub>–CuO<sub>x</sub> Layers Formed by Electrophoretic Method for CO<sub>2</sub> Gas Photoreduction
by: Larisa I. Sorokina, et al.
Published: (2023-07-01)

Preparation and Application of Nb<sub>2</sub>O<sub>5</sub> Nanofibers in CO<sub>2</sub> Photoconversion
by: A. C. F. Prado, et al.
Published: (2021-12-01)

Tunable Carrier Transfer of Polymeric Carbon Nitride with Charge-Conducting CoV<sub>2</sub>O<sub>6</sub>∙2H<sub>2</sub>O for Photocatalytic O<sub>2</sub> Evolution
by: Shaohong Zang, et al.
Published: (2022-06-01)

Photocatalytic H<sub>2</sub> Production on Au/TiO<sub>2</sub>: Effect of Au Photodeposition on Different TiO<sub>2</sub> Crystalline Phases
by: Stefano Andrea Balsamo, et al.
Published: (2022-01-01)

Hydrothermal Synthesis of Layered Titanium Phosphate Ti<sub>2</sub>O<sub>2</sub>H(PO<sub>4</sub>)[(NH<sub>4</sub>)<sub>2</sub>PO<sub>4</sub>]<sub>2</sub> and Its Potential Application in Cosmetics
by: Irina V. Kolesnik, et al.
Published: (2019-06-01)

Flame Spray Pyrolysis Engineering of Nanosized Mullite-Bi<sub>2</sub>Fe<sub>4</sub>O<sub>9</sub> and Perovskite-BiFeO<sub>3</sub> as Highly Efficient Photocatalysts for O<sub>2</sub> Production from H<sub>2</sub>O Splitting
by: Pavlos Psathas, et al.
Published: (2021-08-01)

CuMo<sub>x</sub>W<sub>(1-x)</sub>O<sub>4</sub> Solid Solution Display Visible Light Photoreduction of CO<sub>2</sub> to CH<sub>3</sub>OH Coupling with Oxidation of Amine to Imine
by: Chao Luo, et al.
Published: (2020-07-01)

Designed Syntheses of Three {Ni<sub>6</sub>PW<sub>9</sub>}-Based Polyoxometalates, from Isolated Cluster to Cluster-Organic Helical Chain
by: Chong-An Chen, et al.
Published: (2022-07-01)

In-Situ Fabricating V<sub>2</sub>O<sub>5</sub>/TiO<sub>2</sub>-Carbon Heterojunction from Ti<sub>3</sub>C<sub>2</sub> MXene as Highly Active Visible-Light Photocatalyst
by: Wentao Xu, et al.
Published: (2022-05-01)

Ceramic ZnO-SnO<sub>2</sub>-Fe<sub>2</sub>O<sub>3</sub> Powders and Coatings -Effective Photogenerators of Reactive Oxygen Species
by: Larisa Khomutinnikova, et al.
Published: (2023-04-01)

Composition-Regulated Photocatalytic Activity of ZnIn<sub>2</sub>S<sub>4</sub>@CdS Hybrids for Efficient Dye Degradation and H<sub>2</sub>O<sub>2</sub> Evolution
by: Nikolaos Karamoschos, et al.
Published: (2024-08-01)

In Vitro Antifungal Activity and Mechanism of Ag<sub>3</sub>PW<sub>12</sub>O<sub>40</sub> Composites against <i>Candida</i> Species
by: Xinming Zhang, et al.
Published: (2020-12-01)

Hydrothermal Synthesis and Crystal Structure of Vesuvianite Compounds, Ca<sub>19</sub>Al<sub>13</sub>Si<sub>18</sub>O<sub>71</sub>(OH)<sub>7</sub> and Sr<sub>19</sub>Fe<sub>12</sub>Ge<sub>19</sub>O<sub>72</sub>(OH)<sub>6</sub>
by: Megan M. Smart, et al.
Published: (2023-08-01)

Preparation of Ca<sub>2</sub>Al<sub>1–m</sub>Fe<sub>m</sub>(OH)<sub>6</sub>Cl·2H<sub>2</sub>O-Doped Hydrocalumites and Application of Their Derived Mixed Oxides in the Photodegradation of Ibuprofen
by: Alejandro Jiménez, et al.
Published: (2022-08-01)

Preparation and Evaluation of Nanocomposite Sodalite/α-Al<sub>2</sub>O<sub>3</sub> Tubular Membranes for H<sub>2</sub>/CO<sub>2</sub> Separation
by: Orevaoghene Eterigho-Ikelegbe, et al.
Published: (2020-10-01)

Microextrusion Printing of Multilayer Hierarchically Organized Planar Nanostructures Based on NiO, (CeO<sub>2</sub>)<sub>0.8</sub>(Sm<sub>2</sub>O<sub>3</sub>)<sub>0.2</sub> and La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3−δ</sub>
by: Tatiana L. Simonenko, et al.
Published: (2022-12-01)

Tribocorrosion Evaluation of Nb<sub>2</sub>O<sub>5</sub>, TiO<sub>2</sub>, and Nb<sub>2</sub>O<sub>5</sub> + TiO<sub>2</sub> Coatings for Medical Applications
by: Giovany Orozco-Hernández, et al.
Published: (2021-05-01)

Crystal Structure and Magnetic Properties of Peacock–Weakley Type Polyoxometalates Na<sub>9</sub>[Ln(W<sub>5</sub>O<sub>18</sub>)<sub>2</sub>] (Ln = Tm, Yb): Rare Example of Tm(III) SMM
by: Oleksandra Yu. Mariichak, et al.
Published: (2020-10-01)

UV-Vis Activated Cu<sub>2</sub>O/SnO<sub>2</sub>/WO<sub>3</sub> Heterostructure for Photocatalytic Removal of Pesticides
by: Alexandru Enesca, et al.
Published: (2022-08-01)

Synergistic Ag/g–C<sub>3</sub>N<sub>4</sub> H<sub>2</sub>O<sub>2</sub> System for Photocatalytic Degradation of Azo Dyes
by: Yajing Wang, et al.
Published: (2024-08-01)

Synthesis and Characterization of Ammonium Potassium Tellurium Polyoxomolybdate: (NH<sub>4</sub>)<sub>2</sub>K<sub>2</sub>TeMo<sub>6</sub>O<sub>22</sub>·2H<sub>2</sub>O with One-Dimensional Anionic Polymeric Chain [TeMo<sub>6</sub>O<sub>22</sub>]<sup>4−</sup>
by: Lei Geng, et al.
Published: (2021-04-01)

Comparison of the Magnesiothermic Reduction Behavior of Nb<sub>2</sub>O<sub>5</sub> and Ti<sub>2</sub>Nb<sub>10</sub>O<sub>29</sub>
by: Jiwon Hong, et al.
Published: (2023-10-01)

Ceramic Materials in Na<sub>2</sub>O-CaO-P<sub>2</sub>O<sub>5</sub> System, Obtained via Heat Treatment of Cement-Salt Stone Based on Powder Mixture of Ca<sub>3</sub>(C<sub>6</sub>H<sub>5</sub>O<sub>7</sub>)<sub>2</sub>∙4H<sub>2</sub>O, Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>∙H<sub>2</sub>O and NaH<sub>2</sub>PO<sub>4</sub>
by: Otabek U. Toshev, et al.
Published: (2023-02-01)

Successive Crystallization of Organically Templated Uranyl Sulfates: Synthesis and Crystal Structures of [pyH](H<sub>3</sub>O)[(UO<sub>2</sub>)<sub>3</sub>(SO<sub>4</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>], [pyH]<sub>2</sub>[(UO<sub>2</sub>)<sub>6</sub>(SO<sub>4</sub>)<sub>7</sub>(H<sub>2</sub>O)], and [pyH]<sub>2</sub>[(UO<sub>2</sub>)<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>]
by: Evgeny V. Nazarchuk, et al.
Published: (2021-01-01)

Polymer-Based Immobilized FePMo<sub>12</sub>O<sub>40</sub>@PVP Composite Materials for Photocatalytic RhB Degradation
by: Zijing Wang, et al.
Published: (2024-05-01)

Crystal-to-Crystal Transformation from K<sub>2</sub>[Co(C<sub>2</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·4H<sub>2</sub>O to K<sub>2</sub>[Co(μ-C<sub>2</sub>O<sub>4</sub>)(C<sub>2</sub>O<sub>4</sub>)]
by: Bin Zhang, et al.
Published: (2021-05-01)